Dissociate lattice oxygen redox reactions from capacity and voltage drops of battery electrodes

Wu, Jinpeng; Zhuo, Zengqing; Rong, Xiaohui; Dai, Kehua; Lebens-Higgins, Zachary; Sallis, Shawn; Pan, Feng; Piper, Louis F.  J.; Liu, Gao; Chuang, Yi-de; Hussain, Zahid; Li, Qinghao; Zeng, Rong; Shen, Zhi-xun; Yang, Wanli

doi:10.1126/sciadv.aaw3871

Title: Dissociate lattice oxygen redox reactions from capacity and voltage drops of battery electrodes

Journal Article · Sat Feb 01 00:00:00 EST 2020 · Science Advances

DOI:https://doi.org/10.1126/sciadv.aaw3871· OSTI ID:1598793

^[1]; Zhuo, Zengqing ^[2]; Rong, Xiaohui ^[3]; Dai, Kehua ^[4];

^[5];

^[6]; Pan, Feng ^[7];

^[8];

^[9];

^[6]; Hussain, Zahid ^[6];

^[3]; Zeng, Rong ^[10];

^[11];

^[6]

Stanford Univ., CA (United States). Geballe Lab. for Advanced Materials; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES)
Peking Univ. Shenzhen Graduate School, Shenzhen (China); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Chinese Academy of Sciences (CAS), Beijing (China). Inst. of Physics; Univ. of Chinese Academy of Sciences, Beijing (China)
Northeastern Univ., Shenyang (China); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Binghamton Univ., NY (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Peking Univ. Shenzhen Graduate School, Shenzhen (China)
Binghamton Univ., NY (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Tsinghua Univ., Beijing (China)
Stanford Univ., CA (United States). Geballe Lab. for Advanced Materials; SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES); Stanford Univ., CA (United States)

The oxygen redox (OR) reaction is a promising concept for improving battery energy density, however oxygen activities are generally considered detrimental to the stability and kinetics of batteries. Studies of OR activities often mix the lattice OR with other oxygen-involved reactions, such as gas release, radical oxygen evolution and surface reactions, further shadowing the true property of the practically meaningful lattice OR activities. Here, based on high-efficiency mapping of resonant inelastic X-ray scattering (mRIXS) of both the transition-metals and oxygen, we distinguish and quantify the lattice OR activities Na_0.6[Li_0.2Mn_0.8]O₂.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Northeastern Center for Chemical Energy Storage (NECCES); Binghamton Univ., NY (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; China’s National Key R&D Programmes; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: SC0012583; AC02-05CH11231; AC02-76SF00515

OSTI ID:: 1598793

Alternate ID(s):: OSTI ID: 1573374; OSTI ID: 1601224

Journal Information:: Science Advances, Vol. 6, Issue 6; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 70 works

Citation information provided by
Web of Science

References (49)

