Imaging the inelastic scattering of vibrationally excited NO (ν=1) with Ar

Kamasah, Alexander; Li, Hongwei; Onvlee, Jolijn; van der Avoird, Ad; Parker, David H.; Suits, Arthur G.

doi:10.1016/j.cplett.2017.12.016

Imaging the inelastic scattering of vibrationally excited NO (ν=1) with Ar

Journal Article · Thu Dec 07 00:00:00 EST 2017 · Chemical Physics Letters

DOI:https://doi.org/10.1016/j.cplett.2017.12.016· OSTI ID:1595253

Kamasah, Alexander ^[1]; Li, Hongwei ^[2]; Onvlee, Jolijn ^[3]; van der Avoird, Ad ^[4]; Parker, David H. ^[4]; Suits, Arthur G. ^[2]

Univ. of Missouri, Columbia, MO (United States); U. Missouri
Univ. of Missouri, Columbia, MO (United States)
Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Radboud Univ., Nijmegen (The Netherlands)
Radboud Univ., Nijmegen (The Netherlands)

The inelastic scattering of vibrationally excited NO (v = 1) with Ar at a collision energy of 3.0 kcal mol^-1 was investigated in crossed beams. Vibrationally excited NO was generated by flash heating and rotationally cooled by the supersonic expansion. The differential cross sections were compared to those of the vibrational ground state NO (v = 0) with Ar, which were also compared to theoretical calculations for scattering from the ground vibrational level. Finally, the differential cross sections show a similar strong j dependence of the rotational rainbow maxima from the inelastic scattering for both NO (v = 0) and (v = 1) but no significant differences between NO (v = 0) and (v = 1) were seen.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Missouri, Columbia, MO (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: SC0017130

OSTI ID:: 1595253

Alternate ID(s):: OSTI ID: 1630961

Journal Information:: Chemical Physics Letters, Journal Name: Chemical Physics Letters Journal Issue: C Vol. 692; ISSN 0009-2614

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (31)

