Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design

Saparov, Bayrammurad; Mitzi, David B.

doi:10.1021/acs.chemrev.5b00715

Title: Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design

Journal Article · Mon Apr 04 00:00:00 EDT 2016 · Chemical Reviews

DOI:https://doi.org/10.1021/acs.chemrev.5b00715· OSTI ID:1593872

Saparov, Bayrammurad ^[1]; Mitzi, David B. ^[1]

Duke Univ., Durham, NC (United States). Dept. of Mechanical Engineering and Materials Science and Dept. of Chemistry

Although known since the late 19th century, organic–inorganic perovskites have recently received extraordinary research community attention because of their unique physical properties, which make them promising candidates for application in photovoltaic (PV) and related optoelectronic devices. In this review, we will explore beyond the current focus on three-dimensional (3-D) lead(II) halide perovskites, to highlight the great chemical flexibility and outstanding potential of the broader class of 3-D and lower dimensional organic-based perovskite family for electronic, optical, and energy-based applications as well as fundamental research. The concept of a multifunctional organic–inorganic hybrid, in which the organic and inorganic structural components provide intentional, unique, and hopefully synergistic features to the compound, represents an important contemporary target.

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Research Organization:: Duke Univ., Durham, NC (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0006712; AC05-06OR23100

OSTI ID:: 1593872

Journal Information:: Chemical Reviews, Vol. 116, Issue 7; ISSN 0009-2665

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Integrated Perovskite/Bulk‐Heterojunction Organic Solar Cells Liu, Yongsheng; Chen, Yongsheng Advanced Materials, Vol. 32, Issue 3 https://doi.org/10.1002/adma.201805843	journal	February 2019
Conductivity Tuning via Doping with Electron Donating and Withdrawing Molecules in Perovskite CsPbI ₃ Nanocrystal Films Gaulding, E. Ashley; Hao, Ji; Kang, Hyun Suk Advanced Materials, Vol. 31, Issue 27 https://doi.org/10.1002/adma.201902250	journal	May 2019
Optimization of Low‐Dimensional Components of Quasi‐2D Perovskite Films for Deep‐Blue Light‐Emitting Diodes Yuan, Shuai; Wang, Zhao‐Kui; Xiao, Lei‐Xin Advanced Materials, Vol. 31, Issue 44 https://doi.org/10.1002/adma.201904319	journal	September 2019
Defect Engineering toward Highly Efficient and Stable Perovskite Solar Cells Li, Bowei; Ferguson, Victoria; Silva, S. Ravi P. Advanced Materials Interfaces, Vol. 5, Issue 22 https://doi.org/10.1002/admi.201800326	journal	July 2018
Morphology-Tailored Halide Perovskite Platelets and Wires: From Synthesis, Properties to Optoelectronic Devices Liu, Zhixiong; Mi, Yang; Guan, Xinwei Advanced Optical Materials, Vol. 6, Issue 17 https://doi.org/10.1002/adom.201800413	journal	July 2018
Spintronics of Hybrid Organic–Inorganic Perovskites: Miraculous Basis of Integrated Optoelectronic Devices Liao, Kun; Hu, Xiaoyong; Cheng, Yinke Advanced Optical Materials, Vol. 7, Issue 15 https://doi.org/10.1002/adom.201900350	journal	June 2019
Negative Thermal Quenching of Efficient White‐Light Emission in a 1D Ladder‐Like Organic/Inorganic Hybrid Material Barkaoui, Hamdi; Abid, Haitham; Zelewski, Szymon Advanced Optical Materials, Vol. 7, Issue 20 https://doi.org/10.1002/adom.201900763	journal	July 2019
Perovskite Tandem Solar Cells Lal, Niraj N.; Dkhissi, Yasmina; Li, Wei Advanced Energy Materials, Vol. 7, Issue 18 https://doi.org/10.1002/aenm.201602761	journal	May 2017
Thermodynamically Self-Healing 1D-3D Hybrid Perovskite Solar Cells Fan, Jiandong; Ma, Yunping; Zhang, Cuiling Advanced Energy Materials, Vol. 8, Issue 16 https://doi.org/10.1002/aenm.201703421	journal	March 2018
Stable Dynamics Performance and High Efficiency of ABX ₃ ‐Type Super‐Alkali Perovskites First Obtained by Introducing H ₅ O ₂ Cation Zhou, Tingwei; Wang, Ming; Zang, Zhigang Advanced Energy Materials, Vol. 9, Issue 29 https://doi.org/10.1002/aenm.201900664	journal	June 2019
Hole-Transporting Materials for Perovskite Solar Cells Liu, Fan; Li, Qianqian; Li, Zhen Asian Journal of Organic Chemistry, Vol. 7, Issue 11 https://doi.org/10.1002/ajoc.201800398	journal	September 2018
A Zero-Dimensional Organic Seesaw-Shaped Tin Bromide with Highly Efficient Strongly Stokes-Shifted Deep-Red Emission Zhou, Chenkun; Lin, Haoran; Shi, Hongliang Angewandte Chemie, Vol. 130, Issue 4 https://doi.org/10.1002/ange.201710383	journal	December 2017
A Flexible Composite Mechanical Energy Harvester from a Ferroelectric Organoamino Phosphonium Salt Vijayakanth, Thangavel; Srivastava, Anant Kumar; Ram, Farsa Angewandte Chemie, Vol. 130, Issue 29 https://doi.org/10.1002/ange.201805479	journal	June 2018
Flexible Perowskit‐Solarzellen: Herstellung und Anwendungen Yang, Dong; Yang, Ruixia; Priya, Shashank Angewandte Chemie, Vol. 131, Issue 14 https://doi.org/10.1002/ange.201809781	journal	February 2019
Hybrid Organic–Inorganic Antiperovskites Shi, Chao; Yu, Hui; Wang, Qin‐Wen Angewandte Chemie, Vol. 132, Issue 1 https://doi.org/10.1002/ange.201908945	journal	November 2019
