skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: A carbonate-free, sulfone-based electrolyte for high-voltage Li-ion batteries

Journal Article · · Materials Today

Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)
OSTI ID:
1582797
Journal Information:
Materials Today, Journal Name: Materials Today Vol. 21 Journal Issue: 4; ISSN 1369-7021
Publisher:
ElsevierCopyright Statement
Country of Publication:
United Kingdom
Language:
English
Citation Metrics:
Cited by: 155 works
Citation information provided by
Web of Science

References (77)

Sulfone-Based Electrolytes for Lithium-Ion Batteries journal January 2002
Chemistry, Impedance, and Morphology Evolution in Solid Electrolyte Interphase Films during Formation in Lithium Ion Batteries journal December 2013
Ramifications of Water-in-Salt Interfacial Structure at Charged Electrodes for Electrolyte Electrochemical Stability journal August 2017
Superconcentrated electrolytes for a high-voltage lithium-ion battery journal June 2016
Quantum chemistry study of the oxidation-induced stability and decomposition of propylene carbonate-containing complexes journal January 2014
Oxidative Stability and Initial Decomposition Reactions of Carbonate, Sulfone, and Alkyl Phosphate-Based Electrolytes journal April 2013
Modeling Insight into Battery Electrolyte Electrochemical Stability and Interfacial Structure journal November 2017
4.0 V Aqueous Li-Ion Batteries journal September 2017
Methylene ethylene carbonate: Novel additive to improve the high temperature performance of lithium ion batteries journal June 2012
Ion solvation and association in LiClO4/sulfolane solution: a vibrational spectroscopic and molecular orbital study journal July 2001
How dynamic is the SEI? journal December 2007
Sulfone-based electrolytes for high-voltage Li-ion batteries journal May 2009
Valence state mapping of cobalt and manganese using near-edge fine structures journal August 2000
Lithium Salt Solutions in Mixed Sulfone and Sulfone-Carbonate Solvents: A Walden Plot Analysis of the Maximally Conductive Compositions journal November 2012
Origin of Graphite Exfoliation An Investigation of the Important Role of Solvent Cointercalation journal January 2000
Predicting the voltage dependence of interfacial electrochemical processes at lithium-intercalated graphite edge planes journal January 2015
Physicochemical and electrochemical properties of sulfolane solutions of lithium salts journal May 2008
Improved Performances of Nanosilicon Electrodes Using the Salt LiFSI: A Photoelectron Spectroscopy Study journal June 2013
Whether EC and PC Differ in Interphasial Chemistry on Graphitic Anode and How journal January 2009
Corrosion Prevention Mechanism of Aluminum Metal in Superconcentrated Electrolytes journal July 2015
Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries journal March 2014
Conductivity, Viscosity, and Their Correlation of a Super-Concentrated Aqueous Electrolyte journal January 2017
Electrolyte Solvation and Ionic Association journal January 2012
Effect of succinic anhydride as an electrolyte additive on electrochemical characteristics of silicon thin-film electrode journal June 2010
Elucidation of transport mechanism and enhanced alkali ion transference numbers in mixed alkali metal–organic ionic molten salts journal January 2016
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries journal October 2004
Hindered Glymes for Graphite-Compatible Electrolytes journal July 2015
High Anodic Stability of a New Electrolyte Solvent: Unsymmetric Noncyclic Aliphatic Sulfone journal January 1998
Electrolytes and Interphases in Li-Ion Batteries and Beyond journal October 2014
Prop-1-ene-1,3-sultone as SEI formation additive in propylene carbonate-based electrolyte for lithium ion batteries journal April 2012
Improving the electrochemical performance of high voltage spinel cathode at elevated temperature by a novel electrolyte additive journal January 2016
“Water-in-Salt” Electrolyte Makes Aqueous Sodium-Ion Battery Safe, Green, and Long-Lasting journal July 2017
Studies of Lithium Intercalation into Carbons Using Nonaqueous Electrochemical Cells journal January 1990
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries journal September 2010
Probing the electrode/electrolyte interface in the lithium excess layered oxide Li1.2Ni0.2Mn0.6O2 journal January 2013
Generation of Cathode Passivation Films via Oxidation of Lithium Bis(oxalato) Borate on High Voltage Spinel (LiNi 0.5 Mn 1.5 O 4 ) journal March 2014
A new look at the solid electrolyte interphase on graphite anodes in Li-ion batteries journal February 2006
Enabling linear alkyl carbonate electrolytes for high voltage Li-ion cells journal October 2016
Surface-layer formation by reductive decomposition of LiPF6 at relatively high potentials on negative electrodes in lithium ion batteries and its suppression journal December 2014
New insights into a high potential spinel and alkylcarbonate-based electrolytes journal February 2013
On the difference in cycling behaviors of lithium-ion battery cell between the ethylene carbonate- and propylene carbonate-based electrolytes journal December 2011
