Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes

Windorff, Cory J.; Celis-Barros, Cristian; Sperling, Joseph M.; McKinnon, Noah C.; Albrecht-Schmitt, Thomas E.

doi:10.1039/C9SC05268B

Title: Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes

Journal Article · Wed Mar 11 00:00:00 EDT 2020 · Chemical Science

DOI:https://doi.org/10.1039/C9SC05268B· OSTI ID:1599242

^[1];

^[1]; McKinnon, Noah C. ^[1];

^[1]

Department of Chemistry and Biochemistry, Florida State University, Tallahassee, USA

The synthesis, characterization, and theoretical analysis of meridional americium tribromide tris(tricyclohexylphosphine oxide), mer-AmBr₃(OPcy₃)₃, has been achieved and is compared with its early lanthanide (La to Nd) analogs. The data show that homo trans ligands display significantly shorter bonds than the cis or hetero trans ligands. This is particularly pronounced in the americium compound. DFT along with multiconfigurational CASSCF calculations show that the contraction of the bonds relates qualitatively with overall covalency, i.e. americium shows the most covalent interactions compared to lanthanides. However, the involvement of the 5p and 6p shells in bonding follows a different order, namely cerium > neodymium ~ americium. This study provides further insight into the mechanisms by which ITI operates in low-valent f-block complexes.

View Journal Article

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Actinide Science & Technology (CAST); Florida State Univ., Tallahassee, FL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-13ER16414; SC0010677; SC0016568

OSTI ID:: 1599242

Alternate ID(s):: OSTI ID: 1767704

Journal Information:: Chemical Science, Journal Name: Chemical Science Vol. 11 Journal Issue: 10; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United Kingdom

Language:: English

Citation Metrics:

Cited by: 20 works

Citation information provided by
Web of Science

References (84)