Exploring Lead‐Free Hybrid Double Perovskite Crystals of (BA) ₂ CsAgBiBr ₇ with Large Mobility‐Lifetime Product toward X‐Ray Detection Xu, Zhiyun; Liu, Xin; Li, Yaobin Angewandte Chemie, Vol. 131, Issue 44 https://doi.org/10.1002/ange.201909815	journal	September 2019
Lead-free Perovskite Materials (NH ₄ ) ₃ Sb ₂ I _x Br _{9− x} Zuo, Chuantian; Ding, Liming Angewandte Chemie International Edition, Vol. 56, Issue 23 https://doi.org/10.1002/anie.201702265	journal	April 2017
Hybrid Halide Perovskites: Discussions on Terminology and Materials Mercier, Nicolas Angewandte Chemie International Edition, Vol. 58, Issue 50 https://doi.org/10.1002/anie.201909601	journal	October 2019
Reversible Thermochromism and Strong Ferromagnetism in Two-Dimensional Hybrid Perovskites Sun, Bing; Liu, Xiao-Fei; Li, Xiang-Yang Angewandte Chemie International Edition, Vol. 59, Issue 1 https://doi.org/10.1002/anie.201910701	journal	November 2019
(CH ₃ NH ₃ )AuX ₄ ⋅H ₂ O (X=Cl, Br) and (CH ₃ NH ₃ )AuCl ₄ : Low‐Band Gap Lead‐Free Layered Gold Halide Perovskite Materials Worley, Chris; Yangui, Aymen; Roccanova, Rachel Chemistry – A European Journal, Vol. 25, Issue 42 https://doi.org/10.1002/chem.201901112	journal	July 2019
Multilayered 2D Cesium‐Based Hybrid Perovskite with Strong Polarization Sensitivity: Dimensional Reduction of CsPbBr ₃ Liu, Yi; Wang, Jiaqi; Han, Shiguo Chemistry – A European Journal, Vol. 26, Issue 16 https://doi.org/10.1002/chem.201905531	journal	March 2020
Potential Substitutes for Replacement of Lead in Perovskite Solar Cells: A Review Kour, Ravinder; Arya, Sandeep; Verma, Sonali Global Challenges, Vol. 3, Issue 11 https://doi.org/10.1002/gch2.201900050	journal	July 2019
2D and Quasi‐2D Halide Perovskites: Applications and Progress Kim, Hyojung; Huynh, Kim Anh; Kim, Soo Young physica status solidi (RRL) – Rapid Research Letters, Vol. 14, Issue 2 https://doi.org/10.1002/pssr.201900435	journal	September 2019
Revealing the Cooperative Chemistry of the Organic Cation in the Methylammonium Lead Triiodide Perovskite Semiconductor System Varadwaj, Arpita; Varadwaj, Pradeep R.; Yamashita, Koichi ChemistrySelect, Vol. 3, Issue 25 https://doi.org/10.1002/slct.201703089	journal	July 2018
Perovskite Nanoparticles: Synthesis, Properties, and Novel Applications in Photovoltaics and LEDs Kulkarni, Sneha A.; Mhaisalkar, Subodh G.; Mathews, Nripan Small Methods, Vol. 3, Issue 1 https://doi.org/10.1002/smtd.201800231	journal	October 2018
Melamine Hydroiodide Functionalized MAPbI ₃ Perovskite with Enhanced Photovoltaic Performance and Stability in Ambient Atmosphere Yang, Fu; Kamarudin, Muhammad A.; Hirotani, Daisuke Solar RRL, Vol. 3, Issue 1 https://doi.org/10.1002/solr.201800275	journal	November 2018
Synthesis, structure, and properties of Schiff base iodobismuthate and its alteration in DMSO solution Shestimerova, T. A.; Golubev, N. A.; Mironov, A. V. Russian Chemical Bulletin, Vol. 67, Issue 7 https://doi.org/10.1007/s11172-018-2204-6	journal	July 2018
Dimensionality engineering of hybrid halide perovskite light absorbers Gao, Peng; Bin Mohd Yusoff, Abd Rashid; Nazeeruddin, Mohammad Khaja Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-07382-9	journal	November 2018
Molecular engineering of organic–inorganic hybrid perovskites quantum wells Gao, Yao; Shi, Enzheng; Deng, Shibin Nature Chemistry, Vol. 11, Issue 12 https://doi.org/10.1038/s41557-019-0354-2	journal	November 2019
An integrated approach towards the fabrication of highly efficient and long-term stable perovskite nanowire solar cells Chang, Chih-Yu; Tsai, Bo-Chou; Lin, Min-Zhen Journal of Materials Chemistry A, Vol. 5, Issue 43 https://doi.org/10.1039/c7ta07968k	journal	January 2017
Enhanced performance of perovskite/organic-semiconductor hybrid heterojunction photodetectors with the electron trapping effects Xie, Chao; Yan, Feng Journal of Materials Chemistry C, Vol. 6, Issue 6 https://doi.org/10.1039/c7tc05321e	journal	January 2018
Structural effects on optoelectronic properties of halide perovskites Chen, Kun; Schünemann, Stefan; Song, Seulki Chemical Society Reviews, Vol. 47, Issue 18 https://doi.org/10.1039/c8cs00212f	journal	January 2018
Tunable CsPbBr ₃ /Cs ₄ PbBr ₆ phase transformation and their optical spectroscopic properties Chen, Xiao; Chen, Daqin; Li, Junni Dalton Transactions, Vol. 47, Issue 16 https://doi.org/10.1039/c8dt00430g	journal	January 2018
A facile synthesis of two new IR optical perovskites based on 1,4-diazabicyclo[2,2,2]octane with a high laser damage threshold Song, Jun-Ling; Chen, Wen-Jun; Chu, Kai-Bin Dalton Transactions, Vol. 47, Issue 41 https://doi.org/10.1039/c8dt03047b	journal	January 2018
Successive near-room-temperature dielectric phase transitions in a lead-free hybrid perovskite-like compound Zhang, Jing; Han, Shiguo; Liu, Xitao Inorganic Chemistry Frontiers, Vol. 6, Issue 1 https://doi.org/10.1039/c8qi01097h	journal	January 2019
Recent progressive efforts in perovskite solar cells toward commercialization Kim, Byeong Jo; Lee, Sangwook; Jung, Hyun Suk Journal of Materials Chemistry A, Vol. 6, Issue 26 https://doi.org/10.1039/c8ta02159g	journal	January 2018