Synchrotron X-ray Analytical Techniques for Studying Materials Electrochemistry in Rechargeable Batteries Lin, Feng; Liu, Yijin; Yu, Xiqian Chemical Reviews, Vol. 117, Issue 21 https://doi.org/10.1021/acs.chemrev.7b00007	journal	September 2017
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Spectroscopic Signature of Oxidized Oxygen States in Peroxides Zhuo, Zengqing; Pemmaraju, Chaitanya Das; Vinson, John The Journal of Physical Chemistry Letters, Vol. 9, Issue 21 https://doi.org/10.1021/acs.jpclett.8b02757	journal	October 2018
Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release Hu, Enyuan; Yu, Xiqian; Lin, Ruoqian Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0207-z	journal	July 2018
A new electrode material for rechargeable sodium batteries: P2-type Na _2/3 [Mg _0.28 Mn _0.72 ]O ₂ with anomalously high reversible capacity Yabuuchi, Naoaki; Hara, Ryo; Kubota, Kei J. Mater. Chem. A, Vol. 2, Issue 40 https://doi.org/10.1039/C4TA04351K	journal	January 2014
Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides Qiao, Ruimin; Chin, Timothy; Harris, Stephen J. Current Applied Physics, Vol. 13, Issue 3 https://doi.org/10.1016/j.cap.2012.09.017	journal	May 2013
Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni_0.2Li_0.2Mn_0.6]O₂ Armstrong, A. Robert; Holzapfel, Michael; Novák, Petr Journal of the American Chemical Society, Vol. 128, Issue 26 https://doi.org/10.1021/ja062027+	journal	June 2006
Singlet oxygen evolution from layered transition metal oxide cathode materials and its implications for lithium-ion batteries Wandt, Johannes; Freiberg, Anna T. S.; Ogrodnik, Alexander Materials Today, Vol. 21, Issue 8 https://doi.org/10.1016/j.mattod.2018.03.037	journal	October 2018
Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging Singer, A.; Zhang, M.; Hy, S. Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2018-02753	text	January 2018
Origin of Carbon Dioxide Evolved during Cycling of Nickel-Rich Layered NCM Cathodes Hatsukade, Toru; Schiele, Alexander; Hartmann, Pascal ACS Applied Materials & Interfaces, Vol. 10, Issue 45 https://doi.org/10.1021/acsami.8b13158	journal	October 2018
Anionic Redox Reaction-Induced High-Capacity and Low-Strain Cathode with Suppressed Phase Transition Rong, Xiaohui; Hu, Enyuan; Lu, Yaxiang Joule, Vol. 3, Issue 2 https://doi.org/10.1016/j.joule.2018.10.022	journal	February 2019
Direct evidence of gradient Mn(II) evolution at charged states in LiNi0.5Mn1.5O4 electrodes with capacity fading Qiao, Ruimin; Wang, Yuesheng; Olalde-Velasco, Paul Journal of Power Sources, Vol. 273 https://doi.org/10.1016/j.jpowsour.2014.10.013	journal	January 2015
Anionic and cationic redox and interfaces in batteries: Advances from soft X-ray absorption spectroscopy to resonant inelastic scattering Yang, Wanli; Devereaux, Thomas P. Journal of Power Sources, Vol. 389 https://doi.org/10.1016/j.jpowsour.2018.04.018	journal	June 2018
Bulk sensitive x-ray absorption spectroscopy free of self-absorption effects Achkar, A. J.; Regier, T. Z.; Wadati, H. Physical Review B, Vol. 83, Issue 8 https://doi.org/10.1103/PhysRevB.83.081106	journal	February 2011
Decoupling Cationic–Anionic Redox Processes in a Model Li-Rich Cathode via Operando X-ray Absorption Spectroscopy Assat, Gaurav; Iadecola, Antonella; Delacourt, Charles Chemistry of Materials, Vol. 29, Issue 22 https://doi.org/10.1021/acs.chemmater.7b03434	journal	November 2017
Anionic redox processes for electrochemical devices Grimaud, A.; Hong, W. T.; Shao-Horn, Y. Nature Materials, Vol. 15, Issue 2 https://doi.org/10.1038/nmat4551	journal	January 2016
Oxygen release and oxygen redox Yang, Wanli Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0222-0	journal	July 2018
Oxygen redox chemistry without excess alkali-metal ions in Na2/3[Mg0.28Mn0.72]O2 Maitra, Urmimala; House, Robert A.; Somerville, James W. Nature Chemistry, Vol. 10, Issue 3 https://doi.org/10.1038/nchem.2923	journal	January 2018
