Vertical Strain-Driven Antiferromagnetic to Ferromagnetic Phase Transition in EuTiO 3 Nanocomposite Thin Films

Lin, Yisong; Choi, Eun-Mi; Lu, Ping; Sun, Xing; Wu, Rui; Yun, Chao; Zhu, Bonan; Wang, Haiyan; Li, Weiwei; Maity, Tuhin; MacManus-Driscoll, Judith

doi:10.1021/acsami.9b17887

Title: Vertical Strain-Driven Antiferromagnetic to Ferromagnetic Phase Transition in EuTiO ₃ Nanocomposite Thin Films

Journal Article · Thu Jan 23 00:00:00 EST 2020 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.9b17887· OSTI ID:1601265

Lin, Yisong ^[1];

^[1]; Lu, Ping ^[2]; Sun, Xing ^[3];

^[1];

^[3];

^[1];

^[1]; MacManus-Driscoll, Judith ^[1]

Univ. of Cambridge (United Kingdom). Dept. of Materials Science & Metallurgy
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Purdue Univ., West Lafayette, IN (United States)

Three-dimensional (3D) strain induced in self-assembled vertically aligned nanocomposite (VAN) epitaxial films provides an unrivaled method to induce very large strains in thin films. Here, by growing VAN films of EuTiO₃ (ETO)–Eu₂O₃ (EO) with different EO fractions, the vertical strain was systematically increased in ETO, up to 3.15%, and the Eu–Ti–Eu bond angle along $$\langle$$111$$\rangle$$ decreased by up to 1°, leading to a weakening of the antiferromagnetic interactions and switching from antiferromagnetic to ferromagnetic behavior. Our work has shown for the first time that Eu–Ti–Eu superexchange interactions play a key role in determining the magnetic ground state of ETO. Broadly, our work serves as an exemplar to show that multifunctionalities in strong spin–lattice coupling perovskite oxides can be uniquely tuned at the atomic scale using simple VAN structures.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1601265

Report Number(s):: SAND-2020-1523J; 683578

Journal Information:: ACS Applied Materials and Interfaces, Vol. 12, Issue 7; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 9 works

Citation information provided by
Web of Science

References (55)

