Photostimulated desorption of CO from geologic calcite following 193-nm irradiation

Beck, Kenneth M.; Taylor, David P.; Hess, Wayne P.

doi:10.1103/PhysRevB.55.13253

Photostimulated desorption of CO from geologic calcite following 193-nm irradiation

Journal Article · Thu May 15 04:00:00 EDT 1997 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PhysRevB.55.13253· OSTI ID:1601797

Beck, Kenneth M. ^[1]; Taylor, David P. ^[2]; Hess, Wayne P. ^[1]

BATTELLE (PACIFIC NW LAB)
ASSOC WESTERN UNIVERSITY

We report the results of a photostimulated desorption study of neutral CO product from geologic calcite using very low fluence 193 nm excimer laser radiation.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1601797

Report Number(s):: PNNL-SA-28238

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Journal Name: Physical Review. B, Condensed Matter and Materials Physics Journal Issue: 19 Vol. 55

Country of Publication:: United States

Language:: English

References (57)

Desorption from Metal Surfaces by Low‐Energy Electrons Menzel, Dietrich; Gomer, Robert The Journal of Chemical Physics, Vol. 41, Issue 11 https://doi.org/10.1063/1.1725730	journal	December 1964
Excited-atom production by electron and ion bombardment of alkali halides Walkup, R. E. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 5, Issue 5 https://doi.org/10.1116/1.583628	journal	September 1987
Trapping Centers in Thermoluminescent Calcite Medlin, W. L. Physical Review, Vol. 135, Issue 6A https://doi.org/10.1103/PhysRev.135.A1770	journal	September 1964
Ion Desorption by Core-Hole Auger Decay Knotek, M. L.; Feibelman, Peter J. Physical Review Letters, Vol. 40, Issue 14 https://doi.org/10.1103/PhysRevLett.40.964	journal	April 1978
Drift Tube Studies of Atomic Clusters Jarrold, Martin F. The Journal of Physical Chemistry, Vol. 99, Issue 1 https://doi.org/10.1021/j100001a004	journal	January 1995
The excitonic mechanism of Na-atom desorption from the (100)NaCl surface Puchin, V. E.; Shluger, A. L.; Itoh, N. Journal of Physics: Condensed Matter, Vol. 7, Issue 10 https://doi.org/10.1088/0953-8984/7/10/005	journal	March 1995
Model of self-trapped excitons in alkali halides Puchin, V. E.; Shluger, A. L.; Tanimura, K. Physical Review B, Vol. 47, Issue 11 https://doi.org/10.1103/PhysRevB.47.6226	journal	March 1993
Multiphoton excitation spectroscopy of the B ¹ Σ ⁺ and C ¹ Σ ⁺ Rydberg states of CO Tjossem, Paul J. H.; Smyth, Kermit C. The Journal of Chemical Physics, Vol. 91, Issue 4 https://doi.org/10.1063/1.457064	journal	August 1989
HD scattering from Pt(111): Rotational excitation probabilities Cowin, James P.; Yu, Chein‐Fan; Sibener, Steven J. The Journal of Chemical Physics, Vol. 79, Issue 7 https://doi.org/10.1063/1.446208	journal	October 1983
Laser-Induced Calcite-Aragonite Transition Alam, Mansoor; DebRoy, Tarasankar; Roy, Rustum Journal of the American Ceramic Society, Vol. 73, Issue 3 https://doi.org/10.1111/j.1151-2916.1990.tb06581.x	journal	March 1990
Dynamics of gas-surface interactions: Thermal desorption of Ar and Xe from platinum Tully, John C. Surface Science, Vol. 111, Issue 3 https://doi.org/10.1016/0039-6028(81)90402-7	journal	November 1981
Positive Ion Emission from Excimer Laser Excited MgO Surfaces Dickinson, J. T.; Langford, S. C.; Shin, J. J. Physical Review Letters, Vol. 73, Issue 19 https://doi.org/10.1103/PhysRevLett.73.2630	journal	November 1994
A new model of TL in carbonates Calderon, T.; Aguilar, M.; Coy-Ill, R. Thermochimica Acta, Vol. 135 https://doi.org/10.1016/0040-6031(88)87388-X	journal	October 1988
