Microwave assisted synthesis of heterometallic 3d–4f M4 Ln complexes

Rosado Piquer, L.; Dey, S.; Castilla-Amorós, L.; Teat, S. J.; Cirera, J.; Rajaraman, G.; Sañudo, E. C.

doi:10.1039/c9dt02567g

Title: Microwave assisted synthesis of heterometallic 3d–4f M₄ Ln complexes

Journal Article · Fri Jul 19 00:00:00 EDT 2019 · Dalton Transactions

DOI:https://doi.org/10.1039/c9dt02567g· OSTI ID:1581606

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Univ. de Barcelona (Spain)
Indian Inst. of Technology Bombay, Mumbai (India)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Here, we describe the synthesis and magnetic properties of a series of 3d–4f complexes of general formula [M₄Ln(OH)₂(chp)₄(SALOH)₅(H₂O)(MeCN)(Solv)] (Solv = MeOH, MeCN, H₂O; chp stands for deprotonated 6-chloro-2-hydroxypyridine (C₅H₃ClNO), SALOH stands for monodeprotonated 3,5-ditert-butylsalicylic acid (C₁₅H₂₁O₃)) obtained by a solvent-free microwave assisted synthesis method. The Ni(II) complexes (Ni₄Gd, Solv = MeOH; Ni₄Dy, Solv = MeCN) are not SMMs in the absence of an applied dc field. The replacement of Ni(II) by Co(II) (Co₄La, Solv = MeOH; Co₄Gd, Solv = H₂O; Co₄Gd-MeCN, Solv = MeCN; Co₄Tb, Solv = MeOH; Co₄Dy, Solv = H₂O) results in improved SMM properties.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Spanish Government

Grant/Contract Number:: AC02-05CH11231; CTQ2015-68370-P

OSTI ID:: 1581606

Journal Information:: Dalton Transactions, Vol. 48, Issue 33; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 17 works

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References (73)