Interfacial engineering for highly efficient quasi-two dimensional organic–inorganic hybrid perovskite light-emitting diodes Liu, Qing-Wei; Yuan, Shuai; Sun, Shuang-Qiao Journal of Materials Chemistry C, Vol. 7, Issue 15 https://doi.org/10.1039/c8tc06490c	journal	January 2019
Temperature dependent geometry in perovskite microcrystals for whispering gallery and Fabry–Pérot mode lasing Li, Bobo; Zhou, Taojie; Fang, Xuan Journal of Materials Chemistry C, Vol. 7, Issue 14 https://doi.org/10.1039/c8tc06576d	journal	January 2019
Enhanced yield-mobility products in hybrid halide Ruddlesden–Popper compounds with aromatic ammonium spacers Venkatesan, Naveen R.; Mahdi, Ali; Barraza, Brian Dalton Transactions, Vol. 48, Issue 37 https://doi.org/10.1039/c9dt03074c	journal	January 2019
Effect of interlayer spacing in layered perovskites on resistive switching memory Kim, So-Yeon; Yang, June-Mo; Choi, Eun-Suk Nanoscale, Vol. 11, Issue 30 https://doi.org/10.1039/c9nr00438f	journal	January 2019
Simple fabrication of layered halide perovskite platelets and enhanced photoluminescence from mechanically exfoliated flakes Dhanabalan, Balaji; Castelli, Andrea; Palei, Milan Nanoscale, Vol. 11, Issue 17 https://doi.org/10.1039/c9nr00638a	journal	January 2019
Understanding the mechanism of metal-induced degradation in perovskite nanocrystals Saris, Seryio; Niemann, Valerie; Mantella, Valeria Nanoscale, Vol. 11, Issue 41 https://doi.org/10.1039/c9nr06328e	journal	January 2019
Semiconducting crystalline inorganic–organic hybrid metal halide nanochains Wang, Guan-E; Sun, Cai; Wang, Ming-Sheng Nanoscale, Vol. 12, Issue 8 https://doi.org/10.1039/c9nr10164k	journal	January 2020
Additive-assisted synthesis and optoelectronic properties of (CH ₃ NH ₃ ) ₄ Bi ₆ I ₂₂ Sharma, Manila; Yangui, Aymen; Lusson, Alain Inorganic Chemistry Frontiers, Vol. 7, Issue 7 https://doi.org/10.1039/c9qi01574d	journal	January 2020
Ethylammonium as an alternative cation for efficient perovskite solar cells from first-principles calculations Liu, Diwen; Li, Qiaohong; Wu, Kechen RSC Advances, Vol. 9, Issue 13 https://doi.org/10.1039/c9ra00853e	journal	January 2019
Enhancing the phosphorescence of hybrid metal halides through molecular sensitization Gong, Liao-Kuo; Li, Jian-Rong; Wu, Zhao-Feng Journal of Materials Chemistry C, Vol. 7, Issue 32 https://doi.org/10.1039/c9tc03067k	journal	January 2019
Efficient charge separation at multiple quantum well perovskite/PCBM interface Wei, Yingqiang; Li, Meijin; Li, Renzhi Applied Physics Letters, Vol. 113, Issue 4 https://doi.org/10.1063/1.5045277	journal	July 2018
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Solvent-free synthesis of organometallic halides CH ₃ NH ₃ PbI ₃ and (CH ₃ NH ₃ ) ₃ Bi ₂ I ₉ and their thermoelectric transport properties Long, Xiang; Pan, Zhenyu; Zhang, Zhuolei Applied Physics Letters, Vol. 115, Issue 7 https://doi.org/10.1063/1.5113535	journal	August 2019
Structural and thermodynamic limits of layer thickness in 2D halide perovskites Soe, Chan Myae Myae; Nagabhushana, G. P.; Shivaramaiah, Radha Proceedings of the National Academy of Sciences, Vol. 116, Issue 1 https://doi.org/10.1073/pnas.1811006115	journal	December 2018
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Structural and spectral dynamics of single-crystalline Ruddlesden-Popper phase halide perovskite blue light-emitting diodes Chen, Hong; Lin, Jia; Kang, Joohoon Science Advances, Vol. 6, Issue 4 https://doi.org/10.1126/sciadv.aay4045	journal	January 2020
First representatives of (210)-oriented perovskite variants−Synthesis, crystal structures and properties of the new 2D hybrid perovskites A[HC(NH2)2]PbI4; A=[C(NH2)3], [HSC(NH2)2] Daub, Michael; Hillebrecht, Harald Zeitschrift für Kristallographie - Crystalline Materials, Vol. 233, Issue 8 https://doi.org/10.1515/zkri-2018-2055	journal	July 2018
Lead-free hybrid perovskites for photovoltaics Stroyuk, Oleksandr Beilstein Journal of Nanotechnology, Vol. 9 https://doi.org/10.3762/bjnano.9.207	journal	January 2018
Inch-Size Single Crystal of a Lead-Free Organic-Inorganic Hybrid Perovskite for High-Performance Photodetector Ji, Chengmin; Wang, Peng; Wu, Zhenyue Advanced Functional Materials, Vol. 28, Issue 14 https://doi.org/10.1002/adfm.201705467	journal	January 2018
A Facile Preparative Route of Nanoscale Perovskites over Mesoporous Metal Oxide Films and Their Applications to Photosensitizers and Light Emitters Lee, Hyo Joong; Cho, Kyung Taek; Paek, Sanghyun Advanced Functional Materials, Vol. 28, Issue 39 https://doi.org/10.1002/adfm.201803801	journal	August 2018
Oriented Quasi-2D Perovskites for High Performance Optoelectronic Devices Yang, Rong; Li, Renzhi; Cao, Yu Advanced Materials, Vol. 30, Issue 51 https://doi.org/10.1002/adma.201804771	journal	October 2018
Halide Perovskites for Nonlinear Optics Xu, Jialiang; Li, Xinyue; Xiong, Jianbo Advanced Materials, Vol. 32, Issue 3 https://doi.org/10.1002/adma.201806736	journal	March 2019