General Observation of Lithium Intercalation into Graphite in Ethylene-Carbonate-Free Superconcentrated Electrolytes journal March 2014
Change of Conductivity with Salt Content, Solvent Composition, and Temperature for Electrolytes of LiPF[sub 6] in Ethylene Carbonate-Ethyl Methyl Carbonate journal January 2001
In situ surface protection for enhancing stability and performance of conversion-type cathodes journal January 2017
Study of the Initial Stage of Solid Electrolyte Interphase Formation upon Chemical Reaction of Lithium Metal and N -Methyl- N -Propyl-Pyrrolidinium-Bis(Fluorosulfonyl)Imide journal September 2012
XRD evidence for the electrochemical formation of Li+(PC)yCn- in PC-based electrolytes journal September 2005
Concentrated electrolytes: decrypting electrolyte properties and reassessing Al corrosion mechanisms journal January 2014
A perspective on the high-voltage LiMn1.5Ni0.5O4 spinel cathode for lithium-ion batteries journal January 2014
Measurement of transference numbers for lithium ion electrolytes via four different methods, a comparative study journal April 2011
Inhibition of anodic corrosion of aluminum cathode current collector on recharging in lithium imide electrolytes journal May 2000
Uncovering the roles of oxygen vacancies in cation migration in lithium excess layered oxides journal January 2014
Interfacing electrolytes with electrodes in Li ion batteries journal January 2011
Why Bis(fluorosulfonyl)imide Is a “Magic Anion” for Electrochemistry journal August 2014
Some Fluorinated Carbonates as Electrolyte Additives for Li(Ni 0.4 Mn 0.4 Co 0.2 )O 2 /Graphite Pouch Cells journal January 2016
The vibrational spectra and molecular configuration of sulfolane journal January 1965
Cycling performance and surface analysis of Lithium bis(trifluoromethanesulfonyl)imide in propylene carbonate with graphite journal November 2016
Role of Lithium Salt on Solid Electrolyte Interface (SEI) Formation and Structure in Lithium Ion Batteries journal January 2014
Solvation behavior of carbonate-based electrolytes in sodium ion batteries journal January 2017
(Invited) Challenges with Quantum Chemistry-Based Screening of Electrochemical Stability of Lithium Battery Electrolytes journal September 2015
First-Principles Modeling of Mn(II) Migration above and Dissolution from Li x Mn 2 O 4 (001) Surfaces journal November 2016
Suppression of aluminum corrosion by using high concentration LiTFSI electrolyte journal June 2013
Role of Solution Structure in Solid Electrolyte Interphase Formation on Graphite with LiPF 6 in Propylene Carbonate journal November 2013
Importance of Reduction and Oxidation Stability of High Voltage Electrolytes and Additives journal August 2016
New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM journal November 2017
Influence of electrolyte additives on the cathode electrolyte interphase (CEI) formation on LiNi1/3Mn1/3Co1/3O2 in half cells with Li metal counter electrode journal October 2016
Defect Formation Energy in Spinel LiNi 0.5 Mn 1.5 O 4-δ Using Ab Initio DFT Calculations journal April 2015
On anodic stability and decomposition mechanism of sulfolane in high-voltage lithium ion battery journal July 2014
The Formation Mechanism of Fluorescent Metal Complexes at the Li x Ni 0.5 Mn 1.5 O 4−δ /Carbonate Ester Electrolyte Interface journal March 2015
Understanding Transition-Metal Dissolution Behavior in LiNi 0.5 Mn 1.5 O 4 High-Voltage Spinel for Lithium Ion Batteries journal July 2013
Doped sulfone electrolytes for high voltage Li-ion cell applications journal July 2009
Why Do Sulfone-Based Electrolytes Show Stability at High Voltages? Insight from Density Functional Theory journal November 2013
Filming mechanism of lithium-carbon anodes in organic and inorganic electrolytes journal April 1995
Decoupling effective Li+ ion conductivity from electrolyte viscosity for improved room-temperature cell performance journal February 2017
Electrolyte Solvation and Ionic Association III. Acetonitrile-Lithium Salt Mixtures–Transport Properties journal January 2013
The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model journal January 1979
Towards high throughput screening of electrochemical stability of battery electrolytes journal August 2015
Oxidation induced decomposition of ethylene carbonate from DFT calculations – importance of explicitly treating surrounding solvent journal January 2012

Similar Records

Electrochemical Windows of Sulfone-Based Electrolytes for High-Voltage Li-Ion Batteries
Journal Article · Sat Jan 01 00:00:00 EST 2011 · Journal of Physical Chemistry B · OSTI ID:1582797

Sulfone-based electrolytes for high voltage li-ion batteries.
Journal Article · Fri May 01 00:00:00 EDT 2009 · Electrochem. Commun. · OSTI ID:1582797

Sulfone-carbonate ternary electrolyte with further increased capacity retention and burn resistance for high voltage lithium ion batteries
Journal Article · Sun Nov 01 00:00:00 EDT 2015 · Journal of Power Sources · OSTI ID:1582797

Related Subjects