Photocatalytic Transformation of Amines to Imines by Meso-Porous Copper Sulfides

Dutta, Biswanath; Achola, Laura A.; Clarke, Ryan; Sharma, Vinit; He, Junkai; Kerns, Peter; Suib, Steven L.

doi:10.1002/cctc.201900673

Photocatalytic Transformation of Amines to Imines by Meso-Porous Copper Sulfides

Journal Article · Mon Aug 12 00:00:00 EDT 2019 · ChemCatChem

DOI:https://doi.org/10.1002/cctc.201900673· OSTI ID:1598205

Dutta, Biswanath ^[1]; Achola, Laura A. ^[2]; Clarke, Ryan ^[2]; Sharma, Vinit ^[3]; He, Junkai ^[2]; Kerns, Peter ^[2]; ^[2]

Univ. of Connecticut, Storrs, CT (United States); Univ of Connecticut
Univ. of Connecticut, Storrs, CT (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

We have demonstrated a visible-light-driven catalytic process for amine to imine transformations, using a hydrothermal procedure based mesoporous copper sulfide material. The surface chemistry of this heterogeneously catalyzed process, which was further supported by computational calculations, was determined by the reaction kinetics, and reactive oxygen determination studies.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Connecticut, Storrs, CT (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: FG02-86ER13622

OSTI ID:: 1598205

Journal Information:: ChemCatChem, Journal Name: ChemCatChem Journal Issue: 17 Vol. 11; ISSN 1867-3880

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
amine coupling
copper sulfide
imine
mesoporous materials
photocatalysis
reactive oxygen species

Photocatalytic Transformation of Amines to Imines by Meso-Porous Copper Sulfides

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References (47)

Figures / Tables (3)

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