Probing direct carbon-carbon acylation of furans and long-chain acids over H-ZSM-5

Ji, Yichen; Pan, Jie; Dauenhauer, Paul; Gorte, Raymond J.

doi:10.1016/j.apcata.2019.03.012

Probing direct carbon-carbon acylation of furans and long-chain acids over H-ZSM-5

Journal Article · Thu Mar 21 00:00:00 EDT 2019 · Applied Catalysis. A, General

DOI:https://doi.org/10.1016/j.apcata.2019.03.012· OSTI ID:1594768

^[1]; Pan, Jie ^[2]; Dauenhauer, Paul ^[3]; Gorte, Raymond J. ^[4]

Univ. of Pennsylvania, Philadelphia, PA (United States); University of Pennsylvania
Univ. of Pennsylvania, Philadelphia, PA (United States)
Univ. of Minnesota, Minneapolis, MN (United States); Univ. of Delaware, Newark, DE (United States)
Univ. of Pennsylvania, Philadelphia, PA (United States); Univ. of Delaware, Newark, DE (United States)

The acylation of furan and 2-methylfuran (2-MF) with acetic acid (AA) and 1-hexanoic acid (HA) was studied over an H-ZSM-5 catalyst. Temperature-programmed desorption (TPD) measurements showed evidence that AA adsorbs strongly at Brønsted sites, with reaction to CO₂ and acetone beginning at 523 K, while both furan and 2-MF oligomerize upon adsorption at room temperature. Steady-state, flow-reactor measurements demonstrate that selectivities for the acylation reactions can approach 100% below 523 K when reactions are operated in excess organic acids, with maximum conversion limited by equilibrium. Coking becomes important when the reaction is operated in excess furan or 2-MF and at high reactant concentrations, while ketonization products are observed when the reaction is performed above 523 K. Lastly, potential uses for the reactions are discussed.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI); Univ. of Pennsylvania, Philadelphia, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0001004

OSTI ID:: 1594768

Journal Information:: Applied Catalysis. A, General, Journal Name: Applied Catalysis. A, General Journal Issue: C Vol. 577; ISSN 0926-860X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Probing direct carbon-carbon acylation of furans and long-chain acids over H-ZSM-5

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