Bulk superconductivity at 91 K in single-phase oxygen-deficient perovskite ${Ba}_{2}$ ${YCu}_{3}$ $O_{9 - δ}$ Cava, R. J.; Batlogg, B.; van Dover, R. B. Physical Review Letters, Vol. 58, Issue 16 https://doi.org/10.1103/PhysRevLett.58.1676	journal	April 1987
Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures Wang, J.; Neaton, J. B.; Zheng, H. Science, Vol. 299, Issue 5613, p. 1719-1722 https://doi.org/10.1126/science.1080615	journal	March 2003
Thousandfold Change in Resistivity in Magnetoresistive La-Ca-Mn-O Films Jin, S.; Tiefel, T. H.; McCormack, M. Science, Vol. 264, Issue 5157 https://doi.org/10.1126/science.264.5157.413	journal	April 1994
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH₃NH₃PbI₃ Xing, G.; Mathews, N.; Sun, S. Science, Vol. 342, Issue 6156, p. 344-347 https://doi.org/10.1126/science.1243167	journal	October 2013
Structure dependence of the ferromagnetic transition temperature in rhombohedral ${La}_{1 - x}$ $A_{x}$ ${MnO}_{3}$ ( A =Na, K, Rb, and Sr) Itoh, Mitsuru; Shimura, Tetsuo; Yu, Jian-Ding Physical Review B, Vol. 52, Issue 17 https://doi.org/10.1103/PhysRevB.52.12522	journal	November 1995
Doped LaGaO3 Perovskite Type Oxide as a New Oxide Ionic Conductor Ishihara, Tatsumi; Matsuda, Hideaki; Takita, Yusaku Journal of the American Chemical Society, Vol. 116, Issue 9 https://doi.org/10.1021/ja00088a016	journal	May 1994
Structural effects on the magnetic and transport properties of perovskite $A_{1 - x} A_{x}^{'} {MnO}_{3}$ ( $x = 0.25,$ 0.30) Radaelli, P. G.; Iannone, G.; Marezio, M. Physical Review B, Vol. 56, Issue 13 https://doi.org/10.1103/PhysRevB.56.8265	journal	October 1997
Percolative phase separation underlies colossal magnetoresistance in mixed-valent manganites Uehara, M.; Mori, S.; Chen, C. H. Nature, Vol. 399, Issue 6736 https://doi.org/10.1038/21142	journal	June 1999
Room-temperature ferroelectricity in strained SrTiO₃ Haeni, J. H.; Irvin, P.; Chang, W. Nature, Vol. 430, Issue 7001, p. 758-761 https://doi.org/10.1038/nature02773	journal	August 2004
Enhancement of Ferroelectricity in Strained BaTiO₃ Thin Films Choi, K. J.; Biegalski, M.; Li, Y. L. Science, Vol. 306, Issue 5698, p. 1005-1009 https://doi.org/10.1126/science.1103218	journal	November 2004
Impact of misfit dislocations on the polarization instability of epitaxial nanostructured ferroelectric perovskites Chu, Ming-Wen; Szafraniak, Izabela; Scholz, Roland Nature Materials, Vol. 3, Issue 2 https://doi.org/10.1038/nmat1057	journal	January 2004
Strain Tuning of Ferroelectric Thin Films Schlom, Darrell G.; Chen, Long-Qing; Eom, Chang-Beom Annual Review of Materials Research, Vol. 37, Issue 1 https://doi.org/10.1146/annurev.matsci.37.061206.113016	journal	August 2007
Elastic strain engineering of ferroic oxides Schlom, Darrell G.; Chen, Long-Qing; Fennie, Craig J. MRS Bulletin, Vol. 39, Issue 2 https://doi.org/10.1557/mrs.2014.1	journal	February 2014
Tensile-Strain-Dependent Spin States in Epitaxial ${LaCoO}_{3}$ Thin Films Yokoyama, Y.; Yamasaki, Y.; Taguchi, M. Physical Review Letters, Vol. 120, Issue 20 https://doi.org/10.1103/PhysRevLett.120.206402	journal	May 2018
Pressure dependence of the magnetic transition temperature for ferromagnetic SrRuO3 Shikano, Masahiro; Huang, Tong-Kai; Inaguma, Yoshiyuki Solid State Communications, Vol. 90, Issue 2 https://doi.org/10.1016/0038-1098(94)90942-3	journal	April 1994
Water electrolysis on La1−xSrxCoO3−δ perovskite electrocatalysts Mefford, J. Tyler; Rong, Xi; Abakumov, Artem M. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11053	journal	March 2016
Mixed-valence manganites Coey, J. M. D.; Viret, M.; von Molnár, S. Advances in Physics, Vol. 48, Issue 2 https://doi.org/10.1080/000187399243455	journal	March 1999
Coupling between magnetism and dielectric properties in quantum paraelectric ${EuTiO}_{3}$ Katsufuji, T.; Takagi, H. Physical Review B, Vol. 64, Issue 5 https://doi.org/10.1103/PhysRevB.64.054415	journal	July 2001
A strong ferroelectric ferromagnet created by means of spin–lattice coupling Lee, June Hyuk; Fang, Lei; Vlahos, Eftihia Nature, Vol. 466, Issue 7309 https://doi.org/10.1038/nature09331	journal	August 2010
