Noble and Major Gases Released from Rock Core Materials as Intrinsic Tracers for Detecting Carbon Dioxide Leakage – Laboratory Evaluation
- BATTELLE (PACIFIC NW LAB)
- Ohio State University
- BATTELLE COLUMBUS OFFICE
- OHIO STATE UNIVERSITY
The elemental and isotopic compositions of noble gases constitute a set of non-reactive geochemical tracers. Noble gases released from geological formations in contact with pore water acidified by leaked carbon dioxide (CO2) can potentially be employed as tracers for detection of CO2 leakage from storage reservoirs in carbon sequestration sites. In a set of laboratory tests, core materials from a stratigraphic borehole at the proposed FutureGen 2.0 carbon storage site (Jacksonville, IL, USA) were reacted with an aqueous acid to simulate contact with aqueous CO2 and the gas released from the reaction was collected. The major gas components, the noble gas concentrations and isotopic ratios were determined to evaluate the feasibility of using the released noble gases as tracers for crustal water-rock interactions. Experiments yielded several promising tracer candidates for intrinsic monitoring of CO2 leakage at the proposed FutureGen 2.0 site. The most robust signals stem from CH4 and 4He released by carbonates associated with dolomite and shale formations from the primary containment zone. No useful signal was obtained from the sandstone formation due to its very low yield of gas when acidified. Xenon released from the primary-containment zone also showed promise as a tracer, but a more robust analysis requires a different experimental set up. A general enrichment of CH4, N2 and light noble gas isotopes with respect to Ar abundance was observed and is consistent with the addition of major gases (CO2, CH4, and to a lesser extent N2) released by a combination of the decomposition of carbonate mineral phases and/or organic matter in the dolomite and shale formations. The enrichment of these major gases leads to enhanced signals from heterogeneous molecular and isotopic ratios including 3He/4He, 4He/22Ne, 20Ne/22Ne, 21Ne*/22Ne, 20Ne/36Ar, 84Kr/36Ar, 132Xe/36Ar, and 132Xe/84Kr, amongst others.
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 1591876
- Report Number(s):
- PNWD-SA-10563
- Journal Information:
- International Journal of Greenhouse Gas Control, Vol. 89
- Country of Publication:
- United States
- Language:
- English
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