Revealing and suppressing surface Mn(II) formation of Na0.44MnO2 electrodes for Na-ion batteries Qiao, Ruimin; Dai, Kehua; Mao, Jing Nano Energy, Vol. 16 https://doi.org/10.1016/j.nanoen.2015.06.024	journal	September 2015
Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries Assat, Gaurav; Tarascon, Jean-Marie Nature Energy, Vol. 3, Issue 5 https://doi.org/10.1038/s41560-018-0097-0	journal	April 2018
Fundamental interplay between anionic/cationic redox governing the kinetics and thermodynamics of lithium-rich cathodes Assat, Gaurav; Foix, Dominique; Delacourt, Charles Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02291-9	journal	December 2017
Modular soft x-ray spectrometer for applications in energy sciences and quantum materials Chuang, Yi-De; Shao, Yu-Cheng; Cruz, Alejandro Review of Scientific Instruments, Vol. 88, Issue 1 https://doi.org/10.1063/1.4974356	journal	January 2017
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
High Reversibility of Lattice Oxygen Redox Quantified by Direct Bulk Probes of Both Anionic and Cationic Redox Reactions Dai, Kehua; Wu, Jinpeng; Zhuo, Zengqing Joule, Vol. 3, Issue 2 https://doi.org/10.1016/j.joule.2018.11.014	journal	February 2019
New O2/P2-type Li-Excess Layered Manganese Oxides as Promising Multi-Functional Electrode Materials for Rechargeable Li/Na Batteries Yabuuchi, Naoaki; Hara, Ryo; Kajiyama, Masataka Advanced Energy Materials, Vol. 4, Issue 13 https://doi.org/10.1002/aenm.201301453	journal	May 2014
Critical Role of Oxygen Evolved from Layered Li–Excess Metal Oxides in Lithium Rechargeable Batteries Hong, Jihyun; Lim, Hee-Dae; Lee, Minah Chemistry of Materials, Vol. 24, Issue 14 https://doi.org/10.1021/cm3005634	journal	July 2012
Distinction between Intrinsic and X-ray-Induced Oxidized Oxygen States in Li-Rich 3d Layered Oxides and LiAlO ₂ Lebens-Higgins, Zachary W.; Vinckeviciute, Julija; Wu, Jinpeng The Journal of Physical Chemistry C, Vol. 123, Issue 21 https://doi.org/10.1021/acs.jpcc.9b01298	journal	May 2019
Structure-Induced Reversible Anionic Redox Activity in Na Layered Oxide Cathode Rong, Xiaohui; Liu, Jue; Hu, Enyuan Joule, Vol. 2, Issue 1 https://doi.org/10.1016/j.joule.2017.10.008	journal	January 2018
Elucidating anionic oxygen activity in lithium-rich layered oxides Xu, Jing; Sun, Meiling; Qiao, Ruimin Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03403-9	journal	March 2018
A novel P3-type Na _2/3 Mg _1/3 Mn _2/3 O ₂ as high capacity sodium-ion cathode using reversible oxygen redox Song, Bohang; Hu, Enyuan; Liu, Jue Journal of Materials Chemistry A, Vol. 7, Issue 4 https://doi.org/10.1039/C8TA09422E	journal	January 2019
Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging Singer, A.; Zhang, M.; Hy, S. Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0184-2	journal	July 2018
Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides Gent, William E.; Lim, Kipil; Liang, Yufeng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02041-x	journal	December 2017
Residual Lithium Carbonate Predominantly Accounts for First Cycle CO ₂ and CO Outgassing of Li-Stoichiometric and Li-Rich Layered Transition-Metal Oxides Renfrew, Sara E.; McCloskey, Bryan D. Journal of the American Chemical Society, Vol. 139, Issue 49 https://doi.org/10.1021/jacs.7b08461	journal	November 2017
What Triggers Oxygen Loss in Oxygen Redox Cathode Materials? House, Robert A.; Maitra, Urmimala; Jin, Liyu Chemistry of Materials, Vol. 31, Issue 9 https://doi.org/10.1021/acs.chemmater.9b00227	journal	April 2019
High-efficiency in situ resonant inelastic x-ray scattering (iRIXS) endstation at the Advanced Light Source Qiao, Ruimin; Li, Qinghao; Zhuo, Zengqing Review of Scientific Instruments, Vol. 88, Issue 3 https://doi.org/10.1063/1.4977592	journal	March 2017
Oxygen Release and Surface Degradation of Li- and Mn-Rich Layered Oxides in Variation of the Li ₂ MnO ₃ Content Teufl, Tobias; Strehle, Benjamin; Müller, Philipp Journal of The Electrochemical Society, Vol. 165, Issue 11 https://doi.org/10.1149/2.0691811jes	journal	January 2018