H/F‐Substitution‐Induced Homochirality for Designing High‐ T _c Molecular Perovskite Ferroelectrics Tang, Yuan‐Yuan; Ai, Yong; Liao, Wei‐Qiang Advanced Materials, Vol. 31, Issue 29 https://doi.org/10.1002/adma.201902163	journal	May 2019
Compositional Control in 2D Perovskites with Alternating Cations in the Interlayer Space for Photovoltaics with Efficiency over 18% Luo, Tao; Zhang, Yalan; Xu, Zhuo Advanced Materials, Vol. 31, Issue 44 https://doi.org/10.1002/adma.201903848	journal	September 2019
Molecular and Self-Trapped Excitonic Contributions to the Broadband Luminescence in Diamine-Based Low-Dimensional Hybrid Perovskite Systems Krishnamurthy, Shrreya; Naphade, Rounak; Mir, Wasim J. Advanced Optical Materials, Vol. 6, Issue 20 https://doi.org/10.1002/adom.201800751	journal	July 2018
Addressing Toxicity of Lead: Progress and Applications of Low-Toxic Metal Halide Perovskites and Their Derivatives Lyu, Miaoqiang; Yun, Jung-Ho; Chen, Peng Advanced Energy Materials, Vol. 7, Issue 15 https://doi.org/10.1002/aenm.201602512	journal	March 2017
Cesium Doped NiO _x as an Efficient Hole Extraction Layer for Inverted Planar Perovskite Solar Cells Chen, Wei; Liu, Fang-Zhou; Feng, Xi-Yuan Advanced Energy Materials, Vol. 7, Issue 19 https://doi.org/10.1002/aenm.201700722	journal	June 2017
Tetrathienoanthracene and Tetrathienylbenzene Derivatives as Hole-Transporting Materials for Perovskite Solar Cell Rojas, Diana Elizabeth Meza; Cho, Kyung Taek; Zhang, Yi Advanced Energy Materials, Vol. 8, Issue 25 https://doi.org/10.1002/aenm.201800681	journal	July 2018
High Efficiency Perovskite‐Silicon Tandem Solar Cells: Effect of Surface Coating versus Bulk Incorporation of 2D Perovskite Duong, The; Pham, Huyen; Kho, Teng Choon Advanced Energy Materials, Vol. 10, Issue 9 https://doi.org/10.1002/aenm.201903553	journal	January 2020
Experimental Evidence for a Triboluminescent Antiperovskite Ferroelectric: Tris(trimethylammonium) catena -Tri-μ-chloro-manganate(II) Tetrachloromanganate(II) Li, Peng-Fei; Tang, Yuan-Yuan; Liao, Wei-Qiang Angewandte Chemie, Vol. 130, Issue 37 https://doi.org/10.1002/ange.201805625	journal	August 2018
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Experimental Evidence for a Triboluminescent Antiperovskite Ferroelectric: Tris(trimethylammonium) catena -Tri-μ-chloro-manganate(II) Tetrachloromanganate(II) Li, Peng-Fei; Tang, Yuan-Yuan; Liao, Wei-Qiang Angewandte Chemie International Edition, Vol. 57, Issue 37 https://doi.org/10.1002/anie.201805625	journal	August 2018
Structural phase transition, electrical and semiconducting properties in a lead‐free 2D hybrid perovskite‐like compound: [Cl‐(CH ₂ ) ₂ ‐NH ₃ ] ₂ [CuCl ₄ ] Hajlaoui, Fadhel; Audebrand, Nathalie; Roisnel, Thierry Applied Organometallic Chemistry, Vol. 34, Issue 2 https://doi.org/10.1002/aoc.5293	journal	December 2019
Bandgap Optimization of Perovskite Semiconductors for Photovoltaic Applications Xiao, Zewen; Zhou, Yuanyuan; Hosono, Hideo Chemistry - A European Journal, Vol. 24, Issue 10 https://doi.org/10.1002/chem.201705031	journal	January 2018
Insight into the Mechanochemical Synthesis and Structural Evolution of Hybrid Organic-Inorganic Guanidinium Lead(II) Iodides Wilke, Manuel; Casati, Nicola Chemistry - A European Journal, Vol. 24, Issue 67 https://doi.org/10.1002/chem.201804066	journal	November 2018
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Light Management in Monolithic Perovskite/Silicon Tandem Solar Cells Xu, Qiaojing; Zhao, Ying; Zhang, Xiaodan Solar RRL, Vol. 4, Issue 2 https://doi.org/10.1002/solr.201900206	journal	August 2019
Solution-processed semiconductors for next-generation photodetectors García de Arquer, F. Pelayo; Armin, Ardalan; Meredith, Paul Nature Reviews Materials, Vol. 2, Issue 3 https://doi.org/10.1038/natrevmats.2016.100	journal	January 2017
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Structural diversity in substituted-pyridinium iodo- and bromoplumbates: a matter of halide and temperature Gómez, Verónica; Fuhr, Olaf; Ruben, Mario CrystEngComm, Vol. 18, Issue 42 https://doi.org/10.1039/c6ce01684g	journal	January 2016
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Unusual two-step sequential reversible phase transitions with coexisting switchable nonlinear optical and dielectric behaviors in [(CH ₃ ) ₃ NCH ₂ Cl] ₂ [ZnCl ₄ ] Liao, Wei-Qiang; Gao, Ji-Xing; Hua, Xiu-Ni Journal of Materials Chemistry C, Vol. 5, Issue 45 https://doi.org/10.1039/c7tc04095d	journal	January 2017
Switchable dielectric phase transition behaviors in two organic–inorganic copper( ii ) halides with distinct coordination geometries Mei, Ying-Xuan; Hua, Xiu-Ni; Gao, Ji-Xing CrystEngComm, Vol. 20, Issue 40 https://doi.org/10.1039/c8ce01263f	journal	January 2018
Unprecedented 30 K hysteresis across switchable dielectric and magnetic properties in a bright luminescent organic–inorganic halide (CH ₆ N ₃ ) ₂ MnCl ₄ Sen, Abhijit; Swain, Diptikanta; Guru Row, Tayur N. Journal of Materials Chemistry C, Vol. 7, Issue 16 https://doi.org/10.1039/c9tc00663j	journal	January 2019