Serendipitous assembly of polynuclear cage compounds Winpenny, Richard E. P. Journal of the Chemical Society, Dalton Transactions, Issue 1 https://doi.org/10.1039/b107118c	journal	December 2001
Heterometallic 3d–4f single-molecule magnets Rosado Piquer, Lidia; Sañudo, E. Carolina Dalton Transactions, Vol. 44, Issue 19 https://doi.org/10.1039/C5DT00549C	journal	January 2015
Al, Ga and In heterometallic wheels and their by-products Sañudo, E. Carolina; Muryn, Christopher A.; Helliwell, Madeleine A. Chem. Commun., Issue 8 https://doi.org/10.1039/B613877B	journal	January 2007
Self-Assembled Monolayer of Cr ₇ Ni Molecular Nanomagnets by Sublimation Ghirri, Alberto; Corradini, Valdis; Bellini, Valerio ACS Nano, Vol. 5, Issue 9 https://doi.org/10.1021/nn201800e	journal	August 2011
Verdazyl Radical, a Building Block for a Six-Spin-Center 2p–3d–4f Single-Molecule Magnet Novitchi, Ghénadie; Shova, Sergiu; Lan, Yanhua Inorganic Chemistry, Vol. 55, Issue 23 https://doi.org/10.1021/acs.inorgchem.6b02380	journal	November 2016
Solid state synthesis of [V5O2(Me3CCO2)9Cl2] Sañudo, E. Carolina; Ribas, Joan; Winpenny, Richard E. P. New Journal of Chemistry, Vol. 31, Issue 8 https://doi.org/10.1039/b704191h	journal	January 2007
PHI: A powerful new program for the analysis of anisotropic monomeric and exchange-coupled polynuclear d - and f -block complexes Chilton, Nicholas F.; Anderson, Russell P.; Turner, Lincoln D. Journal of Computational Chemistry, Vol. 34, Issue 13 https://doi.org/10.1002/jcc.23234	journal	February 2013
Synthesis, Structure, and Magnetic Properties of a Mn ₂₁ Single-Molecule Magnet Sañudo, E. Carolina; Wernsdorfer, Wolfgang; Abboud, Khalil A. Inorganic Chemistry, Vol. 43, Issue 14 https://doi.org/10.1021/ic0353864	journal	July 2004
Microwave assisted synthesis of polynuclear Ni(II) complexes Rosado Piquer, Lidia; Sañudo, E. Carolina Polyhedron, Vol. 169 https://doi.org/10.1016/j.poly.2019.05.011	journal	September 2019
A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit Guo, Fu-Sheng; Day, Benjamin M.; Chen, Yan-Cong Angewandte Chemie International Edition, Vol. 56, Issue 38 https://doi.org/10.1002/anie.201705426	journal	July 2017
Empirical parameters for calculating cation–oxygen bond valences Brown, I. D.; Wu, K. K. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 32, Issue 7 https://doi.org/10.1107/S0567740876006869	journal	July 1976
Strategies towards single molecule magnets based on lanthanide ions Sessoli, Roberta; Powell, Annie K. Coordination Chemistry Reviews, Vol. 253, Issue 19-20 https://doi.org/10.1016/j.ccr.2008.12.014	journal	October 2009
Lanthanides in molecular magnetism: old tools in a new field Sorace, Lorenzo; Benelli, Cristiano; Gatteschi, Dante Chemical Society Reviews, Vol. 40, Issue 6 https://doi.org/10.1039/c0cs00185f	journal	January 2011
Magnetic bistability in a metal-ion cluster Sessoli, R.; Gatteschi, D.; Caneschi, A. Nature, Vol. 365, Issue 6442 https://doi.org/10.1038/365141a0	journal	September 1993
New Nanostructured Materials: Synthesis of Dodecanuclear Ni ^II Complexes and Surface Deposition Studies Pons-Balagué, Alba; Piligkos, Stergios; Teat, Simon J. Chemistry - A European Journal, Vol. 19, Issue 27 https://doi.org/10.1002/chem.201204081	journal	May 2013
Molecular magnetic hysteresis at 60 kelvin in dysprosocenium Goodwin, Conrad A. P.; Ortu, Fabrizio; Reta, Daniel Nature, Vol. 548, Issue 7668 https://doi.org/10.1038/nature23447	journal	August 2017
Toward Rapid, “Green”, Predictable Microwave-Assisted Synthesis Roberts, Brett A.; Strauss, Christopher R. Accounts of Chemical Research, Vol. 38, Issue 8 https://doi.org/10.1021/ar040278m	journal	August 2005
High-spin molecules: [Mn12O12(O2CR)16(H2O)4] Sessoli, Roberta; Tsai, Hui Lien; Schake, Ann R. Journal of the American Chemical Society, Vol. 115, Issue 5 https://doi.org/10.1021/ja00058a027	journal	March 1993
Microwave-Enhanced Reaction Rates for Nanoparticle Synthesis Gerbec, Jeffrey A.; Magana, Donny; Washington, Aaron Journal of the American Chemical Society, Vol. 127, Issue 45 https://doi.org/10.1021/ja052463g	journal	November 2005
Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides Sulway, Scott A.; Layfield, Richard A.; Tuna, Floriana Chem. Commun., Vol. 48, Issue 10 https://doi.org/10.1039/C1CC14643B	journal	January 2012
