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Direct observation of the hcp-bcc phase transition and melting along the principal Hugoniot of Mg

Journal Article · · Physical Review B
 [1];  [2];  [2]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Institute for Shock Physics, Washington State University
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Time-resolved x-ray diffraction was used to examine the phase evolution of polycrystalline Mg shocked along the principal Hugoniot to states that span multiple phase boundaries into the liquid. Here, the diffraction data indicate that the hcp-bcc phase boundary lies above 27 GPa, with the hcp-bcc transition occurring within nanoseconds of loading. Experiments at 55 GPa reveal a mixture of bcc and liquid, indicating incipient melt occurring 10–15 GPa lower than previously reported, with complete melting observed at 63 GPa.

Research Organization:
Washington State Univ., Pullman, WA (United States). Inst. for Shock Physics
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA), Office of Defense Programs (DP) (NA-10); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division
Grant/Contract Number:
NA0002442; 89233218CNA000001; AC02-06CH11357
OSTI ID:
1595283
Alternate ID(s):
OSTI ID: 1597351
OSTI ID: 1598009
Journal Information:
Physical Review B, Journal Name: Physical Review B Journal Issue: 2 Vol. 101; ISSN 2469-9950; ISSN PRBMDO
Publisher:
American Physical Society (APS)Copyright Statement
Country of Publication:
United States
Language:
English

References (42)

Shock Wave Compression of Condensed Matter book January 2012
Mg partitioning between solid and liquid iron under the Earth’s core conditions journal January 2018
Crystal Structures and Exotic Behavior of Magnesium under Pressure journal November 2010
In Situ Observations of Phase Changes in Shock Compressed Forsterite journal August 2018
Melting of iron at the physical conditions of the Earth's core journal January 2004
Powering Earth’s dynamo with magnesium precipitation from the core journal January 2016
Ultrafast visualization of crystallization and grain growth in shock-compressed SiO2 journal September 2015
Erratum: Ultrafast visualization of crystallization and grain growth in shock-compressed SiO2 journal October 2015
A metastable limit for compressed liquid water journal March 2007
Strong, Ductile, and Thermally Stable bcc-Mg Nanolaminates journal August 2017
Model of plastic deformation for extreme loading conditions journal January 2003
Ab initio thermodynamics and phase diagram of solid magnesium: A comparison of the LDA and GGA journal November 2006
Direct measurements of the α-ϵ transition stress and kinetics for shocked iron journal May 2009
A constitutive model for metals applicable at high‐strain rate journal March 1980
Dislocation‐mechanics‐based constitutive relations for material dynamics calculations journal March 1987
The laser shock station in the dynamic compression sector. I journal May 2019
Stability of body-centered cubic iron–magnesium alloys in the Earth's inner core journal September 2009
Magnesium under pressure: structure and phase transition journal October 2003
Study of the phase transformations and equation of state of magnesium by synchrotron x-ray diffraction journal February 2003
High-pressure structural phase transition in Mg journal April 1985
Theoretical model for the hcp-bcc transition in Mg journal April 1988
Phase diagram and thermodynamic properties of solid magnesium in the quasiharmonic approximation journal November 1993
First-principles temperature-pressure phase diagram of magnesium journal March 1995
Metastability and dynamics of the shock-induced phase transition in iron journal February 1997
Melting of the alkaline-earth metals to 80 GPa journal December 2001
Ab initio calculations for the elastic properties of magnesium under pressure journal September 2009
In situ lattice measurement of the bcc phase boundary in Mg on the principal shock Hugoniot journal July 2012
Equation of state and high-pressure/high-temperature phase diagram of magnesium journal October 2014
Structural transformations including melting and recrystallization during shock compression and release of germanium up to 45 GPa journal April 2019
Dense Low-Coordination Phases of Lithium journal April 2009
Direct Observation of Melting in Shock-Compressed Bismuth With Femtosecond X-ray Diffraction journal August 2015
Compression Freezing Kinetics of Water to Ice VII journal July 2017
Direct Observations of a Dynamically Driven Phase Transition with in situ X-Ray Diffraction in a Simple Ionic Crystal journal December 2017
In situ X-Ray Diffraction of Shock-Compressed Fused Silica journal March 2018
Nanosecond Melting and Recrystallization in Shock-Compressed Silicon journal September 2018
Nanosecond Freezing of Water at High Pressures: Nucleation and Growth near the Metastability Limit journal October 2018
Measurement of Body-Centered Cubic Gold and Melting under Shock Compression journal July 2019
Structural Transformation and Melting in Gold Shock Compressed to 355 GPa journal July 2019
High-Pressure Structural Phase Transitions in Na, Mg, and Al journal March 1982
Beating the Miscibility Barrier between Iron Group Elements and Magnesium by High-Pressure Alloying journal December 2005
GSAS-II : the genesis of a modern open-source all purpose crystallography software package journal March 2013
HiSPoD : a program for high-speed polychromatic X-ray diffraction experiments and data analysis on polycrystalline samples journal June 2016

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