Electrochemical performance and stability of SrTi0.3Fe0.6Co0.1O3-δ infiltrated La0.8Sr0.2MnO3Zr0.92Y0.16O2-δ oxygen electrodes for intermediate-temperature solid oxide electrochemical cells

Zhang, Shan-Lin; Wang, Hongqian; Lu, Matthew Y.; Li, Cheng-Xin; Li, Chang-Jiu; Barnett, Scott A.

doi:10.1016/j.jpowsour.2019.04.044

Title: Electrochemical performance and stability of SrTi_0.3Fe_0.6Co_0.1O_3-δ infiltrated La_0.8Sr_0.2MnO₃Zr_0.92Y_0.16O_2-δ oxygen electrodes for intermediate-temperature solid oxide electrochemical cells

Journal Article · Tue Apr 16 00:00:00 EDT 2019 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2019.04.044· OSTI ID:1599353

Zhang, Shan-Lin ^[1]; Wang, Hongqian ^[2];

^[2];

^[3]; Li, Chang-Jiu ^[3];

^[2]

Northwestern Univ., Evanston, IL (United States); Xi'an Jiaotong Univ., Shaanxi (China)
Northwestern Univ., Evanston, IL (United States)
Xi'an Jiaotong Univ., Shaanxi (China)

We report that the La_0.8Sr_0.2MnO₃-Zr_0.92Y_0.16O_2-δ (LSM-YSZ) composite is the most widely used oxygen electrode for solid oxide electrochemical cells (SOCs). However, operating temperatures > 700 degrees C are required for good performance since oxygen reactions are limitied to three-phase boundaries (TPBs) because of poor ionic conductivity of LSM. Furthermore, LSM-YSZ electrodes typically delaminate during electrolysis operation leading to cell degradation. One strategy to improve SOCs with LSM-YSZ electrodes is to infiltrate a mixed ionically and electronically conducting (MIEC) material that promotes oxygen exchange. However, infiltrated materials have a nano-scale structure that may not be stable under SOC operating temperatures. Here, we report results on the infiltration of SrTi_0.3Fe_0.6Co_0.1O_3-δ(STFC), a recently reported high performance MIEC, into LSM-YSZ to improve its electrochemical performance and stability at intermediate temperatures. The infiltrated STFC enhances LSM-YSZ and cell performance, typically yielding a decrease in electrode polarization resistance by a factor > 3 times, resulting in an increase in fuel cell maximum power density and electrolysis current density (at 1.3 V) by a factor > 2 times. Perhaps more significantly, the infiltrated electrodes show good performance stability, with suppression of electrode delamination during electrolysis and no evidence of coarsening or segregation induced degradation.

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Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office (HFTO); National Science Foundation (NSF); China Scholarship Council; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: SC0016965; EE0008079; DMR-1506925; DMR-1545907; DMR-1121262; NNCI-1542205; 201606285002; 51602248; EE450008079

OSTI ID:: 1599353

Alternate ID(s):: OSTI ID: 1547504; OSTI ID: 1658926; OSTI ID: 2229573

Journal Information:: Journal of Power Sources, Vol. 426, Issue C; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 26 works

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Title: Electrochemical performance and stability of SrTi0.3Fe0.6Co0.1O3-δ infiltrated La0.8Sr0.2MnO3Zr0.92Y0.16O2-δ oxygen electrodes for intermediate-temperature solid oxide electrochemical cells

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Title: Electrochemical performance and stability of SrTi_0.3Fe_0.6Co_0.1O_3-δ infiltrated La_0.8Sr_0.2MnO₃Zr_0.92Y_0.16O_2-δ oxygen electrodes for intermediate-temperature solid oxide electrochemical cells