Crystal structure of the inversion-breaking metal Cd2Re2O7

Norman, M. R.

doi:10.1103/PhysRevB.101.045117

Title: Crystal structure of the inversion-breaking metal ${Cd}_{2} {Re}_{2} O_{7}$

Journal Article · Mon Jan 13 00:00:00 EST 2020 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.101.045117· OSTI ID:1582583

^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)

Second harmonic generation (SHG) on the pyrochlore metal Cd₂Re₂O₇ indicates the presence of three order parameters setting in below an inversion breaking transition. Here, we explore a possible structural explanation and relate it not only to the SHG data but also to neutron and x-ray diffraction, where we find that such a structural scenario can explain certain reflection extinctions observed in single crystal x-ray data. From this analysis, we suggest future experiments that could be done to resolve this matter. Lastly, we comment on the Landau-violating nature of the inversion breaking transition and its relation to similar phenomena observed in improper ferroelectrics.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1582583

Journal Information:: Physical Review B, Vol. 101, Issue 4; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 5 works

Citation information provided by
Web of Science

References (26)

Structural ordering and symmetry breaking in ${Cd}_{2} {Re}_{2} O_{7}$ Castellan, J. P.; Gaulin, B. D.; van Duijn, J. Physical Review B, Vol. 66, Issue 13 https://doi.org/10.1103/PhysRevB.66.134528	journal	October 2002
Pyrochlore Oxide Superconductor Cd 2 Re 2 O 7 Revisited Hiroi, Zenji; Yamaura, Jun-ichi; Kobayashi, Tatsuo C. Journal of the Physical Society of Japan, Vol. 87, Issue 2 https://doi.org/10.7566/JPSJ.87.024702	journal	February 2018
Electronic structure of pyrochlore Cd ₂ Re ₂ O ₇ Huang, Shih-Wen; Jeng, Horng-Tay; Lin, J-Y Journal of Physics: Condensed Matter, Vol. 21, Issue 19 https://doi.org/10.1088/0953-8984/21/19/195602	journal	April 2009
Structural Order Parameter in the Pyrochlore Superconductor Cd ₂ Re ₂ O ₇ A. Sergienko, Ivan; H. Curnoe, Stephanie Journal of the Physical Society of Japan, Vol. 72, Issue 7 https://doi.org/10.1143/JPSJ.72.1607	journal	July 2003
Electric Toroidal Quadrupoles in the Spin-Orbit-Coupled Metal Cd 2 Re 2 O 7 Hayami, Satoru; Yanagi, Yuki; Kusunose, Hiroaki Physical Review Letters, Vol. 122, Issue 14 https://doi.org/10.1103/PhysRevLett.122.147602	journal	April 2019
The pyrochlore family ? a potential panacea for the frustrated perovskite chemist Weller, Mark T.; Hughes, Robert W.; Rooke, Joanna Dalton Transactions, Issue 19 https://doi.org/10.1039/b401787k	journal	January 2004
Tetrahedral Magnetic Order and the Metal-Insulator Transition in the Pyrochlore Lattice of ${Cd}_{2} {Os}_{2} O_{7}$ Yamaura, J.; Ohgushi, K.; Ohsumi, H. Physical Review Letters, Vol. 108, Issue 24 https://doi.org/10.1103/PhysRevLett.108.247205	journal	June 2012
Formation and Control of Twin Domains in the Pyrochlore Oxide Cd 2 Re 2 O 7 Matsubayashi, Yasuhito; Hirai, Daigorou; Tokunaga, Masashi Journal of the Physical Society of Japan, Vol. 87, Issue 10 https://doi.org/10.7566/JPSJ.87.104604	journal	October 2018
Improper ferroelectricity in perovskite oxide artificial superlattices Bousquet, Eric; Dawber, Matthew; Stucki, Nicolas Nature, Vol. 452, Issue 7188 https://doi.org/10.1038/nature06817	journal	April 2008
Low Temperature Symmetry of Pyrochlore Oxide Cd ₂ Re ₂ O ₇ Yamaura, Jun-Ichi; Hiroi, Zenji Journal of the Physical Society of Japan, Vol. 71, Issue 11 https://doi.org/10.1143/JPSJ.71.2598	journal	November 2002
Order-disorder-order phase transitions in the pyrochlore superconductor ${Cd}_{2} {Re}_{2} O_{7}$ Knee, C. S.; Holmlund, J.; Andreasson, J. Physical Review B, Vol. 71, Issue 21 https://doi.org/10.1103/PhysRevB.71.214518	journal	June 2005
Local structure in the paraelectric phase of Cd 2 Nb 2 O 7 determined from x-ray diffuse scattering, by means of ab initio molecular dynamics and Monte Carlo modeling Paściak, Marek; Wołcyrz, Marek; Pietraszko, Adam Physical Review B, Vol. 81, Issue 1 https://doi.org/10.1103/PhysRevB.81.014107	journal	January 2010