Tailoring the optical properties of lanthanide phosphors: prediction and characterization of the luminescence of Pr ³⁺ -doped LiYF ₄ Ramanantoanina, Harry; Urland, Werner; Herden, Benjamin Physical Chemistry Chemical Physics, Vol. 17, Issue 14 https://doi.org/10.1039/C4CP05148C	journal	January 2015
Examination of Structure and Bonding in 10-Coordinate Europium and Americium Terpyridyl Complexes White, Frankie D.; Gaiser, Alyssa N.; Warzecha, Evan J. Inorganic Chemistry, Vol. 57, Issue 20 https://doi.org/10.1021/acs.inorgchem.8b02085	journal	September 2018
Prospecting Lighting Applications with Ligand Field Tools and Density Functional Theory: A First-Principles Account of the 4f ⁷ –4f ⁶ 5d ¹ Luminescence of CsMgBr ₃ :Eu ²⁺ Ramanantoanina, Harry; Cimpoesu, Fanica; Göttel, Christian Inorganic Chemistry, Vol. 54, Issue 17 https://doi.org/10.1021/acs.inorgchem.5b00988	journal	August 2015
Complexes of Lanthanide Nitrates with Tri Tert Butylphosphine Oxide Bowden, Allen; Coles, Simon J.; Pitak, Mateusz B. Inorganic Chemistry, Vol. 51, Issue 7 https://doi.org/10.1021/ic300142r	journal	March 2012
The Dark Side of Hydrogen Bonds in the Design of Optical Materials: A Charge-Density Perspective Nelyubina, Yulia V.; Puntus, Lada N.; Lyssenko, Konstantin A. Chemistry - A European Journal, Vol. 20, Issue 10 https://doi.org/10.1002/chem.201300566	journal	February 2014
Inner and outer sphere coordination of tricyclohexylphosphine oxide with lanthanide bromides Bowden, Allen; Lees, Anthony M. J.; Platt, Andrew W. G. Polyhedron, Vol. 91 https://doi.org/10.1016/j.poly.2015.02.008	journal	May 2015
Crystal structure of a dysprosium trichloride complex with oxygen donor ligands Zhang, Xing-Wang; Li, Xing-Fu; Benetollo, F. Inorganica Chimica Acta, Vol. 139, Issue 1-2 https://doi.org/10.1016/S0020-1693(00)84048-7	journal	December 1987
A Review of the Industrial and Recent Potential Applications of Trioctylphosphine Oxide Watson, E. K.; Rickelton, W. A. Solvent Extraction and Ion Exchange, Vol. 10, Issue 5 https://doi.org/10.1080/07366299208918141	journal	December 1992
Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes Jones, Matthew B.; Gaunt, Andrew J. Chemical Reviews, Vol. 113, Issue 2 https://doi.org/10.1021/cr300198m	journal	October 2012
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Electronic, Magnetic, and Theoretical Characterization of (NH ₄ ) ₄ UF ₈ , a Simple Molecular Uranium(IV) Fluoride Chemey, Alexander T.; Celis-Barros, Cristian; Huang, Kevin Inorganic Chemistry, Vol. 58, Issue 1 https://doi.org/10.1021/acs.inorgchem.8b02800	journal	December 2018
The structures of the lanthanide ethyl sulfate enneahydrates, M(C2H5SO4)3.9H2O [M = La–Lu (except Pm)], at 171 K Gerkin, R. E.; Reppart, W. J. Acta Crystallographica Section C Crystal Structure Communications, Vol. 40, Issue 5 https://doi.org/10.1107/S0108270184005710	journal	May 1984
Determining Relative f and d Orbital Contributions to M–Cl Covalency in MCl ₆ ^2– (M = Ti, Zr, Hf, U) and UOCl ₅ ^– Using Cl K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R. Journal of the American Chemical Society, Vol. 134, Issue 12 https://doi.org/10.1021/ja2105015	journal	March 2012
Hypersensitivity in the electronic transitions of lanthanide and actinide complexes Henrie, D. E.; Fellows, R. L.; Choppin, G. R. Coordination Chemistry Reviews, Vol. 18, Issue 2 https://doi.org/10.1016/S0010-8545(00)82044-5	journal	February 1976
The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes Gregson, Matthew; Lu, Erli; Mills, David P. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14137	journal	February 2017