Revival of the magnetoelectric effect Fiebig, Manfred Journal of Physics D: Applied Physics, Vol. 38, Issue 8 https://doi.org/10.1088/0022-3727/38/8/R01	journal	April 2005
Towards a magnetoelectric memory Bibes, Manuel; Barthélémy, Agnès Nature Materials, Vol. 7, Issue 6 https://doi.org/10.1038/nmat2189	journal	June 2008
Recent Progress in Multiferroic Magnetoelectric Composites: from Bulk to Thin Films Ma, Jing; Hu, Jiamian; Li, Zheng Advanced Materials, Vol. 23, Issue 9 https://doi.org/10.1002/adma.201003636	journal	February 2011
Origin of giant spin-lattice coupling and the suppression of ferroelectricity in EuTiO $_{3}$ from first principles Birol, Turan; Fennie, Craig J. Physical Review B, Vol. 88, Issue 9 https://doi.org/10.1103/PhysRevB.88.094103	journal	September 2013
Magnetic inhomogeneity in a multiferroic EuTiO $_{3}$ thin film Geng, Yanan; Lee, J. H.; Schlom, D. G. Physical Review B, Vol. 87, Issue 12 https://doi.org/10.1103/PhysRevB.87.121109	journal	March 2013
Ferromagnetism induced by lattice volume expansion and amorphization in EuTiO ₃ thin films Tanaka, Katsuhisa; Fujita, Koji; Maruyama, Yuya Journal of Materials Research, Vol. 28, Issue 8 https://doi.org/10.1557/jmr.2013.60	journal	April 2013
Reversible control of magnetic interactions by electric field in a single-phase material Ryan, P. J.; Kim, J-W; Birol, T. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2329	journal	January 2013
Antiferromagnetic superexchange via $3 d$ states of titanium in EuTiO $_{3}$ as seen from hybrid Hartree-Fock density functional calculations Akamatsu, Hirofumi; Kumagai, Yu; Oba, Fumiyasu Physical Review B, Vol. 83, Issue 21 https://doi.org/10.1103/PhysRevB.83.214421	journal	June 2011
Crystal and Electronic Structure and Magnetic Properties of Divalent Europium Perovskite Oxides Eu M O ₃ ( M = Ti, Zr, and Hf): Experimental and First-Principles Approaches Akamatsu, Hirofumi; Fujita, Koji; Hayashi, Hiroyuki Inorganic Chemistry, Vol. 51, Issue 8 https://doi.org/10.1021/ic2024567	journal	April 2012
Strong Spin-Lattice Coupling Through Oxygen Octahedral Rotation in Divalent Europium Perovskites Akamatsu, Hirofumi; Kumagai, Yu; Oba, Fumiyasu Advanced Functional Materials, Vol. 23, Issue 15 https://doi.org/10.1002/adfm.201202477	journal	November 2012
Antiferromagnetism. Theory of Superexchange Interaction Anderson, P. W. Physical Review, Vol. 79, Issue 2 https://doi.org/10.1103/PhysRev.79.350	journal	July 1950
Theory of the Role of Covalence in the Perovskite-Type Manganites $[La, M (II)] Mn O_{3}$ Goodenough, John B. Physical Review, Vol. 100, Issue 2 https://doi.org/10.1103/PhysRev.100.564	journal	October 1955
Superexchange interaction and symmetry properties of electron orbitals Kanamori, Junjiro Journal of Physics and Chemistry of Solids, Vol. 10, Issue 2-3 https://doi.org/10.1016/0022-3697(59)90061-7	journal	July 1959
Structural phase transitions and stress accommodation in $({La}_{0.67} {Ca}_{0.33} {MnO}_{3})_{1 - x} : (MgO)_{x}$ composite films Lebedev, O. I.; Verbeeck, J.; Van Tendeloo, G. Physical Review B, Vol. 66, Issue 10 https://doi.org/10.1103/PhysRevB.66.104421	journal	September 2002
Multiferroic BaTiO3-CoFe2O4 Nanostructures Zheng, H. Science, Vol. 303, Issue 5658 https://doi.org/10.1126/science.1094207	journal	January 2004
Strain control and spontaneous phase ordering in vertical nanocomposite heteroepitaxial thin films MacManus-Driscoll, Judith L.; Zerrer, Patrick; Wang, Haiyan Nature Materials, Vol. 7, Issue 4 https://doi.org/10.1038/nmat2124	journal	March 2008
A New Material for High-Temperature Lead-Free Actuators Kursumovic, Ahmed; Defay, Emmanuel; Lee, Oon Jew Advanced Functional Materials, Vol. 23, Issue 47 https://doi.org/10.1002/adfm.201300899	journal	June 2013
New strain states and radical property tuning of metal oxides using a nanocomposite thin film approach MacManus-Driscoll, Judith; Suwardi, Ady; Kursumovic, Ahmed APL Materials, Vol. 3, Issue 6 https://doi.org/10.1063/1.4919059	journal	June 2015
Strain Tuning and Strong Enhancement of Ionic Conductivity in SrZrO ₃ -RE ₂ O ₃ (RE = Sm, Eu, Gd, Dy, and Er) Nanocomposite Films Lee, Shinbuhm; Zhang, Wenrui; Khatkhatay, Fauzia Advanced Functional Materials, Vol. 25, Issue 27 https://doi.org/10.1002/adfm.201404420	journal	June 2015