Parity-Breaking Phases of Spin-Orbit-Coupled Metals with Gyrotropic, Ferroelectric, and Multipolar Orders Fu, Liang Physical Review Letters, Vol. 115, Issue 2 https://doi.org/10.1103/PhysRevLett.115.026401	journal	July 2015
A parity-breaking electronic nematic phase transition in the spin-orbit coupled metal Cd ₂ Re ₂ O ₇ Harter, J. W.; Zhao, Z. Y.; Yan, J. -Q. Science, Vol. 356, Issue 6335 https://doi.org/10.1126/science.aad1188	journal	April 2017
Metallic “Ferroelectricity” in the Pyrochlore ${C d}_{2} {R e}_{2} O_{7}$ Sergienko, I. A.; Keppens, V.; McGuire, M. Physical Review Letters, Vol. 92, Issue 6 https://doi.org/10.1103/PhysRevLett.92.065501	journal	February 2004
The crystal structure of Cd 2 Nb 2 O 7 : symmetry mode analysis of the ferroelectric phase Malcherek, T.; Bismayer, U.; Paulmann, C. Journal of Physics: Condensed Matter, Vol. 22, Issue 20 https://doi.org/10.1088/0953-8984/22/20/205401	journal	April 2010
The Role of Trilinear Couplings in the Phase Transitions of Aurivillius Compounds Etxebarria, I.; Perez-Mato, J. M.; Boullay, P. Ferroelectrics, Vol. 401, Issue 1 https://doi.org/10.1080/00150191003670325	journal	October 2010
Nonlinear optical signatures of the tensor order in Cd2Re2O7 Petersen, Jesse C.; Caswell, Michael D.; Dodge, J. Steven Nature Physics, Vol. 2, Issue 9 https://doi.org/10.1038/nphys392	journal	August 2006
Mechanism of Enhanced Optical Second-Harmonic Generation in the Conducting Pyrochlore-Type ${Pb}_{2} {Ir}_{2} O_{7 − x}$ Oxide Compound Hirata, Yasuyuki; Nakajima, Makoto; Nomura, Yusuke Physical Review Letters, Vol. 110, Issue 18 https://doi.org/10.1103/PhysRevLett.110.187402	journal	May 2013
Hybrid Improper Ferroelectricity: A Mechanism for Controllable Polarization-Magnetization Coupling Benedek, Nicole A.; Fennie, Craig J. Physical Review Letters, Vol. 106, Issue 10 https://doi.org/10.1103/PhysRevLett.106.107204	journal	March 2011
AMPLIMODES : symmetry-mode analysis on the Bilbao Crystallographic Server Orobengoa, Danel; Capillas, Cesar; Aroyo, Mois I. Journal of Applied Crystallography, Vol. 42, Issue 5 https://doi.org/10.1107/S0021889809028064	journal	September 2009
Nature of the tensor order in ${Cd}_{2} {Re}_{2} O_{7}$ Di Matteo, S.; Norman, M. R. Physical Review B, Vol. 96, Issue 11 https://doi.org/10.1103/PhysRevB.96.115156	journal	September 2017
Tetrahedral Magnetic Order and the Metal-Insulator Transition in the Pyrochlore Lattice of Cd2Os2O7 Yamaura, J.; Ohgushi, K.; Ohsumi, H. arXiv https://doi.org/10.48550/arxiv.1204.4815	text	January 2012
Parity-breaking phases of spin-orbit-coupled metals with gyrotropic, ferroelectric and multipolar orders Fu, Liang arXiv https://doi.org/10.48550/arxiv.1502.00015	text	January 2015
Formation and Control of Twin Domains in the Pyrochlore Oxide Cd2Re2O7 Matsubayashi, Yasuhito; Hirai, Daigorou; Tokunaga, Masashi arXiv https://doi.org/10.48550/arxiv.1809.00771	text	January 2018
Structural Order Parameter in the Pyrochlore Superconductor Cd2Re2O7 Sergienko, I. A.; Curnoe, S. H. arXiv https://doi.org/10.48550/arxiv.cond-mat/0301029	text	January 2003

Similar Records

Nature of the tensor order in

{Cd}_{2} {Re}_{2} O_{7}

Journal Article · Fri Sep 01 00:00:00 EDT 2017 · Physical Review B · OSTI ID:1582583

Di Matteo, S.; Norman, M. R.

Spin freezing into a disordered state in

CaFeT i_{2} O_{6}

synthesized under high pressure

Journal Article · Fri Aug 03 00:00:00 EDT 2018 · Physical Review B · OSTI ID:1582583

Li, Xiang; Xu, W. M.; McGuire, Michael A.; +9 more

Local structure and its implications for the relaxor ferroelectric

{Cd}_{2} {Nb}_{2} O_{7}

Journal Article · Tue Sep 06 00:00:00 EDT 2022 · Physical Review Research · OSTI ID:1582583

Hickox-Young, Daniel; Laurita, Geneva; Meier, Quintin N.; +4 more

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY

Title: Crystal structure of the inversion-breaking metal Cd 2 Re 2 O 7

Citation Formats

References (26)

Similar Records

Related Subjects

Title: Crystal structure of the inversion-breaking metal ${Cd}_{2} {Re}_{2} O_{7}$