Polymorphism in M(H2PO2)3 (M = V, Al, Ga) compounds with the perovskite-related ReO3 structure

Evans, Hayden A.; Deng, Zeyu; Collings, Ines E.; Wu, Yue; Andrews, Jessica L.; Pilar, Kartik; Tuffnell, Joshua M.; Wu, Guang; Wang, John; Dutton, Siân E.; Bristowe, Paul D.; Seshadri, Ram; Cheetham, Anthony K.

doi:10.1039/C9CC00118B

Title: Polymorphism in M(H₂PO₂)₃ (M = V, Al, Ga) compounds with the perovskite-related ReO₃ structure

Journal Article · Fri Feb 15 00:00:00 EST 2019 · ChemComm

DOI:https://doi.org/10.1039/C9CC00118B· OSTI ID:1599724

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^[4]; Andrews, Jessica L. ^[1];

^[1]; Tuffnell, Joshua M. ^[5]; Wu, Guang ^[1]; Wang, John ^[4];

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Univ. of California, Santa Barbara, CA (United States)
National Univ. of Singapore (Singapore); Univ. of Cambridge (United Kingdom)
European Synchrotron Radiation Facility (ESRF), Grenoble (France)
National Univ. of Singapore (Singapore)
Univ. of Cambridge (United Kingdom)
Univ. of California, Santa Barbara, CA (United States); National Univ. of Singapore (Singapore)

Trivalent metal hypophosphites with the general formula M(H₂PO₂)₃ (M = V, Al, Ga) adopt the ReO₃ structure, with each compound displaying two structural polymorphs. High-pressure synchrotron X-ray studies reflect a pressure-driven phase transition in Ga(H₂PO₂)₃ that can be considered on the basis of ab initio thermodynamics.

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Research Organization:: Univ. of California, Santa Barbara, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Contributing Organization:: University of Cambridge; European Synchrotron Radiation Facility; National University of Singapore

Grant/Contract Number:: SC0012541; DMR-1720256

OSTI ID:: 1599724

Alternate ID(s):: OSTI ID: 1495059

Journal Information:: ChemComm, Vol. 55, Issue 20; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 14 works

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Perovskite-related ReO3-type structures Evans, Hayden A.; Wu, Yue; Seshadri, Ram Nature Reviews Materials, Vol. 5, Issue 3 https://doi.org/10.1038/s41578-019-0160-x	journal	January 2020
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Title: Polymorphism in M(H2PO2)3 (M = V, Al, Ga) compounds with the perovskite-related ReO3 structure

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