Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition

Jang, Moon-Hyung; Kizilkaya, Orhan; Kropf, A. Jeremy; Kurtz, Richard L.; Elam, Jeffrey W.; Lei, Yu

doi:10.1063/1.5128740

Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition

Journal Article · Mon Jan 13 23:00:00 EST 2020 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.5128740· OSTI ID:1591762

^[1]; Kizilkaya, Orhan ^[2]; Kropf, A. Jeremy ^[3]; Kurtz, Richard L. ^[2]; Elam, Jeffrey W. ^[3]; ^[1]

Univ. of Alabama, Huntsville, AL (United States)
Louisiana State Univ., Baton Rouge, LA (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)

Pt-Pd bimetallic nanoparticles were synthesized on TiO₂ support on the planar substrate as well as on high surface area SiO₂ gel by atomic layer deposition to identify the catalytic performance improvement after the formation of Pt-Pd bimetallic nanoparticles by surface analysis techniques. From X-ray absorption near edge spectra of Pt-Pd bimetallic nanoparticles, d-orbital hybridization between Pt 5d and Pd 4d was observed, which is responsible for charge transfer from Pt to Pd. Moreover, it was found from the in situ grazing incidence X-ray absorption spectroscopy study that Pt-Pd nanoparticles have a Pd shell/Pt core structure with CO adsorption. Here, resonant photoemission spectroscopy on Pt-Pd bimetallic nanoparticles showed that Pd resonant intensity is enhanced compared to that of Pd monometallic nanoparticles because of d-orbital hybridization and electronic states broadening of Pt and Pd compared monometallic catalysts, which results in catalytic performance improvement.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); American Chemical Society - Petroleum Research Fund

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1591762

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 2 Vol. 152; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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