110th Anniversary: High-Molecular-Weight Chitin and Cellulose Hydrogels from Biomass in Ionic Liquids without Chemical Crosslinking
Cellulose, chitin, and composite 3D hydrogels and membranes were fabricated without any chemical modification from high-molecular-weight chitin and cellulose-rich material (CRM) extracted from shrimp shell or pine wood, respectively, using the ionic liquid (IL) 1-ethyl-3-methylimidazolium acetate ([C2mim][OAc]). The hydrogels were prepared by redissolution of the extracted biopolymers in the same IL, or in a one-pot process directly from a solution of the biomass after extraction, followed by molding/gelation (“3D gels”) or casting (membranes), and then washing. For comparison, the preparation of gels was attempted using commercial microcrystalline cellulose or chitin. From all of the sources, the regenerated CRM or chitin required significantly lower load. Hydrogels were also converted to aerogels via transformation to alcogels and then Sc-CO2 drying, giving materials of low density, high porosity, favorable compressibility, high water uptake, and moderate antioxidant activity. Air-dried membranes were dense, of high tensile strength, and exhibited high water-vapor transmission.
- Research Organization:
- Univ. of Alabama, Tuscaloosa, AL (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC); China Scholarship Council
- Grant/Contract Number:
- SC0010152; 201306600007
- OSTI ID:
- 1593146
- Alternate ID(s):
- OSTI ID: 1593147
- Journal Information:
- Industrial and Engineering Chemistry Research, Vol. 58, Issue 43; ISSN 0888-5885
- Publisher:
- American Chemical Society (ACS)Copyright Statement
- Country of Publication:
- United States
- Language:
- English
Web of Science
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