A stable metal-covalent-supramolecular organic framework hybrid: enrichment of catalysts for visible light-induced hydrogen production

Li, Xiong-Fei; Yu, Shang-Bo; Yang, Bo; Tian, Jia; Wang, Hui; Zhang, Dan-Wei; Liu, Yi; Li, Zhan-Ting

doi:10.1007/s11426-018-9234-2

Title: A stable metal-covalent-supramolecular organic framework hybrid: enrichment of catalysts for visible light-induced hydrogen production

Journal Article · Wed Apr 11 00:00:00 EDT 2018 · Science China Chemistry

DOI:https://doi.org/10.1007/s11426-018-9234-2· OSTI ID:1599780

Li, Xiong-Fei ^[1]; Yu, Shang-Bo ^[1]; Yang, Bo ^[1]; Tian, Jia ^[1]; Wang, Hui ^[1]; Zhang, Dan-Wei ^[1]; Liu, Yi ^[2]; Li, Zhan-Ting ^[1]

Fudan Univ., Shanghai (China)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Cubic metal-covalent-supramolecular organic framework (MCSOF-1) hybrid has been created from the reaction of two molecular components and subsequent co-assembly with cucurbit[8]uril (CB[8]) in water. In the presence of CB[8], [Ru(bpy)₃]²⁺ -based acylhydrazine 1·2Cl reacted with aldehyde 2·Cl to quantitatively yield six-armed precursor 3·8Cl through the generation of MCSOF-1. MCSOF-1 combines the structural features of metal-, covalent- and supramolecular organic frameworks. Its periodicity in water and in the solid state was confirmed by synchrotron X-ray scattering and diffraction experiments. Finally, MCSOF-1 could enrich discrete anionic polyoxometalates (POMs), maintain periodicity in acidic medium, and remarkably facilitate visible light-induced electron transfer from its [Ru(bpy)₃]²⁺ units to enriched POMs, leading to enhanced catalysis of the POMs for the reduction of proton to H₂ in both aqueous (homogeneous) and organic (heterogeneous) media.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Scientific User Facilities Division (SC-22.3 )

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1599780

Journal Information:: Science China Chemistry, Vol. 61, Issue 7; ISSN 1674-7291

Publisher:: Science China Press and SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 31 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
supramolecular organic framework
self-assembly
cucurbitu[8]ril
photocatalysis
hydrogen production

Title: A stable metal-covalent-supramolecular organic framework hybrid: enrichment of catalysts for visible light-induced hydrogen production

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