Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Evolution of Structure and Lithium Dynamics in LiNi[subscript 0.8]Mn[subscript 0.1]Co[subscript 0.1]O[subscript 2] (NMC811) Cathodes during Electrochemical Cycling

Journal Article · · Chem. Mater.
Abstract not provided
Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Northeastern Center for Chemical Energy Storage (NECCES); Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
Sponsoring Organization:
DOE - BASIC ENERGY SCIENCES
OSTI ID:
1599431
Journal Information:
Chem. Mater., Journal Name: Chem. Mater. Journal Issue: (7) ; 03, 2020 Vol. 31
Country of Publication:
United States
Language:
ENGLISH

References (37)

NMR Studies of Cathode Materials for Lithium-Ion Rechargeable Batteries journal October 2004
Cation Ordering in Li[Ni x Mn x Co (1–2 x ) ]O 2 -Layered Cathode Materials: A Nuclear Magnetic Resonance (NMR), Pair Distribution Function, X-ray Absorption Spectroscopy, and Electrochemical Study journal December 2007
7Li MAS NMR study of electrochemically deintercalated LixNi0.30Co0.70O2 phases: evidence of electronic and ionic mobility, and redox processes journal January 2001
Probing Dynamic Processes in Lithium-Ion Batteries by In Situ NMR Spectroscopy: Application to Li 1.08 Mn 1.92 O 4 Electrodes journal October 2015
Combined NMR and XAS Study on Local Environments and Electronic Structures of Electrochemically Li-Ion Deintercalated Li[sub 1−x]Co[sub 1/3]Ni[sub 1/3]Mn[sub 1/3]O[sub 2] Electrode System journal January 2004
Updating the Structure and Electrochemistry of Li x NiO 2 for 0 ≤ x ≤ 1 journal January 2018
Reaction Heterogeneity in LiNi 0.8 Co 0.15 Al 0.05 O 2 Induced by Surface Layer journal August 2017
Structure Solution of Metal-Oxide Li Battery Cathodes from Simulated Annealing and Lithium NMR Spectroscopy journal June 2017
Structural classification and properties of the layered oxides journal January 1980
A Mg-Doped High-Nickel Layered Oxide Cathode Enabling Safer, High-Energy-Density Li-Ion Batteries journal January 2019
Factors that affect Li mobility in layered lithium transition metal oxides journal September 2006
Identifying the Distribution of Al 3+ in LiNi 0.8 Co 0.15 Al 0.05 O 2 journal October 2016
Determination of the Kinetic Parameters of Mixed-Conducting Electrodes and Application to the System Li[sub 3]Sb journal January 1977
Structural and Electrochemical Study of the Li–Mn–Ni Oxide System within the Layered Single Phase Region journal December 2014
6 Li MAS NMR Studies of the Local Structure and Electrochemical Properties of Cr-doped Lithium Manganese and Lithium Cobalt Oxide Cathode Materials for Lithium-Ion Batteries journal May 2002
Temperature Dependence of 207 Pb MAS Spectra of Solid Lead Nitrate. An Accurate, Sensitive Thermometer for Variable-Temperature MAS journal October 1995
Novel Lithium-Ion Cathode Materials Based on Layered Manganese Oxides journal July 2001
Oxygen Release and Its Effect on the Cycling Stability of LiNi x Mn y Co z O 2 (NMC) Cathode Materials for Li-Ion Batteries journal January 2017
Rapid computation of magnetic resonance line shapes for exchange among many sites journal October 1967
NiO[sub 2] Obtained by Electrochemical Lithium Deintercalation from Lithium Nickelate: Structural Modifications journal January 2000
Capacity Fading of Ni-Rich Li[Ni x Co y Mn 1– xy ]O 2 (0.6 ≤ x ≤ 0.95) Cathodes for High-Energy-Density Lithium-Ion Batteries: Bulk or Surface Degradation? journal January 2018
Understanding the NMR shifts in paramagnetic transition metal oxides using density functional theory calculations journal May 2003
Galvanostatic Intermittent Titration and Performance Based Analysis of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode journal January 2017
Coupled Ion/Electron Hopping in Li x NiO 2 :  A 7 Li NMR Study journal February 2006
Understanding Li Diffusion in Li-Intercalation Compounds journal May 2012
Narrowing the Gap between Theoretical and Practical Capacities in Li-Ion Layered Oxide Cathode Materials journal July 2017
In situ x-ray diffraction and electrochemical studies of Li1−xNiO2 journal December 1993
High-resolution neutron powder diffractometer SPODI at research reactor FRM II
  • Hoelzel, M.; Senyshyn, A.; Juenke, N.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 667 https://doi.org/10.1016/j.nima.2011.11.070
journal March 2012
Study of the Failure Mechanisms of LiNi 0.8 Mn 0.1 Co 0.1 O 2 Cathode Material for Lithium Ion Batteries journal January 2015
A perspective on nickel-rich layered oxide cathodes for lithium-ion batteries journal January 2017
The AMPIX electrochemical cell: a versatile apparatus for in situ X-ray scattering and spectroscopic measurements journal November 2012
Effect of Ambient Storage on the Degradation of Ni-Rich Positive Electrode Materials (NMC811) for Li-Ion Batteries journal January 2018
The Development and Future of Lithium Ion Batteries journal December 2016
Isotropic High Field NMR Spectra of Li-Ion Battery Materials with Anisotropy >1 MHz journal January 2012
Investigation of the Structural Changes in Li[NiyMnyCo(1−2y)]O2(y = 0.05) upon Electrochemical Lithium Deintercalation journal February 2010
Lithium diffusion mechanisms in layered intercalation compounds journal July 2001
Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries journal July 2013