On the inverse trans influence. Density functional studies of [MOX5]n– (M = Pa, n = 2; M = U, n = 1; M = Np, n = 0; X = F, Cl or Br) O'Grady, Emma; Kaltsoyannis, Nikolas Journal of the Chemical Society, Dalton Transactions, Issue 6 https://doi.org/10.1039/b109696f	journal	February 2002
Low‐Temperature Optical Absorption of Americium Halides Pappalardo, R. G.; Carnall, W. T.; Fields, P. R. The Journal of Chemical Physics, Vol. 51, Issue 3 https://doi.org/10.1063/1.1672121	journal	August 1969
On the color of the trivalent lanthanide ions Binnemans, K.; Görller-Walrand, C. Chemical Physics Letters, Vol. 235, Issue 3-4 https://doi.org/10.1016/0009-2614(95)00126-O	journal	March 1995
Chemistry with ADF te Velde, G.; Bickelhaupt, F. M.; Baerends, E. J. Journal of Computational Chemistry, Vol. 22, Issue 9, p. 931-967 https://doi.org/10.1002/jcc.1056	journal	January 2001
Observation of Magnetodielectric Effect in a Dysprosium-Based Single-Molecule Magnet Wang, Yu-Xia; Ma, Yinina; Chai, Yisheng Journal of the American Chemical Society, Vol. 140, Issue 25 https://doi.org/10.1021/jacs.8b04818	journal	May 2018
Quantification of f-element covalency through analysis of the electron density: insights from simulation Kerridge, A. Chemical Communications, Vol. 53, Issue 50 https://doi.org/10.1039/C7CC00962C	journal	January 2017
OLEX2 : a complete structure solution, refinement and analysis program Dolomanov, Oleg V.; Bourhis, Luc J.; Gildea, Richard J. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889808042726	journal	January 2009
The CASSCF state interaction method Malmqvist, Per-Åke; Roos, Björn O. Chemical Physics Letters, Vol. 155, Issue 2 https://doi.org/10.1016/0009-2614(89)85347-3	journal	February 1989
Does Covalency Increase or Decrease across the Actinide Series? Implications for Minor Actinide Partitioning Kaltsoyannis, Nikolas Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic3006025	journal	June 2012
Lanthanoid Complexes with Hexamethylphosphoramide (HMPA) Ligand. Preparation and Crystal Structure of Ytterbium Complexes of HMPA, [Yb(H ₂ O) ₅ (HMPA) ₂ ]Cl ₃ ·H ₂ O·HMPA and YbCl ₃ (HMPA) ₃ Hou, Zhaomin; Kobayashi, Kimiko; Yamazaki, Hiroshi Chemistry Letters, Vol. 20, Issue 2 https://doi.org/10.1246/cl.1991.265	journal	February 1991
The thermal behaviour of rare-earth triphenylphosphine oxide complexes Kingston, J. V.; Krankovits, E. M.; Magee, R. J. Inorganic and Nuclear Chemistry Letters, Vol. 5, Issue 6 https://doi.org/10.1016/0020-1650(69)80128-5	journal	June 1969
The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution Lindqvist-Reis, Patric; Apostolidis, Christos; Rebizant, Jean Angewandte Chemie International Edition, Vol. 46, Issue 6 https://doi.org/10.1002/anie.200603947	journal	January 2007
Phosphine and phosphine oxide adducts of vanadium(IV) chloride: synthesis and structural studies Cotton, F. Albert; Lu, Jian; Ren, Tong Inorganica Chimica Acta, Vol. 215, Issue 1-2 https://doi.org/10.1016/0020-1693(93)03684-3	journal	January 1994
Conversion of Americia to Anhydrous Trivalent Americium Halides Galley, Shane S.; Sperling, Joseph M.; Windorff, Cory J. Organometallics, Vol. 38, Issue 3 https://doi.org/10.1021/acs.organomet.8b00840	journal	January 2019
Elucidation of the inverse trans influence in uranyl and its imido and carbene analogues via quantum chemical simulation Fryer-Kanssen, Izaak; Kerridge, Andy Chemical Communications, Vol. 54, Issue 70 https://doi.org/10.1039/C8CC06088F	journal	January 2018
SHELXT – Integrated space-group and crystal-structure determination Sheldrick, George M. Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053273314026370	journal	January 2015