Spin-enhanced magnetocaloric effect in molecular nanomagnets Evangelisti, Marco; Candini, Andrea; Ghirri, Alberto Applied Physics Letters, Vol. 87, Issue 7 https://doi.org/10.1063/1.2010604	journal	August 2005
Microwave assisted synthesis and magnetic properties of octanuclear and enneanuclear Ni(ii) complexes: an unprecedented coordination mode for the NO2− ligand Pons-Balagué, Alba; Ioanidis, Nicoleta; Wernsdorfer, Wolfgang Dalton Transactions, Vol. 40, Issue 44 https://doi.org/10.1039/c1dt10993f	journal	January 2011
Mononuclear Single-Molecule Magnets: Tailoring the Magnetic Anisotropy of First-Row Transition-Metal Complexes Gomez-Coca, Silvia; Cremades, Eduard; Aliaga-Alcalde, Núria Journal of the American Chemical Society, Vol. 135, Issue 18 https://doi.org/10.1021/ja4015138	journal	April 2013
Microwave-Assisted Synthesis of Metal–Organic Frameworks Klinowski, Jacek; Almeida Paz, Filipe A.; Silva, Patrícia Dalton Trans., Vol. 40, Issue 2 https://doi.org/10.1039/C0DT00708K	journal	January 2011
Single molecule magnets: a new class of magnetic materials Gatteschi, Dante Journal of Alloys and Compounds, Vol. 317-318 https://doi.org/10.1016/S0925-8388(00)01407-9	journal	April 2001
Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet Guo, Fu-Sheng; Day, Benjamin M.; Chen, Yan-Cong Science, Vol. 362, Issue 6421 https://doi.org/10.1126/science.aav0652	journal	October 2018
Clusters from Vertex- and Face-Sharing Adamantane-Like Units: A New Topology for Multinuclear Complexes Brechin, Euan K.; Harris, Steven G.; Parsons, Simon Angewandte Chemie International Edition in English, Vol. 36, Issue 18 https://doi.org/10.1002/anie.199719671	journal	October 1997
A family of heterometallic wheels containing potentially fourteen hundred siblings Laye, Rebecca H.; Larsen, Finn K.; Overgaard, Jacob Chem. Commun., Issue 9 https://doi.org/10.1039/B416770H	journal	January 2005
Simple Method and Materials to Target Co(II)-Dy(III) Multi-Nuclear Magnetic Compounds and Single Molecule Magnets (SMMs): Synthesis, Structure, and Magnetic Studies Zhu, Yan; Luo, Feng; Feng, Xue-Feng Australian Journal of Chemistry, Vol. 66, Issue 1 https://doi.org/10.1071/CH12336	journal	January 2013
Bond-valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database Brown, I. D.; Altermatt, D. Acta Crystallographica Section B Structural Science, Vol. 41, Issue 4 https://doi.org/10.1107/S0108768185002063	journal	August 1985
Field Supported Slow Magnetic Relaxation in a Mononuclear Cu(II) Complex Boča, Roman; Rajnák, Cyril; Titiš, Ján Inorganic Chemistry, Vol. 56, Issue 3 https://doi.org/10.1021/acs.inorgchem.6b02535	journal	January 2017
Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level Ishikawa, Naoto; Sugita, Miki; Ishikawa, Tadahiko Journal of the American Chemical Society, Vol. 125, Issue 29 https://doi.org/10.1021/ja029629n	journal	July 2003
From Serendipitous Assembly to Controlled Synthesis of 3d–4f Single-Molecule Magnets Ledezma-Gairaud, M.; Grangel, L.; Aromí, G. Inorganic Chemistry, Vol. 53, Issue 12 https://doi.org/10.1021/ic500418e	journal	May 2014
Polynuclear vanadium complexes from thermal decomposition of [V ₃ O(O ₂ CPh) ₆ (H ₂ O) ₃ ]Cl Sañudo, E. Carolina; Smith, Andrew A.; Mason, Pamela V. Dalton Trans., Issue 16 https://doi.org/10.1039/B510105K	journal	January 2006
Magnetostructural D Correlations in Hexacoordinated Cobalt(II) Complexes Titiš, Ján; Boča, Roman Inorganic Chemistry, Vol. 50, Issue 22 https://doi.org/10.1021/ic202108j	journal	November 2011
Single-Molecule Magnets: Giant Hysteresis of Single-Molecule Magnets Adsorbed on a Nonmagnetic Insulator (Adv. Mater. 26/2016) Wäckerlin, Christian; Donati, Fabio; Singha, Aparajita Advanced Materials, Vol. 28, Issue 26 https://doi.org/10.1002/adma.201670180	journal	July 2016
A Ferromagnetically Coupled Mn19 Aggregate with a RecordS=83/2 Ground Spin State Ako, Ayuk M.; Hewitt, Ian J.; Mereacre, Valeriu Angewandte Chemie International Edition, Vol. 45, Issue 30 https://doi.org/10.1002/anie.200601467	journal	July 2006
Hybrid molecular-inorganic materials: a heterometallic [Ni ₄ Tb] complex grafted on superparamagnetic iron oxide nanoparticles Rosado Piquer, L.; Jiménez Romero, E.; Lan, Y. Inorganic Chemistry Frontiers, Vol. 4, Issue 4 https://doi.org/10.1039/C6QI00468G	journal	January 2017
