Pressure-Induced Large Volume Collapse, Plane-to-Chain, Insulator to Metal Transition in CaMn2Bi2

Gui, Xin; Finkelstein, Gregory J.; Chen, Keyu; Yong, Tommy; Dera, Przemyslaw; Cheng, Jinguang; Xie, Weiwei

doi:10.1021/acs.inorgchem.9b01362

Pressure-Induced Large Volume Collapse, Plane-to-Chain, Insulator to Metal Transition in CaMn₂Bi₂

Journal Article · Tue Jul 02 00:00:00 EDT 2019 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.9b01362· OSTI ID:1602041

Gui, Xin ^[1]; Finkelstein, Gregory J. ^[2]; Chen, Keyu ^[3]; Yong, Tommy ^[2]; Dera, Przemyslaw ^[2]; ^[4]; ^[5]

Louisiana State Univ., Baton Rouge, LA (United States); Louisiana State University
Univ. of Hawaii at Manoa, Honolulu, HI (United States)
Univ. of Chinese Academy of Sciences, Beijing (China)
Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Sciences, Beijing (China); Songshan Lake Materials Lab., Dongguan, Guangdong (China)
Louisiana State Univ., Baton Rouge, LA (United States)

We report that in situ high pressure single crystal X-ray diffraction study reveals that the quantum material CaMn₂Bi₂ undergoes a unique plane to chain structural transition between 2 and 3 GPa, accompanied by a large volume collapse. Puckered Mn–Mn honeycomb layer converts to quasi-one-dimensional (1D) zigzag chains above the phase transition pressure. Single crystal measurements reveal that the pressure-induced structural transformation is accompanied by a dramatic 2 orders of magnitude drop of resistivity. Although the ambient pressure phase displays semiconducting behavior at low temperatures, metallic temperature dependent resistivity is observed for the high pressure phase, as surprisingly, are two resistivity anomalies with opposite pressure dependences, while one of them could be a magnetic transition and the other originates from Fermi surface instability. Lastly, assessment of the total energies for hypothetical magnetic structures for high pressure CaMn₂Bi₂ indicates that ferrimagnetism is thermodynamically favored.

View Accepted Manuscript (DOE)

Research Organization:: Louisiana State Univ., Baton Rouge, LA (United States)

Sponsoring Organization:: Chinese Academy of Sciences (CAS); National Key R&D Program of China; National Natural Science Foundation of China; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012432

OSTI ID:: 1602041

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 14 Vol. 58; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (51)

