Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties

Cadiau, Amandine; Xie, Lilia S.; Kolobov, Nikita; Shkurenko, Aleksander; Qureshi, Muhammad; Tchalala, Mohamed R.; Park, Sarah S.; Bavykina, Anastasiya; Eddaoudi, Mohamed; Dincă, Mircea; Hendon, Christopher H.; Gascon, Jorge

doi:10.1021/acs.chemmater.9b02462

Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties

Journal Article · Tue Dec 17 23:00:00 EST 2019 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.9b02462· OSTI ID:1601980

Cadiau, Amandine ^[1]; Xie, Lilia S. ^[2]; Kolobov, Nikita ^[3]; ^[3]; Qureshi, Muhammad ^[4]; Tchalala, Mohamed R. ^[3]; Park, Sarah S. ^[2]; Bavykina, Anastasiya ^[3]; ^[3]; ^[2]; ^[5]; ^[3]

King Abdullah Univ. of Science and Technology (KAUST), Thuwal, Jeddah (Saudi Arabia); MIT
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
King Abdullah Univ. of Science and Technology (KAUST), Thuwal, Jeddah (Saudi Arabia)
Univ. of Montpellier (France); French National Centre for Scientific Research (CNRS), Montpellier (France); Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM) (France)
Univ. of Oregon, Eugene, OR (United States)

Nowadays, zirconium metal–organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. In this work, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV–vis spectroscopy. Here, their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.

View Accepted Manuscript (DOE)

Research Organization:: Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); P.I.A “MOPGA”; KAUST Office of Sponsored Research

Grant/Contract Number:: SC0018235

OSTI ID:: 1601980

Alternate ID(s):: OSTI ID: 1769037

Journal Information:: Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 1 Vol. 32; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties

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