Paramagnetism of Aqueous Actinide Cations. Part I: Perchloric Acid Media Wall, Thomas F.; Jan, Steve; Autillo, Matthieu Inorganic Chemistry, Vol. 53, Issue 5 https://doi.org/10.1021/ic402371x	journal	February 2014
Synthesis, Structural Characterisation and Solution Behaviour of High-Symmetry Lanthanide Triflate Complexes with the Sterically Demanding Phosphine Oxides Cy ₃ PO and t Bu ₃ PO: Synthesis, Structural Characterisation and Solution Behaviour of High-Symmetry Lanthanide Triflate Complexes with the Sterically Demanding Phosphine O Coles, Simon J.; Pitak, Mateusz B.; Platt, Andrew W. G. European Journal of Inorganic Chemistry, Vol. 2017, Issue 11 https://doi.org/10.1002/ejic.201601471	journal	March 2017
Calculation of the 4f1→4f05d1 transitions in Ce3+-doped systems by Ligand Field Density Functional Theory Ramanantoanina, Harry; Urland, Werner; García-Fuente, Amador Chemical Physics Letters, Vol. 588 https://doi.org/10.1016/j.cplett.2013.10.012	journal	November 2013
The Reaction Chemistry of Plutonyl(VI) Chloride Complexes with Triphenyl Phosphineoxide and Triphenyl Phosphinimine ^† Berthon, Claude; Boubals, Nathalie; Charushnikova, Iraida A. Inorganic Chemistry, Vol. 49, Issue 20 https://doi.org/10.1021/ic101251a	journal	October 2010
Stable Uranium(VI) Methyl and Acetylide Complexes and the Elucidation of an Inverse Trans Influence Ligand Series Lewis, Andrew J.; Carroll, Patrick J.; Schelter, Eric J. Journal of the American Chemical Society, Vol. 135, Issue 35 https://doi.org/10.1021/ja406610r	journal	August 2013
Pentahalogeno-oxouranates(VI) Bagnall, Kenneth W.; du Preez, Jan G. H.; Gellatly, Barry J. Journal of the Chemical Society, Dalton Transactions, Issue 19 https://doi.org/10.1039/dt9750001963	journal	January 1975
Hypersensitive Transitions in Rare‐Earth Ions Judd, B. R. The Journal of Chemical Physics, Vol. 44, Issue 2 https://doi.org/10.1063/1.1726774	journal	January 1966
Complexes of lanthanide nitrates with tri-isopropylphosphine oxide Bowden, Allen; Coles, Simon J.; Pitak, Mateusz B. Polyhedron, Vol. 68 https://doi.org/10.1016/j.poly.2013.10.028	journal	January 2014
Systematic structural studies on cobalt(II) complexes of tricyclohexylphosphine oxide and related ligands Bou-Moreno, Rafael; Cotton, Simon A.; Hunter, Verity Polyhedron, Vol. 30, Issue 17 https://doi.org/10.1016/j.poly.2011.08.005	journal	November 2011
Development and applications of the LFDFT: the non-empirical account of ligand field and the simulation of the f–d transitions by density functional theory Ramanantoanina, Harry; Sahnoun, Mohammed; Barbiero, Andrea Physical Chemistry Chemical Physics, Vol. 17, Issue 28 https://doi.org/10.1039/C5CP02349A	journal	January 2015
Tetrahalide Complexes of the [U(NR) ₂ ] ²⁺ Ion: Synthesis, Theory, and Chlorine K-Edge X-ray Absorption Spectroscopy Spencer, Liam P.; Yang, Ping; Minasian, Stefan G. Journal of the American Chemical Society, Vol. 135, Issue 6 https://doi.org/10.1021/ja310575j	journal	January 2013
Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium Cross, Justin N.; Macor, Joseph A.; Bertke, Jeffery A. Angewandte Chemie International Edition, Vol. 55, Issue 41 https://doi.org/10.1002/anie.201606367	journal	September 2016
A first phosphine oxide-based extractant with high Am/Cm selectivity Matveev, P. I.; Borisova, N. E.; Andreadi, N. G. Dalton Transactions, Vol. 48, Issue 8 https://doi.org/10.1039/C8DT04729D	journal	January 2019
Halogeno-, oxohalogeno-, and ethoxyhalogeno-complexes of quinquevalent protactinium, uranium, niobium, and tantalum Brown, D.; Rickard, C. E. F. Journal of the Chemical Society A: Inorganic, Physical, Theoretical https://doi.org/10.1039/j19710000081	journal	January 1971