Highly efficient CsPbBr 3 perovskite nanocrystals induced by structure transformation between CsPbBr 3 and Cs 4 PbBr 6 phases Su, Ying; Zeng, Qinghui; Chen, Xuejiao Journal of Materials Chemistry C, Vol. 7, Issue 25 https://doi.org/10.1039/c9tc01763a	journal	January 2019
Unprecedented tin iodide perovskite-like structures featuring ordering of organic moieties McNulty, Jason A.; Lightfoot, Philip Chemical Communications, Vol. 56, Issue 33 https://doi.org/10.1039/d0cc00549e	journal	January 2020
Spin-crossover in an organic–inorganic hybrid perovskite Wu, Wei-Wei; Wu, Si-Guo; Chen, Yan-Cong Chemical Communications, Vol. 56, Issue 33 https://doi.org/10.1039/d0cc00992j	journal	January 2020
Synthetic strategy towards halometallates with imidazo[1,5- a ]pyridinium-based counterions Vassilyeva, Olga Yu.; Buvaylo, Elena A.; Linnik, Rostyslav P. CrystEngComm, Vol. 22, Issue 30 https://doi.org/10.1039/d0ce00018c	journal	January 2020
First principles study of 2D layered organohalide tin perovskites Fraccarollo, Alberto; Canti, Lorenzo; Marchese, Leonardo The Journal of Chemical Physics, Vol. 146, Issue 23 https://doi.org/10.1063/1.4985054	journal	June 2017
Electric and magnetic transitions with 90° turning of polarizations in a layered perovskite of [NH ₄ Cl] ₂ [Ni(HCOO) ₂ (NH ₃ ) ₂ ] Chen, Sa; Shang, Ran; Wang, Bing-Wu APL Materials, Vol. 6, Issue 11 https://doi.org/10.1063/1.5040688	journal	November 2018
Cystamine-configured lead halide based 2D hybrid molecular crystals: Synthesis and photoluminescence systematics Krishnamurthy, Shrreya; Kour, Prachi; Katre, Ankita APL Materials, Vol. 6, Issue 11 https://doi.org/10.1063/1.5042268	journal	November 2018
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Tunable Semiconductors: Control over Carrier States and Excitations in Layered Hybrid Organic-Inorganic Perovskites W., You,; K. -Z., Du,; V., Blum, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/v5ra-ar75	text	January 2018
Emergence of Nanoplatelet Light-Emitting Diodes Xiao, Peng; Huang, Junhua; Yan, Dong Materials, Vol. 11, Issue 8 https://doi.org/10.3390/ma11081376	journal	August 2018
Single crystals of caesium formamidinium lead halide perovskites: solution growth and gamma dosimetry Nazarenko, Olga; Yakunin, Sergii; Morad, Viktoriia ETH Zurich https://doi.org/10.3929/ethz-b-000130696	text	January 2017
Engineering Multiphase Metal Halide Perovskites Thin Films for Stable and Efficient Solar Cells Kim, Min; Figueroa-Tapia, Jetsabel M.; Prato, Mirko Zenodo https://doi.org/10.5281/zenodo.3738931	text	January 2020
Boosting Photovoltaic Performance for Lead Halide Perovskites Solar Cells with BF ₄ ⁻ Anion Substitutions Zhang, Jie; Wu, Shengfan; Liu, Tiantian Advanced Functional Materials, Vol. 29, Issue 47 https://doi.org/10.1002/adfm.201808833	journal	February 2019
The First 2D Homochiral Lead Iodide Perovskite Ferroelectrics: [ R ‐ and S ‐1‐(4‐Chlorophenyl)ethylammonium] ₂ PbI ₄ Yang, Chen‐Kai; Chen, Wang‐Nan; Ding, Yan‐Ting Advanced Materials, Vol. 31, Issue 16 https://doi.org/10.1002/adma.201808088	journal	February 2019
Emerging Self‐Emissive Technologies for Flexible Displays Zhang, Dongdong; Huang, Tianyu; Duan, Lian Advanced Materials, Vol. 32, Issue 15 https://doi.org/10.1002/adma.201902391	journal	October 2019
Halogenated‐Methylammonium Based 3D Halide Perovskites Huang, Sheng; Huang, Peng; Wang, Lei Advanced Materials, Vol. 31, Issue 42 https://doi.org/10.1002/adma.201903830	journal	September 2019
Fullerene-Based Materials for Photovoltaic Applications: Toward Efficient, Hysteresis-Free, and Stable Perovskite Solar Cells Deng, Lin-Long; Xie, Su-Yuan; Gao, Feng Advanced Electronic Materials, Vol. 4, Issue 10 https://doi.org/10.1002/aelm.201700435	journal	December 2017
Enhanced Charge Transport in Hybrid Perovskite Field‐Effect Transistors via Microstructure Control Zeidell, Andrew M.; Tyznik, Colin; Jennings, Laura Advanced Electronic Materials, Vol. 4, Issue 12 https://doi.org/10.1002/aelm.201800316	journal	September 2018
Asymmetric Contact‐Induced Self‐Driven Perovskite‐Microwire‐Array Photodetectors Wu, Chun‐Yan; Peng, Wei; Fang, Ting Advanced Electronic Materials, Vol. 5, Issue 5 https://doi.org/10.1002/aelm.201900135	journal	March 2019
X‐Ray Microscopy of Halide Perovskites: Techniques, Applications, and Prospects Kodur, Moses; Kumar, Rishi E.; Luo, Yanqi Advanced Energy Materials https://doi.org/10.1002/aenm.201903170	journal	January 2020
Intrinsic Self‐Trapped Emission in 0D Lead‐Free (C ₄ H ₁₄ N ₂ ) ₂ In ₂ Br ₁₀ Single Crystal Zhou, Lei; Liao, Jin‐Feng; Huang, Zeng‐Guang Angewandte Chemie International Edition, Vol. 58, Issue 43 https://doi.org/10.1002/anie.201907503	journal	October 2019
Halogen Contacts-Induced Unusual Coloring in Bi III Bromide Complex: Anion-to-Cation Charge Transfer via Br⋅⋅⋅Br Interactions Adonin, Sergey A.; Gorokh, Igor D.; Novikov, Alexander S. Chemistry - A European Journal, Vol. 23, Issue 62 https://doi.org/10.1002/chem.201703747	journal	October 2017
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Photo‐Supercapacitors Based on Third‐Generation Solar Cells Meng, Hongguang; Pang, Shuping; Cui, Guanglei ChemSusChem, Vol. 12, Issue 15 https://doi.org/10.1002/cssc.201900398	journal	July 2019
