skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Isotopic evidence for a young lunar magma ocean

Journal Article · · Earth and Planetary Science Letters

Herein, mare basalt sources and ferroan anorthosite suite cumulates define a linear array on a 146Sm/144Nd versus 142Nd/144Nd isochron plot demonstrating these materials were derived from a common reservoir at 4336+31/–32 Ma. The minimum proportion of the Moon that was in isotopic equilibrium at this time is estimated to be 1-3% of its entire volume based on the geographic extent from which the analyzed samples were collected and the calculated depths from which the samples were derived. Scenarios in which large portions of the Moon were molten to depths of many hundreds of kilometers are required to produce the observed Sm-Nd isotopic equilibrium between the mantle and crustal rocks at 4.34 Ga. This is a consequence of the fact that limited heating of a solid Moon above the blocking temperature of the Sm-Nd isotopic system is insufficient to diffusively homogenize radiogenic Nd throughout the mantle and crust. There are three scenarios that might account for global-scale isotopic equilibrium on the Moon relatively late in Solar System history including: (1) Sm-Nd re-equilibration of a solid Moon resulting from widespread melting in response to mantle overturn or a very large impact, (2) early accretion of the Moon followed by delayed cooling due to the presence of an additional heat source that kept a large portion of the Moon molten until 4.34 Ga, or (3) late accretion of the Moon followed by rapid cooling of the magma ocean late in Solar System history. Neither density-driven overturn of the mantle, nor a large impact, are likely to homogenize the mantle and crust to the extent required by the Sm-Nd isochron. Likewise, secondary heating mechanisms, such as tidal heating or radioactive decay, are not efficient enough to keep the Moon molten to the depth of the mare basalt source regions for many tens to hundreds of millions of years. Instead, the age of equilibrium between such a compositionally diverse set of rocks, produced on a global scale, likely records the time of primordial solidification of the Moon from a magma ocean. This scenario accounts for both the petrogenetic characteristics of lunar rock suites, as well as their Sm-Nd isotopic systematics. It is supported by the preponderance of ~4.35 Ga ages obtained for other hypothetical magma ocean crystallization products, such as ferroan anorthosite suite rocks and K, REE, and P enriched cumulates that are thought to represent flotation cumulates of the magma ocean and the last vestiges of magma ocean solidification, respectively.

Research Organization:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA); National Aeronautics and Space Administration (NASA)
Grant/Contract Number:
AC52-07NA27344; NNH12AT84I; NNH16AC441; NNH13AW501; 17-ERD-001
OSTI ID:
1597212
Alternate ID(s):
OSTI ID: 1543057
Report Number(s):
LLNL-JRNL-785027; 974596; TRN: US2103042
Journal Information:
Earth and Planetary Science Letters, Vol. 523, Issue C; ISSN 0012-821X
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 36 works
Citation information provided by
Web of Science

References (39)

142Nd Evidence for Early (>4.53 Ga) Global Differentiation of the Silicate Earth journal July 2005
A young solidification age for the lunar magma ocean journal September 2014
Anatexis of lunar cumulate mantle in time and space: Clues from trace-element, strontium, and neodymium isotopic chemistry of parental Apollo 12 basalts journal July 1997
Experimental petrology and petrogenesis of mare volcanics journal June 1992
The Absolute Chronology and Thermal Processing of Solids in the Solar Protoplanetary Disk journal November 2012
Neodymium Isotope Evidence for a Chondritic Composition of the Moon journal June 2006
Tungsten isotopic evidence for disproportional late accretion to the Earth and Moon journal April 2015
A highly depleted moon or a non-magma ocean origin for the lunar crust? journal October 2007
146Sm-142Nd formation interval for the lunar mantle journal July 1995
A nucleosynthetic origin for the Earth’s anomalous 142Nd composition journal September 2016
Chronology, geochemistry, and petrology of a ferroan noritic anorthosite clast from Descartes breccia 67215: Clues to the age, origin, structure, and impact history of the lunar crust journal April 2003
Accretion timescale and impact history of Mars deduced from the isotopic systematics of martian meteorites journal February 2016
Lunar tungsten isotopic evidence for the late veneer journal April 2015
Structure and Formation of the Lunar Farside Highlands journal November 2010
The origin of KREEP journal January 1979
Oxygen isotopic evidence for vigorous mixing during the Moon-forming giant impact journal January 2016
Satellite-sized planetesimals and lunar origin journal April 1975
Constraints on the formation age and evolution of the Moon from 142Nd–143Nd systematics of Apollo 12 basalts journal June 2014
A review of lunar chronology revealing a preponderance of 4.34-4.37 Ga ages journal November 2014
Coupled thermal–orbital evolution of the early Moon journal July 2010
Stratigraphy of the lunar highland crust; depths of burial of lunar samples from cooling-rate studies journal October 1996
An ancient Sm-Nd age for a ferroan noritic anorthosite clast from lunar breccia 67016 journal July 1994
Non-nucleosynthetic heterogeneity in non-radiogenic stable Hf isotopes: Implications for early solar system chronology journal June 2010
Chronological evidence that the Moon is either young or did not have a global magma ocean journal August 2011
A Shorter 146Sm Half-Life Measured and Implications for 146Sm-142Nd Chronology in the Solar System journal March 2012
A method for purifying Lu and Hf for analyses by MC-ICP-MS using TODGA resin journal September 2006
Density and porosity of the lunar crust from gravity and topography: DENSITY AND POROSITY OF THE LUNAR CRUST journal May 2012
A chemical model for generating the sources of mare basalts: Combined equilibrium and fractional crystallization of the lunar magmasphere journal October 1992
Cooling history of lunar Mg-suite gabbronorite 76255, troctolite 76535 and Stillwater pyroxenite SC-936: The record in exsolution and ordering in pyroxenes journal December 2006
The age of ferroan anorthosite 60025: oldest crust on a young Moon? journal October 1988
Tungsten isotopes and the origin of the Moon journal October 2017
Samarium–neodymium chronology and rubidium–strontium systematics of an Allende calcium–aluminum-rich inclusion with implications for 146Sm half-life journal November 2014
Basaltic magmatism on the Moon: A perspective from volcanic picritic glass beads journal October 1993
Early formation of the Moon 4.51 billion years ago journal January 2017
Oxygen Isotopes and the Moon-Forming Giant Impact journal October 2001
The proto-Earth as a significant source of lunar material journal March 2012
The lunar magma ocean: Reconciling the solidification process with lunar petrology and geochronology journal April 2011
Isotopic evidence for chondritic Lu/Hf and Sm/Nd of the Moon journal October 2013
Re-evaluating 142Nd/144Nd in lunar mare basalts with implications for the early evolution and bulk Sm/Nd of the Moon journal October 2009

Cited By (1)

Geochronology of an Apollo 16 Clast Provides Evidence for a Basin‐Forming Impact 4.3 Billion Years Ago journal October 2019

Similar Records

The timing of lunar solidification and mantle overturn recorded in ferroan anorthosite 62237
Journal Article · Fri May 15 00:00:00 EDT 2020 · Earth and Planetary Science Letters · OSTI ID:1597212

Accretion timescale and impact history of Mars deduced from the isotopic systematics of martian meteorites
Journal Article · Sat Dec 12 00:00:00 EST 2015 · Geochimica et Cosmochimica Acta · OSTI ID:1597212

Sm-Nd systematics of lunar ferroan anorthositic suite rocks: Constraints on lunar crust
Journal Article · Sun Sep 28 00:00:00 EDT 2014 · Geochimica et Cosmochimica Acta · OSTI ID:1597212