Relationship between blue color and radiation damage in calcite Calderon, T.; Aguilar, M.; Coy-Yll, R. Radiation Effects, Vol. 76, Issue 5 https://doi.org/10.1080/01422448308209660	journal	January 1983
Dynamics of gas–surface interactions: Scattering and desorption of NO from Ag(111) and Pt(111) Muhlhausen, Carl W.; Williams, Leah Ruby; Tully, John C. The Journal of Chemical Physics, Vol. 83, Issue 5 https://doi.org/10.1063/1.449253	journal	September 1985
Laser-induced-fluorescence studies of no scattering from Ag(111) Kleyn, A. W.; Luntz, A. C.; Auerbach, D. J. Surface Science, Vol. 117, Issue 1-3 https://doi.org/10.1016/0039-6028(82)90482-4	journal	May 1982
Multiphoton-induced desorption of positive ions from barium fluoride Matthias, E. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 5, Issue 5 https://doi.org/10.1116/1.583627	journal	September 1987
Positive-ion production by electron bombardment of alkali halides Walkup, R. E.; Avouris, Ph.; Ghosh, A. P. Physical Review B, Vol. 36, Issue 8 https://doi.org/10.1103/PhysRevB.36.4577	journal	September 1987
Activators of photoluminescence in calcite: evidence from high-resolution, laser-excited luminescence spectroscopy Pedone, Vicki A.; Cercone, Karen Rose; Burruss, R. C. Chemical Geology, Vol. 88, Issue 1-2 https://doi.org/10.1016/0009-2541(90)90112-K	journal	October 1990
Fluorescence of Mn2+ in CaCO3 Aguilar, G. M.; Osendi, M. I. Journal of Luminescence, Vol. 27, Issue 4 https://doi.org/10.1016/0022-2313(82)90037-0	journal	December 1982
Electron Spin Resonance Absorption Spectrum of Y ³⁺ ‐Stabilized CO ₃ ³⁻ Molecule–Ion in Single‐Crystal Calcite Marshall, S. A.; McMillan, J. A.; Serway, R. A. The Journal of Chemical Physics, Vol. 48, Issue 11 https://doi.org/10.1063/1.1668185	journal	June 1968
Internal state distributions of CO from HNCO photodissociation Spiglanin, Thomas A.; Perry, Robert A.; Chandler, David W. The Journal of Chemical Physics, Vol. 87, Issue 3 https://doi.org/10.1063/1.453215	journal	August 1987
Anisotropy of Color Centers in Calcite Kolbe, W. F.; Smakula, A. Physical Review, Vol. 124, Issue 6 https://doi.org/10.1103/PhysRev.124.1754	journal	December 1961
Measurement of CO pressures in the ultrahigh vacuum regime using resonance‐enhanced multiphoton‐ionization time‐of‐flight mass spectroscopy Looney, J. Patrick; Harrington, Joel E.; Smyth, Kermit C. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 11, Issue 6 https://doi.org/10.1116/1.578306	journal	November 1993
Observation of photon-stimulated desorption following valence-band excitation of alkali halides Bunton, P. H.; Haglund, R. F.; Liu, D. Physical Review B, Vol. 45, Issue 9 https://doi.org/10.1103/PhysRevB.45.4566	journal	March 1992
Multiphoton induced fluorescence and ionization of carbon monoxide ( B ¹ Σ ⁺ ) Loge, G. W.; Tiee, J. J.; Wampler, F. B. The Journal of Chemical Physics, Vol. 79, Issue 1 https://doi.org/10.1063/1.445556	journal	July 1983
Photon- and electron-stimulated desorption of excited alkali-metal atoms from alkali halide surfaces Liu, D.; Seifert, N.; McClure, D. J. Physical Review B, Vol. 47, Issue 3 https://doi.org/10.1103/PhysRevB.47.1553	journal	January 1993
CO2 emission accompanying the fracture of calcite Dickinson, J. T.; Jensen, L. C.; Langford, S. C. Physics and Chemistry of Minerals, Vol. 18, Issue 5 https://doi.org/10.1007/BF00200189	journal	December 1991
Interaction of wide band gap single crystals with 248 nm excimer laser radiation. IV. Positive ion emission from MgO and NaNO ₃ Ermer, D. R.; Shin, J. ‐J.; Langford, S. C. Journal of Applied Physics, Vol. 80, Issue 11 https://doi.org/10.1063/1.363665	journal	December 1996