ChemInform Abstract: Isolated ∞1[ZnPn2]4- Chains in the Zintl Phases Ba2ZnPn2 (Pn: As, Sb, Bi)-Synthesis, Structure, and Bonding. Saparov, Bayrammurad; Bobev, Svilen ChemInform, Vol. 41, Issue 34 https://doi.org/10.1002/chin.201034012	journal	July 2010
Environment-assisted quantum walks in photosynthetic energy transfer Mohseni, Masoud; Rebentrost, Patrick; Lloyd, Seth The Journal of Chemical Physics, Vol. 129, Issue 17 https://doi.org/10.1063/1.3002335	journal	November 2008
Topological quantum fluctuations and travelling wave amplifiers Peano, Vittorio; Houde, Martin; Marquardt, Florian arXiv https://doi.org/10.48550/arxiv.1604.04179	text	January 2016
Polyanionic Clusters and Networks of the Early p-Element Metals in the Solid State: Beyond the Zintl Boundary Corbett, John D. Angewandte Chemie International Edition, Vol. 39, Issue 4 https://doi.org/10.1002/(SICI)1521-3773(20000218)39:4<670::AID-ANIE670>3.0.CO;2-M	journal	February 2000
Zintl Phases as Thermoelectric Materials: Tuned Transport Properties of the Compounds CaxYb1-xZn2Sb2 Gascoin, F.; Ottensmann, S.; Stark, D. Advanced Functional Materials, Vol. 15, Issue 11 https://doi.org/10.1002/adfm.200500043	journal	November 2005
Realization of a Type-II Nodal-Line Semimetal in Mg ₃ Bi ₂ Chang, Tay-Rong; Pletikosic, Ivo; Kong, Tai Advanced Science, Vol. 6, Issue 4 https://doi.org/10.1002/advs.201800897	journal	November 2018
Endohedral Zintl Ions: Intermetalloid Clusters Fässler, Thomas F.; Hoffmann, Stephan D. Angewandte Chemie International Edition, Vol. 43, Issue 46 https://doi.org/10.1002/anie.200460427	journal	October 2004
A logarithmic equation of state Poirier, J. -P; Tarantola, A. Physics of the Earth and Planetary Interiors, Vol. 109, Issue 1-2 https://doi.org/10.1016/S0031-9201(98)00112-5	journal	November 1998
Quantum entanglement in condensed matter systems Laflorencie, Nicolas Physics Reports, Vol. 646 https://doi.org/10.1016/j.physrep.2016.06.008	journal	August 2016
High-Pressure Synthesis: A New Frontier in the Search for Next-Generation Intermetallic Compounds Walsh, James P. S.; Freedman, Danna E. Accounts of Chemical Research, Vol. 51, Issue 6 https://doi.org/10.1021/acs.accounts.8b00143	journal	May 2018
Coexistence of Spin-Canting, Metamagnetism, and Spin-Flop in a (4,4) Layered Manganese Azide Polymer Wang, Xin-Yi; Wang, Lu; Wang, Zhe-Ming Chemistry of Materials, Vol. 17, Issue 25 https://doi.org/10.1021/cm0521830	journal	November 2005
Synthesis, Structure, and Magnetic Properties of the Rare-Earth Zintl Compounds Eu ₁₄ MnPn ₁₁ and Eu ₁₄ InPn ₁₁ (Pn = Sb, Bi) Chan, Julia Y.; Wang, Mary E.; Rehr, Anette Chemistry of Materials, Vol. 9, Issue 10 https://doi.org/10.1021/cm970219l	journal	October 1997
Colossal Magnetoresistance in the Transition-Metal Zintl Compound Eu ₁₄ MnSb ₁₁ Chan, Julia Y.; Kauzlarich, Susan M.; Klavins, Peter Chemistry of Materials, Vol. 9, Issue 12 https://doi.org/10.1021/cm9704241	journal	December 1997
Isolated _∞ ¹ [ZnPn ₂ ] ⁴⁻ Chains in the Zintl Phases Ba ₂ ZnPn ₂ (Pn = As, Sb, Bi)—Synthesis, Structure, and Bonding Saparov, Bayrammurad; Bobev, Svilen Inorganic Chemistry, Vol. 49, Issue 11 https://doi.org/10.1021/ic100296x	journal	June 2010
The birth of topological insulators Moore, Joel E. Nature, Vol. 464, Issue 7286 https://doi.org/10.1038/nature08916	journal	March 2010
Spin liquids in frustrated magnets Balents, Leon Nature, Vol. 464, Issue 7286 https://doi.org/10.1038/nature08917	journal	March 2010
Re-emerging superconductivity at 48 kelvin in iron chalcogenides Sun, Liling; Chen, Xiao-Jia; Guo, Jing Nature, Vol. 483, Issue 7387 https://doi.org/10.1038/nature10813	journal	February 2012
Interplay of Dirac electrons and magnetism in CaMnBi2 and SrMnBi2 Zhang, Anmin; Liu, Changle; Yi, Changjiang Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13833	journal	December 2016
Pressure-induced superconductivity in the iron-based ladder material BaFe2S3 Takahashi, Hiroki; Sugimoto, Akira; Nambu, Yusuke Nature Materials, Vol. 14, Issue 10 https://doi.org/10.1038/nmat4351	journal	July 2015