Mechanochemical synthesis of methylammonium lead iodide perovskite Manukyan, K. V.; Yeghishyan, A. V.; Moskovskikh, D. O. Journal of Materials Science, Vol. 51, Issue 19 https://doi.org/10.1007/s10853-016-0165-4	journal	July 2016
Effects of organotin halide perovskite and Pt nanoparticles in SnO2-based sensing materials on the detection of formaldehyde Zhang, Xinyu; Sun, Yue; Fan, Yu Journal of Materials Science: Materials in Electronics, Vol. 30, Issue 23 https://doi.org/10.1007/s10854-019-02428-0	journal	November 2019
Halogen substitution effects on optical and electrical properties in 3D molecular perovskites Zhao, Meng-Meng; Zhou, Lin; Shi, Ping-Ping Chemical Communications, Vol. 54, Issue 94 https://doi.org/10.1039/c8cc07052k	journal	January 2018
Tetrahalometallate salts of N -(4-picolinium)-1,8-naphthalimide: structures and solid-state fluorescence Beebeejaun-Boodoo, B. M. P.; Erasmus, R.; Rademeyer, M. CrystEngComm, Vol. 20, Issue 33 https://doi.org/10.1039/c8ce00292d	journal	January 2018
Two new 3-D cadmium bromoplumbates: the only example of heterometallic bromoplumbate based on crown [Cd(Pb 4 O 4 )Br 2 ] clusters Xiao, Hong; Zhou, Jian; Liu, Xing Dalton Transactions, Vol. 47, Issue 14 https://doi.org/10.1039/c8dt00428e	journal	January 2018
Dielectric phase transition triggered by the order–disorder transformation of cyclopropylamine in a layered organic–inorganic halide perovskite Han, Shiguo; Liu, Xitao; Zhang, Jing Journal of Materials Chemistry C, Vol. 6, Issue 38 https://doi.org/10.1039/c8tc03517b	journal	January 2018
Luminescent perovskite quantum dots: synthesis, microstructures, optical properties and applications Chen, Daqin; Chen, Xiao Journal of Materials Chemistry C, Vol. 7, Issue 6 https://doi.org/10.1039/c8tc05545a	journal	January 2019
Temperature- and pressure-dependent studies of a highly flexible and compressible perovskite-like cadmium dicyanamide framework templated with protonated tetrapropylamine Mączka, Mirosław; Ptak, Maciej; Gągor, Anna Journal of Materials Chemistry C, Vol. 7, Issue 8 https://doi.org/10.1039/c8tc06401f	journal	January 2019
Bluish-white-light-emitting diodes based on two-dimensional lead halide perovskite (C ₆ H ₅ C ₂ H ₄ NH ₃ ) ₂ PbCl ₂ Br ₂ Cai, Peiqing; Wang, Xiangfu; Seo, Hyo Jin Applied Physics Letters, Vol. 112, Issue 15 https://doi.org/10.1063/1.5023797	journal	April 2018
Enhanced Optical and Electrical Properties of Polymer-Assisted All-Inorganic Perovskites for Light-Emitting Diodes Ling, Yichuan; Tian, Yu; Wang, Xi Advanced Materials, Vol. 28, Issue 40 https://doi.org/10.1002/adma.201602513	journal	August 2016
Tunable Spin Characteristic Properties in Spin Valve Devices Based on Hybrid Organic–Inorganic Perovskites Wang, Jingying; Zhang, Chuang; Liu, Haoliang Advanced Materials, Vol. 31, Issue 41 https://doi.org/10.1002/adma.201904059	journal	August 2019
Engineering Multiphase Metal Halide Perovskites Thin Films for Stable and Efficient Solar Cells Kim, Min; Figueroa‐Tapia, Jetsabel M.; Prato, Mirko Advanced Energy Materials, Vol. 10, Issue 8 https://doi.org/10.1002/aenm.201903221	journal	January 2020
High Efficiency Perovskite‐Silicon Tandem Solar Cells: Effect of Surface Coating versus Bulk Incorporation of 2D Perovskite Duong, The; Pham, Huyen; Kho, Teng Choon Advanced Energy Materials, Vol. 10, Issue 32 https://doi.org/10.1002/aenm.202002139	journal	August 2020
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Low-Dimensional Organic Tin Bromide Perovskites and Their Photoinduced Structural Transformation Zhou, Chenkun; Tian, Yu; Wang, Mingchao Angewandte Chemie International Edition, Vol. 56, Issue 31 https://doi.org/10.1002/anie.201702825	journal	July 2017
Intrinsic Broadband White-Light Emission from Ultrastable, Cationic Lead Halide Layered Materials Zhuang, Zewen; Peng, Chengdong; Zhang, Guiyang Angewandte Chemie International Edition, Vol. 56, Issue 46 https://doi.org/10.1002/anie.201706660	journal	October 2017
Recent Advances in Flexible Perovskite Solar Cells: Fabrication and Applications Yang, Dong; Yang, Ruixia; Priya, Shashank Angewandte Chemie International Edition, Vol. 58, Issue 14 https://doi.org/10.1002/anie.201809781	journal	February 2019
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Memory effect behavior with respect to the crystal grain size in the organic-inorganic hybrid perovskite nonvolatile resistive random access memory Heo, Jin Hyuck; Shin, Dong Hee; Moon, Sang Hwa Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-16805-4	journal	November 2017
Do alkyl groups on aromatic or aliphatic structure directing agents affect water stabilities and properties of hybrid iodoargentates? Liu, Guang-Ning; Zhang, Xu; Wang, Hong-Mei Dalton Transactions, Vol. 46, Issue 37 https://doi.org/10.1039/c7dt02152f	journal	January 2017
Optical deformation potential and self-trapped excitons in 2D hybrid perovskites Yu, Zhi-Gang Physical Chemistry Chemical Physics, Vol. 21, Issue 40 https://doi.org/10.1039/c9cp03080h	journal	January 2019