Bound level resonances in rotationally inelastic HD/Pt (111) surface scattering Cowin, James P.; Yu, Chien‐Fan; Sibener, Steven J. The Journal of Chemical Physics, Vol. 75, Issue 2 https://doi.org/10.1063/1.442067	journal	July 1981
Laser-induced fluorescence of CO+ and the CO a3Πi, state produced by multiphoton absorption in a supersonic jet Dimauro, L. F.; Miller, Terry A. Chemical Physics Letters, Vol. 138, Issue 2-3 https://doi.org/10.1016/0009-2614(87)80364-0	journal	July 1987
Emission of Na atoms from undamaged and slightly damaged NaCl (100) surfaces by electronic excitation Kubo, Tomohiro; Okano, Akiko; Kanasaki, Jyun’ichi Physical Review B, Vol. 49, Issue 7 https://doi.org/10.1103/PhysRevB.49.4931	journal	February 1994
Studies of the calcite cleavage surface for comparison with calculation Baer, D. R.; Blanchard, David L. Applied Surface Science, Vol. 72, Issue 4 https://doi.org/10.1016/0169-4332(93)90365-I	journal	December 1993
On some luminescent and optical properties of synthetic calcite single crystals Lapraz, D.; Iacconi, P. Physica Status Solidi (a), Vol. 36, Issue 2 https://doi.org/10.1002/pssa.2210360221	journal	August 1976
Reinterpretation of electron-stimulated desorption data from chemisorption systems Feibelman, Peter J.; Knotek, M. L. Physical Review B, Vol. 18, Issue 12 https://doi.org/10.1103/PhysRevB.18.6531	journal	December 1978
On the effect of Knudsen-layer formation on studies of vaporization, sputtering, and desorption Kelly, Roger; Dreyfus, R. W. Surface Science, Vol. 198, Issue 1-2 https://doi.org/10.1016/0039-6028(88)90483-9	journal	January 1988
Delay times in the sputtering of atoms from alkali-halide crystals during low-energy electron bombardment Overeijnder, H.; Tol, R. R.; De Vries, A. E. Surface Science, Vol. 90, Issue 2 https://doi.org/10.1016/0039-6028(79)90343-1	journal	December 1979
Dissolution kinetics at the calcite-water interface Liang, Yong; Baer, Donald R.; McCoy, James M. Geochimica et Cosmochimica Acta, Vol. 60, Issue 23 https://doi.org/10.1016/S0016-7037(96)00337-7	journal	December 1996
Interaction of slow Electrons with Chemisorbed Oxygen Redhead, P. A. Canadian Journal of Physics, Vol. 42, Issue 5 https://doi.org/10.1139/p64-083	journal	May 1964
Thermal state distributions deduced from (2 + 1) resonance enhanced multiphoton ionization of CO Beck, Kenneth M.; German, Kristine A. H.; Hess, Wayne P. Chemical Physics Letters, Vol. 256, Issue 3 https://doi.org/10.1016/0009-2614(96)00447-2	journal	June 1996
Excited-Atom Production by Electron Bombardment of Alkali Halides Walkup, R. E.; Avouris, Ph.; Ghosh, A. P. Physical Review Letters, Vol. 57, Issue 17 https://doi.org/10.1103/PhysRevLett.57.2227	journal	October 1986
Subthermal photoproduct surface desorption distributions arising from excimer laser excitation of adsorbed trimethylaluminum Higashi, G. S. The Journal of Chemical Physics, Vol. 88, Issue 1 https://doi.org/10.1063/1.454618	journal	January 1988
Energy distributions of atoms sputtered from alkali halides by 540 eV electrons Overeijnder, H.; Szymonski, M.; Haring, A. Radiation Effects, Vol. 36, Issue 1-2 https://doi.org/10.1080/00337577808233172	journal	January 1978
Direct inelastic scattering of nitric oxide from clean Ag(111): Rotational and fine structure distributions Kubiak, G. D.; Hurst, J. E.; Rennagel, H. G. The Journal of Chemical Physics, Vol. 79, Issue 10 https://doi.org/10.1063/1.445643	journal	November 1983
Neutral atom and molecule emission accompanying 248-nm laser irradiation of single crystal NaNO3 Webb, R. L.; Langford, S. C.; Dickinson, J. T. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 103, Issue 3 https://doi.org/10.1016/0168-583X(95)00611-7	journal	November 1995