Synthesis, properties and solution speciation of lanthanide chloride complexes of triphenylphosphine oxide Glazier, Mikael J.; Levason, William; Matthews, Melissa L. Inorganica Chimica Acta, Vol. 357, Issue 4 https://doi.org/10.1016/j.ica.2003.09.015	journal	March 2004
Extraction and Complexation of Alkali, Alkaline Earth, and F-Element Cations by Calixaryl Phosphine Oxides Arnaud-Neu, F.; Browne, J. K.; Byrne, D. Chemistry - A European Journal, Vol. 5, Issue 1 https://doi.org/10.1002/(SICI)1521-3765(19990104)5:1<175::AID-CHEM175>3.0.CO;2-P	journal	January 1999
Uranium–Ligand Multiple Bonding in Uranyl Analogues, [L═U═L] ^{n +} , and the Inverse Trans Influence La Pierre, Henry S.; Meyer, Karsten Inorganic Chemistry, Vol. 52, Issue 2 https://doi.org/10.1021/ic302412j	journal	December 2012
Complexes of triphenylphosphine oxide with lanthanide bromides Bowden, Allen; Platt, Andrew W. G.; Singh, Kuldip Inorganica Chimica Acta, Vol. 363, Issue 1 https://doi.org/10.1016/j.ica.2009.08.016	journal	January 2010
High-Pressure Studies of Cesium Uranyl Chloride Warzecha, Evan; Celis-Barros, Cristian; Dilbeck, Tristan Inorganic Chemistry, Vol. 58, Issue 1 https://doi.org/10.1021/acs.inorgchem.8b02300	journal	December 2018
Symmetry-Supported Magnetic Blocking at 20 K in Pentagonal Bipyramidal Dy(III) Single-Ion Magnets Chen, Yan-Cong; Liu, Jun-Liang; Ungur, Liviu Journal of the American Chemical Society, Vol. 138, Issue 8 https://doi.org/10.1021/jacs.5b13584	journal	February 2016
Experimental and Theoretical Comparison of Transition-Metal and Actinide Tetravalent Schiff Base Coordination Complexes Klamm, Bonnie E.; Windorff, Cory J.; Celis-Barros, Cristian Inorganic Chemistry, Vol. 57, Issue 24 https://doi.org/10.1021/acs.inorgchem.8b02700	journal	November 2018
Mixed Phosphine−Phosphine Oxide Ligands Grushin, Vladimir V. Chemical Reviews, Vol. 104, Issue 3 https://doi.org/10.1021/cr030026j	journal	March 2004
The strength of actinide–element bonds from the quantum theory of atoms-in-molecules Huang, Qian-Rui; Kingham, Jennifer R.; Kaltsoyannis, Nikolas Dalton Transactions, Vol. 44, Issue 6 https://doi.org/10.1039/C4DT02323D	journal	January 2015
Structural Variety in Solvated Lanthanoid(III ) Halide Complexes Deacon, Glen B.; Feng, Tiecheng; Junk, Peter C. Australian Journal of Chemistry, Vol. 53, Issue 10 https://doi.org/10.1071/CH00117	journal	January 2000
Covalent Bonding and the Trans Influence in Lanthanide Compounds Krogh-Jespersen, Karsten; Romanelli, Michael D.; Melman, Jonathan H. Inorganic Chemistry, Vol. 49, Issue 2 https://doi.org/10.1021/ic901571m	journal	January 2010
Trans influence in a mer -octahedral triiodidolanthanide: triiodidotris(tetrahydrofuran-κ O )ytterbium(III) Emge, Thomas J.; Kornienko, A.; Brennan, John G. Acta Crystallographica Section C Crystal Structure Communications, Vol. 65, Issue 11 https://doi.org/10.1107/S0108270109038268	journal	October 2009
Charge control of the inverse trans-influence La Pierre, Henry S.; Rosenzweig, Michael; Kosog, Boris Chemical Communications, Vol. 51, Issue 93 https://doi.org/10.1039/C5CC07211E	journal	January 2015
Preparation and X-Ray Crystal Structures of Tetrahydrofuran-Complexed Rare Earth Chlorides — a Structurally Rich Series Deacon, Glen B.; Feng, Tiecheng; Junk, Peter C. Australian Journal of Chemistry, Vol. 51, Issue 1 https://doi.org/10.1071/C97174	journal	January 1998
Crystal structure refinement with SHELXL Sheldrick, George M. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053229614024218	journal	January 2015
