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Durability of ionomer encapsulants in photovoltaic modules

Journal Article · · Solar Energy Materials and Solar Cells
 [1];  [2];  [1];  [1]
  1. Stanford Univ., CA (United States)
  2. National Renewable Energy Lab. (NREL), Golden, CO (United States)
Ethylene vinyl acetate (EVA) has for decades been the preferred material for photovoltaic (PV) module encapsulation. However, while it is relatively inexpensive and initially adheres well to module components, EVA discolors with age and - as interfacial adhesion degrades - becomes susceptible to delamination, ultimately resulting in reduced module efficiency and shortened service lifetimes. As potential replacements for EVA, ionomer thermoplastic materials cure faster, are more resistant to discoloration and potential induced degradation, and do not evolve corrosive acetic acid, making them compatible with new device materials such as perovskites. Since there is limited information on ionomer durability for PV module applications, a series of field and accelerated laboratory aging studies were conducted to assess ionomer interface stability in the presence of terrestrial environmental stressors. It is shown that adhesion to the glass and cell interfaces of PV modules is inferior to EVA, both before and after aging, rendering ionomers particularly susceptible to delamination after short timeframes. Potential solutions to improve ionomer adhesion are discussed.
Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Solar Energy Technologies Office (EE-4S), Bay Area Photovoltaic Consortium
Grant/Contract Number:
AC36-08GO28308; EE0004946
OSTI ID:
1598129
Alternate ID(s):
OSTI ID: 1595184
Report Number(s):
NREL/JA--5K00-75808
Journal Information:
Solar Energy Materials and Solar Cells, Journal Name: Solar Energy Materials and Solar Cells Journal Issue: C Vol. 208; ISSN 0927-0248
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (13)

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Evaluation of moisture ingress from the perimeter of photovoltaic modules
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Effect of ionomer thickness on mode I interlaminar fracture toughness for ionomer toughened CFRP journal November 1999
Acetic acid production and glass transition concerns with ethylene-vinyl acetate used in photovoltaic devices journal February 2007
Determining the degree of crosslinking of ethylene vinyl acetate photovoltaic module encapsulants—A comparative study journal September 2013
Performance and life prediction model for photovoltaic modules: Effect of encapsulant constitutive behavior journal March 2014
Prevention of Potential-Induced Degradation With Thin Ionomer Film journal January 2015
Encapsulant Adhesion to Surface Metallization on Photovoltaic Cells journal November 2017
Defining Threshold Values of Encapsulant and Backsheet Adhesion for PV Module Reliability journal November 2017

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