Quantum computing in molecular magnets Leuenberger, Michael N.; Loss, Daniel Nature, Vol. 410, Issue 6830 https://doi.org/10.1038/35071024	journal	April 2001
Single-Molecule Magnets Christou, George; Gatteschi, Dante; Hendrickson, David N. MRS Bulletin, Vol. 25, Issue 11 https://doi.org/10.1557/mrs2000.226	journal	November 2000
Weak Dy ^III –Dy ^III Interactions in Dy ^III –Phthalocyaninato Multiple-Decker Single-Molecule Magnets Effectively Suppress Magnetic Relaxation Horii, Yoji; Katoh, Keiichi; Cosquer, Goulven Inorganic Chemistry, Vol. 55, Issue 22 https://doi.org/10.1021/acs.inorgchem.6b01870	journal	November 2016
Magnetic Anisotropy of Cr7Ni Spin Clusters on Surfaces Corradini, Valdis; Ghirri, Alberto; Garlatti, Elena Advanced Functional Materials, Vol. 22, Issue 17 https://doi.org/10.1002/adfm.201200478	journal	May 2012
Microwave assisted synthesis: A Mn/Ni reaction system affording Mn5Ni4, Mn2Ni2 and Mn7 complexes Ledezma-Gairaud, Marisol; Pineda, Leslie W.; Aromí, Guillem Polyhedron, Vol. 64 https://doi.org/10.1016/j.poly.2013.02.018	journal	November 2013
Quantum Tunneling of Magnetization in Lanthanide Single-Molecule Magnets: Bis(phthalocyaninato)terbium and Bis(phthalocyaninato)dysprosium Anions Ishikawa, Naoto; Sugita, Miki; Wernsdorfer, Wolfgang Angewandte Chemie International Edition, Vol. 44, Issue 19 https://doi.org/10.1002/anie.200462638	journal	May 2005
Microwave-Assisted Synthesis of a Hexanuclear Mn ^III Single-Molecule Magnet Milios, Constantinos J.; Vinslava, Alina; Whittaker, A. Gavin Inorganic Chemistry, Vol. 45, Issue 14 https://doi.org/10.1021/ic0606678	journal	July 2006
New polynuclear nickel complexes with a variety of pyridonate and carboxylate ligands Blake, Alexander J.; Brechin, Euan K.; Codron, Arnaud Journal of the Chemical Society, Chemical Communications, Issue 19 https://doi.org/10.1039/c39950001983	journal	January 1995
What Controls the Magnetic Exchange and Anisotropy in a Family of Tetranuclear {Mn ₂ ^II Mn ₂ ^III } Single-Molecule Magnets? Vignesh, Kuduva R.; Langley, Stuart K.; Gartshore, Christopher J. Inorganic Chemistry, Vol. 56, Issue 4 https://doi.org/10.1021/acs.inorgchem.6b02527	journal	February 2017
Microwave assisted synthesis in coordination chemistry Pons-Balagué, Alba; Ojea, María José Heras; Ledezma-Gairaud, Marisol Polyhedron, Vol. 52 https://doi.org/10.1016/j.poly.2012.07.051	journal	March 2013
Molecular vs. inorganic spintronics: the role of molecular materials and single molecules Camarero, Julio; Coronado, Eugenio Journal of Materials Chemistry, Vol. 19, Issue 12 https://doi.org/10.1039/b819594n	journal	January 2009
Molecular spintronics using single-molecule magnets Bogani, Lapo; Wernsdorfer, Wolfgang Nature Materials, Vol. 7, Issue 3 https://doi.org/10.1038/nmat2133	journal	March 2008
Giant Single-Molecule Magnets: A{Mn84} Torus and Its Supramolecular Nanotubes Tasiopoulos, Anastasios J.; Vinslava, Alina; Wernsdorfer, Wolfgang Angewandte Chemie International Edition, Vol. 43, Issue 16 https://doi.org/10.1002/anie.200353352	journal	April 2004
Facile and Efficient Guanylation of Amines Using Thioureas and Mukaiyama's Reagent Yong, Yaw Fui; Kowalski, Jennifer A.; Lipton, Mark A. The Journal of Organic Chemistry, Vol. 62, Issue 5 https://doi.org/10.1021/jo962196k	journal	March 1997
Synthesis, structure and properties of {M ₄ O ₄ } cubanes containing nickel( ii ) and cobalt( ii ) Isele, Katharina; Gigon, Fabienne; Williams, Alan F. Dalton Trans., Issue 3 https://doi.org/10.1039/B614424A	journal	January 2007
Comprehensive derivation of bond-valence parameters for ion pairs involving oxygen Gagné, Olivier Charles; Hawthorne, Frank Christopher Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 71, Issue 5 https://doi.org/10.1107/S2052520615016297	journal	September 2015
The Drosophila of single-molecule magnetism: [Mn12O12(O2CR)16(H2O)4] Bagai, Rashmi; Christou, George Chemical Society Reviews, Vol. 38, Issue 4 https://doi.org/10.1039/b811963e	journal	January 2009