Proximate Kitaev quantum spin liquid behaviour in a honeycomb magnet Banerjee, A.; Bridges, C. A.; Yan, J. -Q. Nature Materials, Vol. 15, Issue 7 https://doi.org/10.1038/nmat4604	journal	April 2016
New materials from high-pressure experiments McMillan, Paul F. Nature Materials, Vol. 1, Issue 1 https://doi.org/10.1038/nmat716	journal	September 2002
Photonic quantum simulators Aspuru-Guzik, Alán; Walther, Philip Nature Physics, Vol. 8, Issue 4 https://doi.org/10.1038/nphys2253	journal	April 2012
A quantum dipolar spin liquid Yao, N. Y.; Zaletel, M. P.; Stamper-Kurn, D. M. Nature Physics, Vol. 14, Issue 4 https://doi.org/10.1038/s41567-017-0030-7	journal	February 2018
Ferromagnetism in thin-film Cr-doped topological insulator Bi ₂ Se ₃ Haazen, P. P. J.; Laloë, J. -B.; Nummy, T. J. Applied Physics Letters, Vol. 100, Issue 8 https://doi.org/10.1063/1.3688043	journal	February 2012
Ultrathin two-dimensional superconductivity with strong spin–orbit coupling Nam, Hyoungdo; Chen, Hua; Liu, Tijiang Proceedings of the National Academy of Sciences, Vol. 113, Issue 38 https://doi.org/10.1073/pnas.1611967113	journal	September 2016
1T-TaS ₂ as a quantum spin liquid Law, K. T.; Lee, Patrick A. Proceedings of the National Academy of Sciences, Vol. 114, Issue 27 https://doi.org/10.1073/pnas.1706769114	journal	June 2017
High-pressure phases of III-V zinc-blende semiconductors Zhang, S. B.; Cohen, Marvin L. Physical Review B, Vol. 35, Issue 14 https://doi.org/10.1103/PhysRevB.35.7604	journal	May 1987
Magnetic-field-induced metal-insulator phenomena in Pr 1 − x Ca x Mn O 3 with controlled charge-ordering instability Tomioka, Y.; Asamitsu, A.; Kuwahara, H. Physical Review B, Vol. 53, Issue 4 https://doi.org/10.1103/PhysRevB.53.R1689	journal	January 1996
Antiferromagnetic Mott insulating state in single crystals of the honeycomb lattice material Na 2 IrO 3 Singh, Yogesh; Gegenwart, P. Physical Review B, Vol. 82, Issue 6 https://doi.org/10.1103/PhysRevB.82.064412	journal	August 2010
Magnetic and electronic properties of CaMn 2 Bi 2 : A possible hybridization gap semiconductor Gibson, Q. D.; Wu, H.; Liang, T. Physical Review B, Vol. 91, Issue 8 https://doi.org/10.1103/PhysRevB.91.085128	journal	February 2015
Magnetic order in α − RuCl 3 : A honeycomb-lattice quantum magnet with strong spin-orbit coupling Sears, J. A.; Songvilay, M.; Plumb, K. W. Physical Review B, Vol. 91, Issue 14 https://doi.org/10.1103/PhysRevB.91.144420	journal	April 2015
Realization of insulating state and superconductivity in the Rashba semiconductor BiTeCl Ying, Jian-Jun; Struzhkin, Viktor V.; Cao, Zi-Yu Physical Review B, Vol. 93, Issue 10 https://doi.org/10.1103/PhysRevB.93.100504	journal	March 2016
Optical investigation of the strong spin-orbit-coupled magnetic semimetal YbMnBi 2 Chaudhuri, Dipanjan; Cheng, Bing; Yaresko, Alexander Physical Review B, Vol. 96, Issue 7 https://doi.org/10.1103/PhysRevB.96.075151	journal	August 2017
Nonmonotonic and anisotropic magnetoresistance effect in antiferromagnet CaMn 2 Bi 2 Kawaguchi, N.; Urata, T.; Hatano, T. Physical Review B, Vol. 97, Issue 14 https://doi.org/10.1103/PhysRevB.97.140403	journal	April 2018
Pressure Induced Superconductivity in CaFe 2 As 2 Torikachvili, Milton S.; Bud’ko, Sergey L.; Ni, Ni Physical Review Letters, Vol. 101, Issue 5 https://doi.org/10.1103/PhysRevLett.101.057006	journal	July 2008
Superconductivity in Cu x Bi 2 Se 3 and its Implications for Pairing in the Undoped Topological Insulator Hor, Y. S.; Williams, A. J.; Checkelsky, J. G. Physical Review Letters, Vol. 104, Issue 5 https://doi.org/10.1103/PhysRevLett.104.057001	journal	February 2010
Disordered Ground State and Magnetic Field-Induced Long-Range Order in an S = 3 / 2 Antiferromagnetic Honeycomb Lattice Compound Bi 3 Mn 4 O 12 ( NO 3 ) Matsuda, M.; Azuma, M.; Tokunaga, M. Physical Review Letters, Vol. 105, Issue 18 https://doi.org/10.1103/PhysRevLett.105.187201	journal	October 2010