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Cs ₄ PbBr ₆ /CsPbBr ₃ perovskite composites for WLEDs: pure white, high luminous efficiency and tunable color temperature Huang, Shangxuan; Yang, Sen; Wang, Qi RSC Advances, Vol. 9, Issue 72 https://doi.org/10.1039/c9ra10183g	journal	January 2019
Zero-dimensional metal oxide Li ₄ TiO ₄ Du, Mao-Hua Journal of Materials Chemistry C, Vol. 7, Issue 19 https://doi.org/10.1039/c9tc00197b	journal	January 2019
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Metal‐Halide Perovskite Transistors for Printed Electronics: Challenges and Opportunities Lin, Yen‐Hung; Pattanasattayavong, Pichaya; Anthopoulos, Thomas D. Advanced Materials, Vol. 29, Issue 46 https://doi.org/10.1002/adma.201702838	journal	October 2017
Two-Dimensional Organic-Inorganic Hybrid Perovskites: A New Platform for Optoelectronic Applications Hu, Jun; Yan, Liang; You, Wei Advanced Materials, Vol. 30, Issue 48 https://doi.org/10.1002/adma.201802041	journal	September 2018
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Integrating Properties Modification in the Synthesis of Metal Halide Perovskites Huang, Ke; Liu, Jinxin; Chang, Xuejiao Advanced Materials Technologies, Vol. 4, Issue 2 https://doi.org/10.1002/admt.201800321	journal	November 2018
Why are Hot Holes Easier to Extract than Hot Electrons from Methylammonium Lead Iodide Perovskite? Dursun, Ibrahim; Maity, Partha; Yin, Jun Advanced Energy Materials, Vol. 9, Issue 22 https://doi.org/10.1002/aenm.201900084	journal	April 2019
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Exploring Lead‐Free Hybrid Double Perovskite Crystals of (BA) ₂ CsAgBiBr ₇ with Large Mobility‐Lifetime Product toward X‐Ray Detection Xu, Zhiyun; Liu, Xin; Li, Yaobin Angewandte Chemie International Edition, Vol. 58, Issue 44 https://doi.org/10.1002/anie.201909815	journal	September 2019
[(CH ₃ ) ₃ NH] ₃ Bi ₂ I ₉ : A Polar Lead-Free Hybrid Perovskite-Like Material as a Potential Semiconducting Absorber Zhang, Jing; Han, Shiguo; Ji, Chengmin Chemistry - A European Journal, Vol. 23, Issue 68 https://doi.org/10.1002/chem.201703346	journal	November 2017
Low‐dimensional metal halide perovskites and related optoelectronic applications Zhu, Pengchen; Zhu, Jia InfoMat, Vol. 2, Issue 2 https://doi.org/10.1002/inf2.12086	journal	February 2020
Strategies Toward Extending the Near‐Infrared Photovoltaic Response of Perovskite Solar Cells Bai, Yiming; Lang, Kun; Zhao, Chunyan Solar RRL, Vol. 4, Issue 2 https://doi.org/10.1002/solr.201900280	journal	August 2019
The Optical Band-Gap Evolution in Perovskite-Like Hybrid Iodobismuthates Effected by Nuclearity and Dimension: An Experimental and DFT Calculation Study Jiang, Yu-Xiang; Wang, You-Yu; Song, Li Journal of Cluster Science, Vol. 30, Issue 6 https://doi.org/10.1007/s10876-019-01587-8	journal	May 2019
One-Year stable perovskite solar cells by 2D/3D interface engineering Grancini, G.; Roldán-Carmona, C.; Zimmermann, I. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15684	journal	June 2017
A hybrid organic-inorganic perovskite dataset Kim, Chiho; Huan, Tran Doan; Krishnan, Sridevi Scientific Data, Vol. 4, Issue 1 https://doi.org/10.1038/sdata.2017.57	journal	May 2017
Construction of a bicontinuous donor–acceptor hybrid material at the molecular level by inserting inorganic nanowires into porous MOFs Liu, Jian-Jun; Guan, Ying-Fang; Li, Ling Chemical Communications, Vol. 53, Issue 32 https://doi.org/10.1039/c7cc00495h	journal	January 2017
Sequential dielectric phase transitions induced by the vibrations of water molecules in an organic–inorganic hybrid halide (N-(2-ammoniumethyl)piperazinium) CuCl ₅ ·2H ₂ O Wang, Zhongxia; Lu, Yang; Zafar, Zainab Dalton Transactions, Vol. 46, Issue 31 https://doi.org/10.1039/c7dt01378g	journal	January 2017
KLi 3 Fe(C 2 O 4 ) 3 : a perovskite-like compound with 1 : 3 ordering at both A and B sites Yao, Wenjiao; Guo, Yuan-Yuan; Lightfoot, Philip Dalton Trans., Vol. 46, Issue 39 https://doi.org/10.1039/c7dt03468g	journal	January 2017
Nanoarchitectonics in dielectric/ferroelectric layered perovskites: from bulk 3D systems to 2D nanosheets Osada, Minoru; Sasaki, Takayoshi Dalton Transactions, Vol. 47, Issue 9 https://doi.org/10.1039/c7dt03719h	journal	January 2018
Cation-templated cyanometallate-based supramolecular rectangular cage compounds showing dielectric transitions Liu, Yu-Ling; Zhang, Wen Inorganic Chemistry Frontiers, Vol. 4, Issue 8 https://doi.org/10.1039/c7qi00218a	journal	January 2017
Emerging two-dimensional halide perovskite nanomaterials Dou, Letian Journal of Materials Chemistry C, Vol. 5, Issue 43 https://doi.org/10.1039/c7tc02863f	journal	January 2017
(2-Methylpiperidine)PbI ₃ : an ABX ₃ -type organic–inorganic hybrid chain compound and its semiconducting nanowires with photoconductive properties Wu, Zhenyue; Ji, Chengmin; Wang, Sasa Journal of Materials Chemistry C, Vol. 5, Issue 44 https://doi.org/10.1039/c7tc03844e	journal	January 2017
White perovskite based lighting devices Bidikoudi, M.; Fresta, E.; Costa, R. D. Chemical Communications, Vol. 54, Issue 59 https://doi.org/10.1039/c8cc03166e	journal	January 2018