The Li-Ion Rechargeable Battery: A Perspective Goodenough, John B.; Park, Kyu-Sung Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja3091438	journal	January 2013
Direct Quantification of Anionic Redox over Long Cycling of Li-Rich NMC via Hard X-ray Photoemission Spectroscopy Assat, Gaurav; Iadecola, Antonella; Foix, Dominique ACS Energy Letters, Vol. 3, Issue 11 https://doi.org/10.1021/acsenergylett.8b01798	journal	October 2018
Oxygen Release and Its Effect on the Cycling Stability of LiNi _x Mn _y Co _z O ₂ (NMC) Cathode Materials for Li-Ion Batteries Jung, Roland; Metzger, Michael; Maglia, Filippo Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.0021707jes	journal	January 2017
Quantitative probe of the transition metal redox in battery electrodes through soft x-ray absorption spectroscopy Li, Qinghao; Qiao, Ruimin; Wray, L. Andrew Journal of Physics D: Applied Physics, Vol. 49, Issue 41 https://doi.org/10.1088/0022-3727/49/41/413003	journal	September 2016
Key electronic states in lithium battery materials probed by soft X-ray spectroscopy Yang, Wanli; Liu, Xiaosong; Qiao, Ruimin Journal of Electron Spectroscopy and Related Phenomena, Vol. 190 https://doi.org/10.1016/j.elspec.2013.03.008	journal	October 2013
Exploring reversible oxidation of oxygen in a manganese oxide Du, Ke; Zhu, Jinyou; Hu, Guorong Energy & Environmental Science, Vol. 9, Issue 8 https://doi.org/10.1039/C6EE01367H	journal	January 2016
Tunable-excitation soft X-ray fluorescence spectroscopy of high-Tc superconductors: an inequivalent-site seeing story Butorin, Sergei M.; Guo, Jinghua; Wassdahl, Nial Journal of Electron Spectroscopy and Related Phenomena, Vol. 110-111 https://doi.org/10.1016/S0368-2048(00)00167-5	journal	October 2000
Solid-state Redox Reaction of Oxide Ions for Rechargeable Batteries Yabuuchi, Naoaki Chemistry Letters, Vol. 46, Issue 4 https://doi.org/10.1246/cl.161044	journal	April 2017
Anionic Redox Reaction-Induced High-Capacity and Low-Strain Cathode with Suppressed Phase Transition Rong, Xiaohui; Hu, Enyuan; Lu, Yaxiang Joule, Vol. 3, Issue 2 https://doi.org/10.1016/j.joule.2019.01.010	journal	February 2019
Bulk sensitive x-ray absorption spectroscopy free of self-absorption effects Achkar, A. J.; Regier, T. Z.; Wadati, H. arXiv https://doi.org/10.48550/arxiv.1001.1925	text	January 2010
Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides Qiao, Ruimin; Chin, Timothy; Harris, Stephen J. arXiv https://doi.org/10.48550/arxiv.1208.6319	text	January 2012
Spectroscopic Signature of Oxidized Oxygen States in Peroxides Zhuo, Zengqing; Pemmaraju, Chaitanya Das; Vinson, John arXiv https://doi.org/10.48550/arxiv.1809.08292	text	January 2018
Elemental-sensitive Detection of the Chemistry in Batteries through Soft X-ray Absorption Spectroscopy and Resonant Inelastic X-ray Scattering Wu, Jinpeng; Sallis, Shawn; Qiao, Ruimin Journal of Visualized Experiments, Issue 134 https://doi.org/10.3791/57415-v	journal	April 2018

Similar Records

Fingerprint Oxygen Redox Reactions in Batteries through High-Efficiency Mapping of Resonant Inelastic X-ray Scattering

Journal Article · Sat Jan 05 00:00:00 EST 2019 · Condensed Matter · OSTI ID:1598793

Wu, Jinpeng; Li, Qinghao; Sallis, Shawn; +6 more

High Reversibility of Lattice Oxygen Redox Quantified by Direct Bulk Probes of Both Anionic and Cationic Redox Reactions

Journal Article · Fri Feb 01 00:00:00 EST 2019 · Joule · OSTI ID:1598793

Dai, Kehua; Wu, Jinpeng; Zhuo, Zengqing; +17 more

Enhancing the Reversibility of Lattice Oxygen Redox Through Modulated Transition Metal–Oxygen Covalency for Layered Battery Electrodes

Journal Article · Mon Apr 11 00:00:00 EDT 2022 · Advanced Materials · OSTI ID:1598793

Cheng, Chen; Chen, Chi; Chu, Shiyong; +9 more

Related Subjects

25 ENERGY STORAGE

Title: Dissociate lattice oxygen redox reactions from capacity and voltage drops of battery electrodes

Citation Formats

References (49)

Similar Records

Related Subjects