Surface-reaction induced structural oscillations in the subsurface

Sun, Xianhu; Zhu, Wenhui; Wu, Dongxiang; Li, Chaoran; Wang, Jianyu; Zhu, Yaguang; Chen, Xiaobo; Boscoboinik, Jorge Anibal; Sharma, Renu; Zhou, Guangwen

doi:10.1038/s41467-019-14167-1

Title: Surface-reaction induced structural oscillations in the subsurface

Journal Article · Thu Jan 16 00:00:00 EST 2020 · Nature Communications

DOI:https://doi.org/10.1038/s41467-019-14167-1· OSTI ID:1619731

Sun, Xianhu; Zhu, Wenhui; Wu, Dongxiang; Li, Chaoran; Wang, Jianyu; Zhu, Yaguang; Chen, Xiaobo;

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Surface and subsurface are commonly considered as separate entities because of the difference in the bonding environment and are often investigated separately due to the experimental challenges in differentiating the surface and subsurface effects. Using in-situ atomic-scale transmission electron microscopy to resolve the surface and subsurface at the same time, we show that the hydrogen-CuO surface reaction results in structural oscillations in deeper atomic layers via the cycles of ordering and disordering of oxygen vacancies in the subsurface. Together with atomistic calculations, we show that the structural oscillations in the subsurface are induced by the hydrogen oxidation induced cyclic loss of oxygen from the oxide surface. These results demonstrate the propagation of the surface reaction dynamics into the deeper layers in inducing nonstoichiometry in the subsurface and have significant implications in modulating various chemical processes involving surface-subsurface mass transport such as heterogeneous catalysis, oxidation, corrosion and carburization.

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Research Organization:: State Univ. of New York (SUNY), Binghamton, NY (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN) and National Synchrotron Light Source II (NSLS-II); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: SC0001135; SC0012704; OCI-1053575

OSTI ID:: 1619731

Alternate ID(s):: OSTI ID: 1593988; OSTI ID: 1603753; OSTI ID: 1808966; OSTI ID: 1864758

Report Number(s):: BNL-213699-2020-JAAM; BNL-221861-2021-JACI; 305; PII: 14167

Journal Information:: Nature Communications, Journal Name: Nature Communications Vol. 11 Journal Issue: 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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Cited by: 16 works

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