Emergence of the structure-directing role of f-orbital overlap-driven covalency Lu, Erli; Sajjad, Saira; Berryman, Victoria E. J. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08553-y	journal	February 2019
Anhydrous scandium, yttrium, lanthanide and actinide halide complexes with neutral oxygen and nitrogen donor ligands Mishra, Shashank Coordination Chemistry Reviews, Vol. 252, Issue 18-20 https://doi.org/10.1016/j.ccr.2007.10.029	journal	October 2008
The Inverse Trans Influence in a Family of Pentavalent Uranium Complexes Lewis, Andrew J.; Mullane, Kimberly C.; Nakamaru-Ogiso, Eiko Inorganic Chemistry, Vol. 53, Issue 13 https://doi.org/10.1021/ic500833s	journal	June 2014
On enantiomorph-polarity estimation Flack, H. D. Acta Crystallographica Section A Foundations of Crystallography, Vol. 39, Issue 6 https://doi.org/10.1107/S0108767383001762	journal	November 1983
Origin of Selectivity of a Triazinyl Ligand for Americium(III) over Neodymium(III) Dan, David; Celis‐Barros, Cristian; White, Frankie D. Chemistry – A European Journal https://doi.org/10.1002/chem.201806070	journal	February 2019
From weak to strong interactions: A comprehensive analysis of the topological and energetic properties of the electron density distribution involving X–H⋯F–Y systems Espinosa, Enrique; Alkorta, Ibon; Elguero, José The Journal of Chemical Physics, Vol. 117, Issue 12 https://doi.org/10.1063/1.1501133	journal	September 2002
Topological Study of Bonding in Aquo and Bis(triazinyl)pyridine Complexes of Trivalent Lanthanides and Actinides: Does Covalency Imply Stability? Fryer-Kanssen, Izaak; Austin, Jonathan; Kerridge, Andrew Inorganic Chemistry, Vol. 55, Issue 20 https://doi.org/10.1021/acs.inorgchem.6b00968	journal	August 2016
Electronic Energy Levels of the Lighter Actinides: U ³⁺ , Np ³⁺ , Pu ³⁺ , Am ³⁺ , and Cm ³⁺ Carnall, W. T.; Wybourne, B. G. The Journal of Chemical Physics, Vol. 40, Issue 11 https://doi.org/10.1063/1.1725018	journal	June 1964
Hydrophobic Deep Eutectic Solvents Incorporating Trioctylphosphine Oxide: Advanced Liquid Extractants Gilmore, Mark; McCourt, Éadaoin N.; Connolly, Francis ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 12 https://doi.org/10.1021/acssuschemeng.8b04843	journal	October 2018
Yttrium halide complexes of phosphine- and arsine oxides: synthesis, multinuclear NMR and structural studies Hill, Nicholas J.; Levason, William; Popham, Michael C. Polyhedron, Vol. 21, Issue 4 https://doi.org/10.1016/S0277-5387(01)01011-7	journal	March 2002
Synthesis of Uranium(VI) Terminal Oxo Complexes: Molecular Geometry Driven by the Inverse Trans -Influence Kosog, Boris; La Pierre, Henry S.; Heinemann, Frank W. Journal of the American Chemical Society, Vol. 134, Issue 11 https://doi.org/10.1021/ja211618v	journal	March 2012
Complexes of lanthanide chlorides with tricyclohexylphosphine oxide. The single crystal X-ray structures and solution properties of pentagonal bipyramidal complexes [Ln(H2O)5(Cy3PO)2]3+·Cy3PO·3Cl− Ln=Dy, Er Lees, Anthony M. J.; Platt, Andrew W. G. Polyhedron, Vol. 67 https://doi.org/10.1016/j.poly.2013.09.026	journal	January 2014
Lanthanide phosphine oxide complexes Platt, Andrew W. G. Coordination Chemistry Reviews, Vol. 340 https://doi.org/10.1016/j.ccr.2016.09.012	journal	June 2017
Covalency in Americium(III) Hexachloride Cross, Justin N.; Su, Jing; Batista, Enrique R. Journal of the American Chemical Society, Vol. 139, Issue 25 https://doi.org/10.1021/jacs.7b03755	journal	June 2017
[Am(C ₅ Me ₄ H) ₃ ]: An Organometallic Americium Complex Goodwin, Conrad A. P.; Su, Jing; Albrecht-Schmitt, Thomas E. Angewandte Chemie International Edition, Vol. 58, Issue 34 https://doi.org/10.1002/anie.201905225	journal	July 2019