The Spectrum of Nitric Oxide Between 1700 and 2100 cm−1 Coudert, L. H.; Dana, V.; Mandin, J. Y. Journal of Molecular Spectroscopy, Vol. 172, Issue 2 https://doi.org/10.1006/jmsp.1995.1191	journal	August 1995
Far-Infrared Rotational and Fine-Structure Transition Frequencies and Molecular Constants of 14NO and 15NO in the X2Π (v = 0) State Varberg, Thomas D.; Stroh, Fred; Evenson, Kenneth M. Journal of Molecular Spectroscopy, Vol. 196, Issue 1 https://doi.org/10.1006/jmsp.1999.7850	journal	July 1999
State-to-state rotational and electronic collisional relaxation study of nitric oxide Sudbo, A. S.; Loy, M. M. T. Chemical Physics Letters, Vol. 82, Issue 1 https://doi.org/10.1016/0009-2614(81)85123-8	journal	August 1981
Alignment effects in the multiple photon ionisation of nitric oxide Booth, J. P.; Bragg, S. L.; Hancock, G. Chemical Physics Letters, Vol. 113, Issue 6 https://doi.org/10.1016/0009-2614(85)85022-3	journal	February 1985
Vibrational relaxation of NO(X2Π, υ = 1) studied by an IR-UV-double-resonance technique Kosanetzky, J.; List, U.; Urban, W. Chemical Physics, Vol. 50, Issue 3 https://doi.org/10.1016/0301-0104(80)85106-8	journal	September 1980
Calculation of transition frequencies and rotational line strengths in the γ-bands of nitric oxide Paul, P. H. Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 57, Issue 5 https://doi.org/10.1016/S0022-4073(96)00158-6	journal	May 1997
Sign of the state-to-state steric asymmetry of rotationally inelastic atom–molecule collisions Gijsbertsen, A.; de Lange, M. J. L.; Wiskerke, A. E. Chemical Physics, Vol. 301, Issue 2-3 https://doi.org/10.1016/j.chemphys.2004.02.003	journal	June 2004
State-resolved differential cross sections for crossed-beam argon-nitric oxide inelastic scattering by direct ion imaging Bontuyan, L. S.; Suits, A. G.; Houston, P. L. The Journal of Physical Chemistry, Vol. 97, Issue 24 https://doi.org/10.1021/j100126a006	journal	June 1993
Quantum Interference as the Source of Steric Asymmetry and Parity Propensity Rules in NO−Rare Gas Inelastic Scattering Gijsbertsen, Arjan; Linnartz, Harold; Taatjes, Craig A. Journal of the American Chemical Society, Vol. 128, Issue 27 https://doi.org/10.1021/ja057828b	journal	July 2006
Differential Cross Section for Rotationally Inelastic Scattering of Vibrationally Excited NO( v =5) from Ar Dixit, Amitavikram A.; Pisano, Patrick J.; Houston, Paul L. The Journal of Physical Chemistry A, Vol. 105, Issue 50 https://doi.org/10.1021/jp012318z	journal	December 2001
Crossed-Beam Slice Imaging of Cl Reaction Dynamics with Butene Isomers Joalland, Baptiste; Van Camp, Richard; Shi, Yuanyuan The Journal of Physical Chemistry A, Vol. 117, Issue 32 https://doi.org/10.1021/jp403030s	journal	June 2013
Strong-Field Ionization of Flash Pyrolysis Reaction Products Cudry, Fadia; Oldham, James M.; Lingenfelter, Steven The Journal of Physical Chemistry A, Vol. 119, Issue 3 https://doi.org/10.1021/jp510552a	journal	January 2015
Interference structures in the differential cross-sections for inelastic scattering of NO by Ar Eyles, C. J.; Brouard, M.; Yang, C. -H. Nature Chemistry, Vol. 3, Issue 8 https://doi.org/10.1038/nchem.1071	journal	June 2011
State-resolved diffraction oscillations imaged for inelastic collisions of NO radicals with He, Ne and Ar von Zastrow, Alexander; Onvlee, Jolijn; Vogels, Sjoerd N. Nature Chemistry, Vol. 6, Issue 3 https://doi.org/10.1038/nchem.1860	journal	February 2014
Fully Λ-doublet resolved state-to-state differential cross-sections for the inelastic scattering of NO(X) with Ar Eyles, C. J.; Brouard, M.; Chadwick, H. Physical Chemistry Chemical Physics, Vol. 14, Issue 16 https://doi.org/10.1039/c2cp23258h	journal	January 2012
Flash pyrolysis nozzle for generation of radicals in a supersonic jet expansion Kohn, Daniel W.; Clauberg, Horst; Chen, Peter Review of Scientific Instruments, Vol. 63, Issue 8 https://doi.org/10.1063/1.1143254	journal	August 1992
Velocity map imaging of ions and electrons using electrostatic lenses: Application in photoelectron and photofragment ion imaging of molecular oxygen Eppink, André T. J. B.; Parker, David H. Review of Scientific Instruments, Vol. 68, Issue 9 https://doi.org/10.1063/1.1148310	journal	September 1997
State-to-state differential cross sections for spin–multiplet-changing collisions of NO(X 2Π1/2) with argon Elioff, Michael S.; Chandler, David W. The Journal of Chemical Physics, Vol. 117, Issue 14 https://doi.org/10.1063/1.1505440	journal	October 2002
Differential cross sections for collisions of hexapole state-selected NO with He Gijsbertsen, A.; Linnartz, H.; Rus, G. The Journal of Chemical Physics, Vol. 123, Issue 22 https://doi.org/10.1063/1.2126969	journal	December 2005
Reduction of 1+1 resonance enhanced MPI spectra to population distributions: Application to the NO A ² Σ ⁺ – X ² Π system Jacobs, D. C.; Madix, R. J.; Zare, R. N. The Journal of Chemical Physics, Vol. 85, Issue 10 https://doi.org/10.1063/1.451557	journal	November 1986
Differential cross sections for state‐selected products by direct imaging: Ar+NO Suits, A. G.; Bontuyan, L. S.; Houston, P. L. The Journal of Chemical Physics, Vol. 96, Issue 11 https://doi.org/10.1063/1.462265	journal	June 1992
A combined experimental and theoretical study of rotational energy transfer in collisions between NO(X 2Π1/2, v=3,J) and He, Ar and N2 at temperatures down to 7 K James, Philip L.; Sims, Ian R.; Smith, Ian W. M. The Journal of Chemical Physics, Vol. 109, Issue 10 https://doi.org/10.1063/1.476517	journal	September 1998
A new, fully ab initio investigation of the NO(X 2Π)Ar system. I. Potential energy surfaces and inelastic scattering Alexander, Millard H. The Journal of Chemical Physics, Vol. 111, Issue 16 https://doi.org/10.1063/1.480066	journal	October 1999
Investigation of steric effects in inelastic collisions of NO(X 2Π) with Ar Alexander, Millard H.; Stolte, Steven The Journal of Chemical Physics, Vol. 112, Issue 18 https://doi.org/10.1063/1.481401	journal	May 2000
Note: A short-pulse high-intensity molecular beam valve based on a piezoelectric stack actuator Abeysekera, Chamara; Joalland, Baptiste; Shi, Yuanyuan Review of Scientific Instruments, Vol. 85, Issue 11 https://doi.org/10.1063/1.4902153	journal	November 2014
Resolving rainbows with superimposed diffraction oscillations in NO + rare gas scattering: experiment and theory Onvlee, Jolijn; Vogels, Sjoerd N.; Avoird, Ad van der New Journal of Physics, Vol. 17, Issue 5 https://doi.org/10.1088/1367-2630/17/5/055019	journal	May 2015
Direct Measurement of the Preferred Sense of NO Rotation After Collision with Argon Lorenz, K. T. Science, Vol. 293, Issue 5537 https://doi.org/10.1126/science.1062754	journal	September 2001
Fully State-Resolved Differential Cross Sections for the Inelastic Scattering of the Open-Shell NO Molecule by Ar Kohguchi, H. Science, Vol. 294, Issue 5543 https://doi.org/10.1126/science.1063774	journal	October 2001
Molecular Beam Studies of Elementary Chemical Processes Lee, Y. T. Science, Vol. 236, Issue 4803 https://doi.org/10.1126/science.236.4803.793	journal	May 1987
Scattering of Stark-decelerated OH radicals with rare-gas atoms Scharfenberg, L.; Gubbels, K. B.; Kirste, M. The European Physical Journal D, Vol. 65, Issue 1-2 https://doi.org/10.1140/epjd/e2011-20009-4	journal	April 2011
Analysis of velocity-mapped ion images from high-resolution crossed-beam scattering experiments: a tutorial review von Zastrow, Alexander; Onvlee, Jolijn; Parker, David H. EPJ Techniques and Instrumentation, Vol. 2, Issue 1 https://doi.org/10.1140/epjti/s40485-015-0020-z	journal	July 2015

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