Anisotropic Dirac Fermions in a Bi Square Net of SrMnBi 2 Park, Joonbum; Lee, G.; Wolff-Fabris, F. Physical Review Letters, Vol. 107, Issue 12 https://doi.org/10.1103/PhysRevLett.107.126402	journal	September 2011
Emergent Magnetic Degeneracy in Iron Pnictides due to the Interplay between Spin-Orbit Coupling and Quantum Fluctuations Christensen, Morten H.; Orth, Peter P.; Andersen, Brian M. Physical Review Letters, Vol. 121, Issue 5 https://doi.org/10.1103/PhysRevLett.121.057001	journal	July 2018
Evidence for Superconductivity above 260 K in Lanthanum Superhydride at Megabar Pressures Somayazulu, Maddury; Ahart, Muhtar; Mishra, Ajay K. Physical Review Letters, Vol. 122, Issue 2 https://doi.org/10.1103/PhysRevLett.122.027001	journal	January 2019
Superconductivity at 93 K in a new mixed-phase Y-Ba-Cu-O compound system at ambient pressure Wu, M. K.; Ashburn, J. R.; Torng, C. J. Physical Review Letters, Vol. 58, Issue 9 https://doi.org/10.1103/PhysRevLett.58.908	journal	March 1987
Pressure-Induced Superconductivity in Quasi-2D CeRhIn 5 Hegger, H.; Petrovic, C.; Moshopoulou, E. G. Physical Review Letters, Vol. 84, Issue 21 https://doi.org/10.1103/PhysRevLett.84.4986	journal	May 2000
Topological Quantum Fluctuations and Traveling Wave Amplifiers Peano, Vittorio; Houde, Martin; Marquardt, Florian Physical Review X, Vol. 6, Issue 4 https://doi.org/10.1103/PhysRevX.6.041026	journal	November 2016
Quantum spin liquid states Zhou, Yi; Kanoda, Kazushi; Ng, Tai-Kai Reviews of Modern Physics, Vol. 89, Issue 2 https://doi.org/10.1103/RevModPhys.89.025003	journal	April 2017
Superconductivity in Boron Eremets, M. I. Science, Vol. 293, Issue 5528 https://doi.org/10.1126/science.1062286	journal	July 2001
Superconductivity in Dense Lithium Struzhkin, V. V. Science, Vol. 298, Issue 5596 https://doi.org/10.1126/science.1078535	journal	October 2002
Quantum Oscillations and Hall Anomaly of Surface States in the Topological Insulator Bi₂Te₃ Qu, D.-X.; Hor, Y. S.; Xiong, J. Science, Vol. 329, Issue 5993, p. 821-824 https://doi.org/10.1126/science.1189792	journal	July 2010
Thousandfold Change in Resistivity in Magnetoresistive La-Ca-Mn-O Films Jin, S.; Tiefel, T. H.; McCormack, M. Science, Vol. 264, Issue 5157 https://doi.org/10.1126/science.264.5157.413	journal	April 1994
Colossal Magnetoresistance Without Mn3+/Mn4+ Double Exchange in the Stoichiometric Pyrochlore Tl2Mn2O7 Subramanian, M. A.; Toby, B. H.; Ramirez, A. P. Science, Vol. 273, Issue 5271 https://doi.org/10.1126/science.273.5271.81	journal	July 1996
High-Pressure Synthesis, Characterization, and Tuning of Solid State Materials Badding, J. V. Annual Review of Materials Science, Vol. 28, Issue 1 https://doi.org/10.1146/annurev.matsci.28.1.631	journal	August 1998
Neue intermetallische Verbindungen im anti-Ce2O2S-Strukturtyp. / New Intermetallic Compounds in the anti-Ce2O2S-Structure Type Cordier, Gerhard; Schäfer, Herbert Zeitschrift für Naturforschung B, Vol. 31, Issue 11 https://doi.org/10.1515/znb-1976-1105	journal	November 1976

Figures / Tables (11)

Similar Records

Incommensurate Spiral Spin Order in CaMn₂Bi₂ Observed via High-Pressure Neutron Diffraction

Journal Article · Mon Nov 27 19:00:00 EST 2023 · Inorganic Chemistry · OSTI ID:2301631

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
Crystal structure
Materials
Phase transitions
Quantum mechanics
Transition metals

CSD 1916930: Experimental Crystal Structure Determination Xin, Gui,; J., Finkelstein, Gregory; Keyu, Chen, https://doi.org/10.25505/fiz.icsd.cc22bqgm The current record is supplemented by this dataset	dataset	January 2019
CSD 1917383: Experimental Crystal Structure Determination Xin, Gui,; J., Finkelstein, Gregory; Keyu, Chen, https://doi.org/10.25505/fiz.icsd.cc22c62r The current record is supplemented by this dataset	dataset	January 2019
CSD 1917417: Experimental Crystal Structure Determination Xin, Gui,; J., Finkelstein, Gregory; Keyu, Chen, https://doi.org/10.25505/fiz.icsd.cc22c75w The current record is supplemented by this dataset	dataset	January 2019