Composite epitaxial thin films: A new platform for tuning, probing, and exploiting mesoscale oxides MacManus-Driscoll, J. L.; Suwardi, A.; Wang, H. MRS Bulletin, Vol. 40, Issue 11 https://doi.org/10.1557/mrs.2015.258	journal	November 2015
X‐Ray Diffractometry of Low‐Temperature Phase Transformations in Strontium Titanate Lytle, Farrel W. Journal of Applied Physics, Vol. 35, Issue 7 https://doi.org/10.1063/1.1702820	journal	July 1964
Relationship between tunnel magnetoresistance and magnetic layer structure in EuO-based tunnel junctions investigated using polarized neutron reflectivity Watson, S. M.; Santos, T. S.; Borchers, J. A. Journal of Applied Physics, Vol. 103, Issue 7 https://doi.org/10.1063/1.2837873	journal	April 2008
Elastic Modulus-Porosity Relation in Polycrystalline Rare-Earth Oxides Phani, K. K.; Niyogi, S. K. Journal of the American Ceramic Society, Vol. 70, Issue 12 https://doi.org/10.1111/j.1151-2916.1987.tb04920.x	journal	December 1987
Lattice instabilities in bulk EuTiO $_{3}$ Bessas, D.; Rushchanskii, K. Z.; Kachlik, M. Physical Review B, Vol. 88, Issue 14 https://doi.org/10.1103/PhysRevB.88.144308	journal	October 2013
Anisotropic exchange interaction between nonmagnetic europium cations in Eu $_{2}$ O $_{3}$ Concas, G.; Dewhurst, J. K.; Sanna, A. Physical Review B, Vol. 84, Issue 1 https://doi.org/10.1103/PhysRevB.84.014427	journal	July 2011
Nanoscale strain-induced pair suppression as a vortex-pinning mechanism in high-temperature superconductors Llordés, A.; Palau, A.; Gázquez, J. Nature Materials, Vol. 11, Issue 4 https://doi.org/10.1038/nmat3247	journal	February 2012
Thick lead-free ferroelectric films with high Curie temperatures through nanocomposite-induced strain Harrington, Sophie A.; Zhai, Junyi; Denev, Sava Nature Nanotechnology, Vol. 6, Issue 8 https://doi.org/10.1038/nnano.2011.98	journal	July 2011
Synthesis and Unique Photoluminescence Properties of Eu ₂ Ti ₂ O ₇ and Eu ₂ TiO ₅ Orihashi, Takuya; Nakamura, Toshihiro; Adachi, Sadao Journal of the American Ceramic Society, Vol. 99, Issue 9 https://doi.org/10.1111/jace.14318	journal	May 2016
Magnetic properties of ${EuTiO}_{3}$ , ${Eu}_{2}$ ${TiO}_{4}$ , and ${Eu}_{3}$ ${Ti}_{2}$ $O_{7}$ Chien, Chia-Ling; DeBenedetti, S.; Barros, F. De S. Physical Review B, Vol. 10, Issue 9 https://doi.org/10.1103/PhysRevB.10.3913	journal	November 1974
Oxygen-Vacancy-Induced Antiferromagnetism to Ferromagnetism Transformation in Eu0.5Ba0.5TiO3−δ Multiferroic Thin Films Li, Weiwei; Zhao, Run; Wang, Le Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02618	journal	September 2013
Manipulating multiple order parameters via oxygen vacancies: The case of $E u_{0.5} B a_{0.5} Ti O_{3 - δ}$ Li, Weiwei; He, Qian; Wang, Le Physical Review B, Vol. 96, Issue 11 https://doi.org/10.1103/PhysRevB.96.115105	journal	September 2017
High-quality antiferromagnetic EuTiO3 epitaxial thin films on SrTiO3 prepared by pulsed laser deposition and postannealing Fujita, Koji; Wakasugi, Naoki; Murai, Shunsuke Applied Physics Letters, Vol. 94, Issue 6 https://doi.org/10.1063/1.3072598	journal	February 2009
Electronic structure and magnetism of EuTiO ₃ : a first-principles study Ranjan, Rajeev; Sadat Nabi, Hasan; Pentcheva, Rossitza Journal of Physics: Condensed Matter, Vol. 19, Issue 40 https://doi.org/10.1088/0953-8984/19/40/406217	journal	September 2007
Atomap: a new software tool for the automated analysis of atomic resolution images using two-dimensional Gaussian fitting Nord, Magnus; Vullum, Per Erik; MacLaren, Ian Advanced Structural and Chemical Imaging, Vol. 3, Issue 1 https://doi.org/10.1186/s40679-017-0042-5	journal	February 2017
Magnetic Structure of EuTiO ₃ McGuire, T. R.; Shafer, M. W.; Joenk, R. J. Journal of Applied Physics, Vol. 37, Issue 3 https://doi.org/10.1063/1.1708549	journal	March 1966
First-principles prediction of oxygen octahedral rotations in perovskite-structure EuTiO $_{3}$ Rushchanskii, Konstantin Z.; Spaldin, Nicola A.; Ležaić, Marjana Physical Review B, Vol. 85, Issue 10 https://doi.org/10.1103/PhysRevB.85.104109	journal	March 2012

