Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores

Yu, Liang; Wang, Hao; Liu, Wei; Teat, Simon J.; Li, Jing

doi:10.1021/acs.cgd.9b01284

Title: Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores

Journal Article · Mon Oct 28 00:00:00 EDT 2019 · Crystal Growth and Design

DOI:https://doi.org/10.1021/acs.cgd.9b01284· OSTI ID:1581611

Yu, Liang ^[1];

^[1]; Liu, Wei ^[1]; Teat, Simon J. ^[2];

^[1]

Shenzhen Polytechnic (China)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Here, we demonstrate that two new zirconium-based metal-organic frameworks can be constructed from organic chromophore ligands. Both compounds show intense yellow emission when excited by blue light, with a notable fluorescence red shift and quantum yield enhancement compared to the organic chromophore.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1581611

Journal Information:: Crystal Growth and Design, Vol. 19, Issue 12; ISSN 1528-7483

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 13 works

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References (16)

Thermal design and analysis of multi-chip LED module with ceramic substrate Yin, Luqiao; Yang, Lianqiao; Yang, Weiqiao Solid-State Electronics, Vol. 54, Issue 12 https://doi.org/10.1016/j.sse.2010.06.028	journal	December 2010
Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors Lustig, William P.; Wang, Fangming; Teat, Simon J. Inorganic Chemistry, Vol. 55, Issue 15 https://doi.org/10.1021/acs.inorgchem.6b00897	journal	May 2016
Prospects for LED lighting Pimputkar, Siddha; Speck, James S.; DenBaars, Steven P. Nature Photonics, Vol. 3, Issue 4 https://doi.org/10.1038/nphoton.2009.32	journal	April 2009
Turn-On Fluorescence in Tetraphenylethylene-Based Metal–Organic Frameworks: An Alternative to Aggregation-Induced Emission Shustova, Natalia B.; McCarthy, Brian D.; Dincă, Mircea Journal of the American Chemical Society, Vol. 133, Issue 50 https://doi.org/10.1021/ja209327q	journal	December 2011
Solution Processable MOF Yellow Phosphor with Exceptionally High Quantum Efficiency Gong, Qihan; Hu, Zhichao; Deibert, Benjamin J. Journal of the American Chemical Society, Vol. 136, Issue 48 https://doi.org/10.1021/ja509446h	journal	November 2014
Achieving exceptionally high luminescence quantum efficiency by immobilizing an AIE molecular chromophore into a metal–organic framework Hu, Zhichao; Huang, Guangxi; Lustig, William P. Chemical Communications, Vol. 51, Issue 15 https://doi.org/10.1039/C4CC07642G	journal	January 2015
Metal–organic frameworks: functional luminescent and photonic materials for sensing applications Lustig, William P.; Mukherjee, Soumya; Rudd, Nathan D. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C6CS00930A	journal	January 2017
Luminescent metal–organic frameworks and coordination polymers as alternative phosphors for energy efficient lighting devices Lustig, William P.; Li, Jing Coordination Chemistry Reviews, Vol. 373 https://doi.org/10.1016/j.ccr.2017.09.017	journal	October 2018
AIE-active Metal-organic Coordination Complexes Based on Tetraphenylethylene Unit and Their Applications Jiang, Bo; Zhang, Chang-Wei; Shi, Xue-Liang Chinese Journal of Polymer Science, Vol. 37, Issue 4 https://doi.org/10.1007/s10118-019-2216-1	journal	January 2019
Immobilization of AIEgens into metal-organic frameworks: Ligand design, emission behavior, and applications Gui, Bo; Yu, Na; Meng, Yi Journal of Polymer Science Part A: Polymer Chemistry, Vol. 55, Issue 11 https://doi.org/10.1002/pola.28552	journal	March 2017
AIE-active tetraphenylethene functionalized metal–organic framework for selective detection of nitroaromatic explosives and organic photocatalysis Li, Qiu-Yan; Ma, Zheng; Zhang, Wen-Qiang Chemical Communications, Vol. 52, Issue 75 https://doi.org/10.1039/C6CC04997D	journal	January 2016
Highly Stable Mesoporous Zirconium Porphyrinic Frameworks with Distinct Flexibility Xu, Lei; Luo, Yan-Ping; Sun, Lin Chemistry - A European Journal, Vol. 22, Issue 18 https://doi.org/10.1002/chem.201600447	journal	March 2016
Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement Wei, Zhangwen; Gu, Zhi-Yuan; Arvapally, Ravi K. Journal of the American Chemical Society, Vol. 136, Issue 23 https://doi.org/10.1021/ja5006866	journal	May 2014
Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers Wang, Hao; Dong, Xinglong; Lin, Junzhong Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04152-5	journal	May 2018
Topological Analysis of Metal–Organic Frameworks with Polytopic Linkers and/or Multiple Building Units and the Minimal Transitivity Principle Li, Mian; Li, Dan; O’Keeffe, Michael Chemical Reviews, Vol. 114, Issue 2 https://doi.org/10.1021/cr400392k	journal	November 2013
Chemical and Structural Stability of Zirconium-based Metal-Organic Frameworks with Large Three-Dimensional Pores by Linker Engineering Kalidindi, Suresh B.; Nayak, Sanjit; Briggs, Michael E. Angewandte Chemie International Edition, Vol. 54, Issue 1 https://doi.org/10.1002/anie.201406501	journal	December 2014

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Title: Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores

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