An Er-doped TiO ₂ phase junction as an electron transport layer for efficient perovskite solar cells fabricated in air Ren, Ziqiu; Wu, Jinde; Wang, Na Journal of Materials Chemistry A, Vol. 6, Issue 31 https://doi.org/10.1039/c8ta04444a	journal	January 2018
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Synthesis of ultrathin two-dimensional organic–inorganic hybrid perovskite nanosheets for polymer field-effect transistors Zhu, Lijie; Zhang, Huaye; Lu, Qipeng Journal of Materials Chemistry C, Vol. 6, Issue 15 https://doi.org/10.1039/c8tc00289d	journal	January 2018
Mechanical properties of the ferroelectric metal-free perovskite [MDABCO](NH ₄ )I ₃ Ehrenreich, Michael G.; Zeng, Zhixin; Burger, Stefan Chemical Communications, Vol. 55, Issue 27 https://doi.org/10.1039/c9cc00580c	journal	January 2019
Strongly emissive white-light-emitting silver iodide based inorganic–organic hybrid structures with comparable quantum efficiency to commercial phosphors Lin, Fang; Liu, Wei; Wang, Hao Chemical Communications, Vol. 56, Issue 10 https://doi.org/10.1039/c9cc09260a	journal	January 2020
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Research Update: Challenges for high-efficiency hybrid lead-halide perovskite LEDs and the path towards electrically pumped lasing Li, Guangru; Price, Michael; Deschler, Felix APL Materials, Vol. 4, Issue 9 https://doi.org/10.1063/1.4962351	journal	September 2016
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Synthetic control over orientational degeneracy of spacer cations enhances solar cell efficiency in two-dimensional perovskites Y., Lin,; H., Ade,; M. M., Nahid, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/rj6r-nh10	text	January 2019
Exciton-polaron spectral structures in two dimensional hybrid lead-halide perovskites Neutzner, Stefanie; Thouin, Félix; Cortecchia, Daniele arXiv https://doi.org/10.48550/arxiv.1803.02455	text	January 2018
Charge transfer tuning in TiO2 hybrid nanostructures with acceptor-acceptor systems Pilarczyk, K.; Lewandowska, K.; Mech, K. arXiv https://doi.org/10.48550/arxiv.1810.10522	text	January 2018
Absolute energy level positions in tin and lead based halide perovskites Tao, Shuxia; Schmidt, Ines; Brocks, Geert arXiv https://doi.org/10.48550/arxiv.1902.06646	text	January 2019
Progress on lead-free metal halide perovskites for photovoltaic applications: a review Hoefler, Sebastian F.; Trimmel, Gregor; Rath, Thomas Monatshefte für Chemie - Chemical Monthly, Vol. 148, Issue 5 https://doi.org/10.1007/s00706-017-1933-9	journal	March 2017
Hybrid Field-Effect Transistors and Photodetectors Based on Organic Semiconductor and CsPbI3 Perovskite Nanorods Bilayer Structure Chen, Yantao; Wu, Xiaohan; Chu, Yingli Nano-Micro Letters, Vol. 10, Issue 4 https://doi.org/10.1007/s40820-018-0210-8	journal	June 2018
Computational Design of Two-Dimensional Perovskites with Functional Organic Cations Maheshwari, Sudeep; Savenije, Tom J.; Renaud, Nicolas The Journal of Physical Chemistry C, Vol. 122, Issue 30 https://doi.org/10.1021/acs.jpcc.8b05715	journal	March 2018
POSS-Appended Diphenylalanine: Self-Cleaning, Pollution-Protective, and Fire-Retardant Hybrid Molecular Material Maji, Krishnendu; Haldar, Debasish ACS Omega, Vol. 2, Issue 5 https://doi.org/10.1021/acsomega.7b00234	journal	May 2017
Broadband Emission in Hybrid Organic–Inorganic Halides of Group 12 Metals Roccanova, Rachel; Houck, Matthew; Yangui, Aymen ACS Omega, Vol. 3, Issue 12 https://doi.org/10.1021/acsomega.8b02883	journal	December 2018
Guanidinium-Formamidinium Lead Iodide: A Layered Perovskite-Related Compound with Red Luminescence at Room Temperature Nazarenko, Olga; Kotyrba, Martin R.; Yakunin, Sergii Journal of the American Chemical Society, Vol. 140, Issue 11 https://doi.org/10.1021/jacs.8b00194	journal	February 2018
Absolute energy level positions in tin- and lead-based halide perovskites Tao, Shuxia; Schmidt, Ines; Brocks, Geert Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10468-7	journal	June 2019
CH3NH3PbX3 (X = I, Br) encapsulated in silicon carbide/carbon nanotube as advanced diodes Zhang, Lishu; Dai, Xinyue; Li, Tao Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-33668-5	journal	October 2018
Characterizing temperature-dependent optical properties of (MA0.13FA0.87) PbI3 single crystals using spectroscopic ellipsometry Chen, Hsiao-Wen; Gulo, Desman Perdamaian; Chao, Yu-Chiang Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-54636-7	journal	December 2019
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Large Thermal Motion in Halide Perovskites Tyson, T. A.; Gao, W.; Chen, Y. -S. arXiv https://doi.org/10.48550/arxiv.1702.06603	preprint	January 2017
Methylammonium Lead Trihalide Perovskite Solar Cell Semiconductors Are Not Organometallic Varadwaj, Pradeep R. arXiv https://doi.org/10.48550/arxiv.1703.09885	preprint	January 2017
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The role of lattice mismatch on the emergence of surface states in 2D hybrid perovskite quantum wells Kepenekian, M.; Traore, B.; Blancon, J. -C. arXiv https://doi.org/10.48550/arxiv.1801.00704	text	January 2018
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