Quantum Tunneling of Magnetization in a New [Mn ₁₈ ] ²⁺ Single-Molecule Magnet with S = 13 Brechin, Euan K.; Boskovic, Colette; Wernsdorfer, Wolfgang Journal of the American Chemical Society, Vol. 124, Issue 33 https://doi.org/10.1021/ja026407g	journal	August 2002
Magnetic Exchange Interactions and Magneto-Structural Correlations in Heterobridged μ-Phenoxo-μ _1,1 -Azide Dinickel(II) Compounds: A Combined Experimental and Theoretical Exploration Sasmal, Sujit; Hazra, Susanta; Kundu, Parimal Inorganic Chemistry, Vol. 50, Issue 15 https://doi.org/10.1021/ic200833y	journal	August 2011
A ring cycle: studies of heterometallic wheels Affronte, Marco; Carretta, Stefano; Timco, Grigore A. Chemical Communications, Issue 18 https://doi.org/10.1039/b615543j	journal	January 2007
Microwave processing: fundamentals and applications Thostenson, E. T.; Chou, T. -W. Composites Part A: Applied Science and Manufacturing, Vol. 30, Issue 9 https://doi.org/10.1016/S1359-835X(99)00020-2	journal	September 1999
Structural and Magnetic Properties of [Ni4(.mu.3-OMe)4(dbm)4(MeOH)4] and [Ni4(.eta.1,.mu.3-N3)4(dbm)4(EtOH)4]. Magnetostructural Correlations for [Ni4X4]4+ Cubane Complexes Halcrow, Malcolm A.; Sun, Jui-Sui; Huffman, John C. Inorganic Chemistry, Vol. 34, Issue 16 https://doi.org/10.1021/ic00120a022	journal	August 1995
Synthesis, structures and magnetic properties of linear {CoII2LnIII2} coordination clusters Chen, Sihuai; Mereacre, Valeriu; Zhao, Zhiying New Journal of Chemistry, Vol. 42, Issue 2 https://doi.org/10.1039/C7NJ04022A	journal	January 2018
Origin of slow magnetic relaxation in Kramers ions with non-uniaxial anisotropy Gómez-Coca, Silvia; Urtizberea, Ainhoa; Cremades, Eduard Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5300	journal	July 2014
Field influence on the slow magnetic relaxation of nickel-based single ion magnets Titiš, Ján; Rajnák, Cyril; Valigura, Dušan Dalton Transactions, Vol. 47, Issue 24 https://doi.org/10.1039/C8DT01445K	journal	January 2018
Influencing the properties of dysprosium single-molecule magnets with phosphorus donor ligands Pugh, Thomas; Tuna, Floriana; Ungur, Liviu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8492	journal	July 2015
Discrete {Gd ^III ₄ M} (M = Gd ^III or Co ^II ) pentanuclear complexes: a new class of metal-organophosphate molecular coolers Gupta, Sandeep K.; Dar, Aijaz A.; Rajeshkumar, Thayalan Dalton Transactions, Vol. 44, Issue 13 https://doi.org/10.1039/C4DT03655G	journal	January 2015
Giant Single-Molecule Magnets: A{Mn84} Torus and Its Supramolecular Nanotubes Tasiopoulos, Anastasios J.; Vinslava, Alina; Wernsdorfer, Wolfgang Angewandte Chemie, Vol. 116, Issue 16 https://doi.org/10.1002/ange.200353352	journal	April 2004
A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit Guo, Fu-Sheng; Day, Benjamin M.; Chen, Yan-Cong Angewandte Chemie, Vol. 129, Issue 38 https://doi.org/10.1002/ange.201705426	journal	July 2017
Toward Rapid, “Green”, Predictable Microwave-Assisted Synthesis Roberts, Brett A.; Strauss, Christopher R. ChemInform, Vol. 36, Issue 48 https://doi.org/10.1002/chin.200548249	journal	November 2005
A Ferromagnetically Coupled Mn19 Aggregate with a RecordS=83/2 Ground Spin State Ako, Ayuk M.; Hewitt, Ian J.; Mereacre, Valeriu Angewandte Chemie, Vol. 118, Issue 30 https://doi.org/10.1002/ange.200601467	journal	July 2006
Single-Molecule Magnets Ruiz-molina, Daniel; Christou, George; Hendrickson, David N. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol. 343, Issue 1 https://doi.org/10.1080/10587250008023497	journal	May 2000
Quantum Tunneling of Magnetization in Lanthanide Single-Molecule Magnets: Bis(phthalocyaninato)terbium and Bis(phthalocyaninato)dysprosium Anions Ishikawa, Naoto; Sugita, Miki; Wernsdorfer, Wolfgang Angewandte Chemie, Vol. 117, Issue 19 https://doi.org/10.1002/ange.200462638	journal	May 2005
Quantum Computing in Molecular Magnets Leuenberger, Michael N.; Loss, Daniel arXiv https://doi.org/10.48550/arxiv.cond-mat/0011415	text	January 2000
Spin-enhanced magnetocaloric effect in molecular nanomagnets Evangelisti, Marco; Candini, Andrea; Ghirri, Alberto arXiv https://doi.org/10.48550/arxiv.cond-mat/0507407	text	January 2005

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Title: Microwave assisted synthesis of heterometallic 3d–4f M4 Ln complexes

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