Synthesis, structure, and properties of binuclear molybdenum (V) complexes with carboxylate ligands
Journal Article
·
· Russian Journal of Coordination Chemistry
OSTI ID:160072
- Boreskov Institute of Catalysis (Russian Federation); and others
A simple procedure for the synthesis of binuclear molybdenum(V) complexes with carboxylate ligands is proposed. Hydrazinium [di({mu}-oxo)bis(aquodihydroxooxomolybdate(V))] of the formula (N{sub 2}H{sub 5}){sub 2}[Mo{sub 2}O{sub 4}(OH){sub 4}(H{sub 2}O){sub 2}] is used as an initial reagent in the synthesis. The synthesized complexes are studied by IR and EXAFS spectroscopic techniques, as well as by {sup 95}Mo, {sup 17}O, and {sup 14}N NMR spectroscopy. The oxidation state Mo(V) and the core fragment of the initial reagent remain the same in all the complexes.
- OSTI ID:
- 160072
- Journal Information:
- Russian Journal of Coordination Chemistry, Journal Name: Russian Journal of Coordination Chemistry Journal Issue: 9 Vol. 21; ISSN RJCCEY
- Country of Publication:
- United States
- Language:
- English
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