Similar Records

Multiferroic behavior in EuTiO₃ films constrained by symmetry

Journal Article · Fri May 29 00:00:00 EDT 2020 · Physical Review B · OSTI ID:1601265

Ryan, P. J.; Sterbinsky, G. E.; Choi, Y.; +11 more

Solution precursor synthesis and magnetic properties of Eu{sub 1-x}Ca{sub x}TiO{sub 3}

Journal Article · Mon Mar 15 00:00:00 EDT 2010 · Journal of Solid State Chemistry · OSTI ID:1601265

Henderson, Nathaniel L; Ke, Xianglin; Schiffer, Peter

Self-assembled HfO₂-Au nanocomposites with ultra-fine vertically aligned Au nanopillars

Journal Article · Fri Jul 22 00:00:00 EDT 2022 · Nanoscale · OSTI ID:1601265

Zhang, Yizhi; Zhang, Di; Liu, Juncheng; +6 more

Related Subjects

36 MATERIALS SCIENCE
nanocomposite
multiferroics
self-assembled nanostructures
thin films
spintronics
Lattices
Nanocomposites
Magnetic properties
Epitaxy

Title: Vertical Strain-Driven Antiferromagnetic to Ferromagnetic Phase Transition in EuTiO 3 Nanocomposite Thin Films

Citation Formats

References (55)

Linked Research (1)

Similar Records

Related Subjects

Title: Vertical Strain-Driven Antiferromagnetic to Ferromagnetic Phase Transition in EuTiO ₃ Nanocomposite Thin Films