Color center growth curves in calcite Medlin, W. L. Journal of Physics and Chemistry of Solids, Vol. 28, Issue 9 https://doi.org/10.1016/0022-3697(67)90149-7	journal	September 1967
An XPS study of ion-induced dissociation on metal carbonate surfaces Christie, Ab; Sutherland, I.; Walls, Jm Vacuum, Vol. 31, Issue 10-12 https://doi.org/10.1016/0042-207X(81)90051-8	journal	October 1981
Electron sputtering of alkali halides a study of its dependence on the beam energy and target temperature Overeijnder, H.; Szymoński, M.; Haring, A. Radiation Effects, Vol. 38, Issue 1-2 https://doi.org/10.1080/00337577808233204	journal	January 1978
Multiphonon dephasing of the 1086- cm − 1 mode in calcite Delfyett, P. J.; Dorsinville, R.; Alfano, R. R. Physical Review B, Vol. 39, Issue 6 https://doi.org/10.1103/PhysRevB.39.3845	journal	February 1989
Motional Effects in the Electron Spin Resonance Absorption Spectrum of CO ₂ ^– Molecule‐Ions in Single‐Crystal Calcite McMillan, J. A.; Marshall, S. A. The Journal of Chemical Physics, Vol. 48, Issue 1 https://doi.org/10.1063/1.1667947	journal	January 1968
Reinvestigation of the vacuum ultraviolet spectrum of CO and isotopic species: The B1Σ+ ↔ X1Σ+ transition Eidelsberg, M.; Roncin, J. -Y.; Le Floch, A. Journal of Molecular Spectroscopy, Vol. 121, Issue 2 https://doi.org/10.1016/0022-2852(87)90055-5	journal	February 1987
Theoretical simulation of V _K -centre migration in KCl. I. A quantum-chemical study Shluger, A. L.; Kantorovich, L. N.; Heifets, E. N. Journal of Physics: Condensed Matter, Vol. 4, Issue 36 https://doi.org/10.1088/0953-8984/4/36/015	journal	September 1992
Theoretical study of Na-atom emission from NaCl (100) surfaces Puchin, Vladimir; Shluger, Alexander; Nakai, Yasuo Physical Review B, Vol. 49, Issue 16 https://doi.org/10.1103/PhysRevB.49.11364	journal	April 1994
Phonon sudden theory of Debye–Waller attenuation. Temperature dependence of rotational energy transfer in molecule/surface scattering Schinke, R.; Gerber, R. B. The Journal of Chemical Physics, Vol. 82, Issue 3 https://doi.org/10.1063/1.448432	journal	February 1985
Thermoluminescence from natural calcites Calderon, T.; Aguilar, M.; Jaque, F. Journal of Physics C: Solid State Physics, Vol. 17, Issue 11 https://doi.org/10.1088/0022-3719/17/11/021	journal	April 1984
Laser-induced emission of neutral atoms and molecules from electron-irradiated NaNO 3 Dickinson, J. T.; Shin, J. J.; Langford, S. C. Applied Surface Science, Vol. 96-98 https://doi.org/10.1016/0169-4332(95)00438-6	journal	April 1996
Wavelength dependence of laser‐induced sputtering from the (111) surface of BaF ₂ Reif, J.; Fallgren, H.; Cooke, W. E. Applied Physics Letters, Vol. 49, Issue 13 https://doi.org/10.1063/1.97542	journal	September 1986

Similar Records

Photostimulated desorption of CO from geologic calcite following 193-nm irradiation

Journal Article · Thu May 01 00:00:00 EDT 1997 · Physical Review, B: Condensed Matter · OSTI ID:565337

Quantum-State Resolved Products Via Vacuum Ultraviolet Photostimulated Desorption From Geologic Calcite

Journal Article · Fri Oct 31 23:00:00 EST 1997 · Applied Surface Science · OSTI ID:15001249

Molecular desorption from ionic molecular crystals following resonant UV excitation

Conference · Tue Dec 30 23:00:00 EST 1997 · OSTI ID:560054

Related Subjects

calcite
oxide
photostimulated
desorption
excimer laser radiation

Photostimulated desorption of CO from geologic calcite following 193-nm irradiation

Citation Formats

References (57)

Similar Records

Related Subjects