Electronic Structure and Bonding in Actinyl Ions and their Analogs Denning, Robert G. The Journal of Physical Chemistry A, Vol. 111, Issue 20 https://doi.org/10.1021/jp071061n	journal	May 2007
Structures of trimethylphosphonium trans-tetrachlorobis(trimethylphosphine)chromate(III), mer-trichlorobis(dimethylphenylphosphine)(dimethylphenylphosphine oxide)chromium(III) and mer-trichlorotris(trimethylphosphine oxide)molybdenum(III) dichloromethane solvate Cotton, F. A.; Luck, R. L. Acta Crystallographica Section C Crystal Structure Communications, Vol. 47, Issue 5 https://doi.org/10.1107/S0108270190011787	journal	May 1991
Structure of a six-coordinate rare earth complex: Trichlorotris(hexamethylphos-phoramide)praseodymium(III) Radonovich, Lewis J.; Glick, Milton D. Journal of Inorganic and Nuclear Chemistry, Vol. 35, Issue 8 https://doi.org/10.1016/0022-1902(73)80505-6	journal	August 1973
Solid-state phosphorus-31 NMR and x-ray crystallographic studies of tertiary phosphines and their derivatives Davies, Julian A.; Dutremez, Sylvain.; Pinkerton, A. Alan. Inorganic Chemistry, Vol. 30, Issue 10 https://doi.org/10.1021/ic00010a029	journal	May 1991
Trans-effects in octahedral transition metal complexes Coe, Benjamin J.; Glenwright, Susan J. Coordination Chemistry Reviews, Vol. 203, Issue 1 https://doi.org/10.1016/S0010-8545(99)00184-8	journal	June 2000
Ab initio calculations of heavy-actinide hexahalide compounds: do these heavy actinides behave like their isoelectronic lanthanide analogues? Celis-Barros, Cristian; Páez-Hernández, Dayán; Beltrán-Leiva, María J. Physical Chemistry Chemical Physics, Vol. 20, Issue 6 https://doi.org/10.1039/C7CP06585J	journal	January 2018
Ligand field density functional theory calculation of the 4f2 → 4f15d1 transitions in the quantum cutter Cs2KYF6:Pr3+ Ramanantoanina, Harry; Urland, Werner; Cimpoesu, Fanica Physical Chemistry Chemical Physics, Vol. 15, Issue 33 https://doi.org/10.1039/c3cp51344k	journal	January 2013
High-Resolution Solid-State Oxygen-17 NMR of Actinide-Bearing Compounds: An Insight into the 5f Chemistry Martel, Laura; Magnani, Nicola; Vigier, Jean-Francois Inorganic Chemistry, Vol. 53, Issue 13 https://doi.org/10.1021/ic5007555	journal	June 2014
Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform Corbey, Jordan F.; Rapko, Brian M.; Wang, Zheming Inorganic Chemistry, Vol. 57, Issue 4 https://doi.org/10.1021/acs.inorgchem.7b03154	journal	February 2018

Similar Records

Actinide inverse trans influence versus cooperative pushing from below and multi-center bonding

Journal Article · Tue Jul 18 00:00:00 EDT 2023 · Nature Communications · OSTI ID:1599242

Motta, Laura C.; Autschbach, Jochen

Electronic Structure and Properties of Berkelium Iodates

Journal Article · Thu Sep 14 00:00:00 EDT 2017 · Journal of the American Chemical Society · OSTI ID:1599242

Silver, Mark A.; Cary, Samantha K.; Garza, Alejandro J.; +28 more

Cyclopentadienyl coordination induces unexpected ionic Am-N bonding in an americium bipyridyl complex

Journal Article · Tue Jan 11 00:00:00 EST 2022 · Nature Communications · OSTI ID:1599242

Long, Brian N.; Beltrán-Leiva, María J.; Celis-Barros, Cristian; +5 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
nuclear
defects
mechanical behavior
corrosion
charge transport
superconductivity
magnetism and spin physics
separations
geophysics/geochemistry
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (predictive)
synthesis (scalable processing)

Title: Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes

Citation Formats

References (84)

Similar Records

Related Subjects