Improving LMOF luminescence quantum yield through guest-mediated rigidification

Lustig, William P.; Teat, Simon J.; Li, Jing

doi:10.1039/c9tc05216j

Improving LMOF luminescence quantum yield through guest-mediated rigidification

Journal Article · Fri Nov 08 00:00:00 EST 2019 · Journal of Materials Chemistry C

DOI:https://doi.org/10.1039/c9tc05216j· OSTI ID:1581599

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Rutgers Univ..Piscataway, NJ (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Luminescent metal–organic frameworks (LMOFs) are among the fastest growing solid-state optical materials and have been studied for a wide variety of applications. However, when developing a new LMOF, it can be challenging to balance a strong luminescence quantum yield with all other important properties required by the intended application (appropriate excitation/emission wavelengths, chemical and physical stability, low toxicity, etc.). Being able to post-synthetically improve a LMOF's quantum yield is valuable, as it offers additional tunability in materials design and modification. As framework flexibility can limit quantum yield, post-synthetic methods of rigidifying an LMOF have the potential to improve its performance. This paper discusses a pair of nearly identical isoreticular LMOFs, and uses them as a model system to investigate how framework flexibility affects quantum yield. Finally, introducing optically-inactive guests into a LMOF pore is shown to be an effective method for rigidifying the framework, improving the quantum yield of a flexible LMOF from 12.2% to 59.3%—an improvement of nearly 400%.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1581599

Alternate ID(s):: OSTI ID: 1576034

Journal Information:: Journal of Materials Chemistry C, Journal Name: Journal of Materials Chemistry C Journal Issue: 46 Vol. 7; ISSN JMCCCX; ISSN 2050-7526

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (41)

Stable Metal-Organic Frameworks: Design, Synthesis, and Applications Yuan, Shuai; Feng, Liang; Wang, Kecheng Advanced Materials, Vol. 30, Issue 37 https://doi.org/10.1002/adma.201704303	journal	February 2018
Dynamic Structural Behavior and Anion-Responsive Tunable Luminescence of a Flexible Cationic Metal-Organic Framework Manna, Biplab; Chaudhari, Abhijeet K.; Joarder, Biplab Angewandte Chemie, Vol. 125, Issue 3 https://doi.org/10.1002/ange.201206724	journal	December 2012
Dynamic Structural Behavior and Anion-Responsive Tunable Luminescence of a Flexible Cationic Metal-Organic Framework Manna, Biplab; Chaudhari, Abhijeet K.; Joarder, Biplab Angewandte Chemie International Edition, Vol. 52, Issue 3 https://doi.org/10.1002/anie.201206724	journal	December 2012
An Interpenetrated Framework Material with Hysteretic CO ₂ Uptake Mulfort, KarenâL.; Farha, OmarâK.; Malliakas, ChristosâD. Chemistry - A European Journal, Vol. 16, Issue 1 https://doi.org/10.1002/chem.200902104	journal	January 2010
Assembly of Framework-Isomeric 4 d-4 f Heterometallic Metal-Organic Frameworks with Neutral/Anionic Micropores and Guest-Tuned Luminescence Properties Ma, Jing-xin; Huang, Xiao-feng; Song, Xue-qin Chemistry - A European Journal, Vol. 19, Issue 11 https://doi.org/10.1002/chem.201204022	journal	February 2013
Exploring Atypical Fluorine-Hydrogen Bonds and Their Effects on Nucleoside Conformations O'Reilly, Daniel; Stein, Robin S.; Patrascu, Mihai Burai Chemistry - A European Journal, Vol. 24, Issue 61 https://doi.org/10.1002/chem.201803940	journal	October 2018
Gadolinium(III)-Based Porous Luminescent Metal-Organic Frameworks for Bimodal Imaging Kundu, Tanay; Mitra, Shouvik; Díaz Díaz, David ChemPlusChem, Vol. 81, Issue 8 https://doi.org/10.1002/cplu.201600233	journal	June 2016
Metal–Organic Framework-Based Sensors for Environmental Contaminant Sensing Fang, Xian; Zong, Boyang; Mao, Shun Nano-Micro Letters, Vol. 10, Issue 4 https://doi.org/10.1007/s40820-018-0218-0	journal	July 2018
Enhancement of the π-electron delocalization and fluorescence efficiency of 1,6-diphenyl-1,3,5-hexatriene by covalent rigidification Jousselme, Bruno; Blanchard, Philippe; Frère, Pierre Tetrahedron Letters, Vol. 41, Issue 26 https://doi.org/10.1016/S0040-4039(00)00792-9	journal	June 2000
Luminescent metal–organic frameworks and coordination polymers as alternative phosphors for energy efficient lighting devices Lustig, William P.; Li, Jing Coordination Chemistry Reviews, Vol. 373 https://doi.org/10.1016/j.ccr.2017.09.017	journal	October 2018
Photoluminescent, upconversion luminescent and nonlinear optical metal-organic frameworks: From fundamental photophysics to potential applications Nguyen, Tu N.; Ebrahim, Fatmah Mish; Stylianou, Kyriakos C. Coordination Chemistry Reviews, Vol. 377 https://doi.org/10.1016/j.ccr.2018.08.024	journal	December 2018
Luminescent metal-organic frameworks as potential sensory materials for various environmental toxic agents Rasheed, Tahir; Nabeel, Faran Coordination Chemistry Reviews, Vol. 401 https://doi.org/10.1016/j.ccr.2019.213065	journal	December 2019
High-Performance Blue-Excitable Yellow Phosphor Obtained from an Activated Solvochromic Bismuth-Fluorophore Metal–Organic Framework Deibert, Benjamin J.; Velasco, Ever; Liu, Wei Crystal Growth & Design, Vol. 16, Issue 8 https://doi.org/10.1021/acs.cgd.6b00622	journal	July 2016
Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors Lustig, William P.; Wang, Fangming; Teat, Simon J. Inorganic Chemistry, Vol. 55, Issue 15 https://doi.org/10.1021/acs.inorgchem.6b00897	journal	May 2016
Toxic Aromatics Induced Responsive Facets for a Pore Surface Functionalized Luminescent Coordination Polymer Manna, Biplab; Sharma, Shivani; Mukherjee, Soumya Inorganic Chemistry, Vol. 56, Issue 12 https://doi.org/10.1021/acs.inorgchem.7b00215	journal	May 2017
Ultrastable Luminescent Hybrid Bromide Perovskite@MOF Nanocomposites for the Degradation of Organic Pollutants in Water Mollick, Samraj; Mandal, Tarak Nath; Jana, Atanu ACS Applied Nano Materials, Vol. 2, Issue 3 https://doi.org/10.1021/acsanm.8b02214	journal	February 2019
Nanocomposites of Zr(IV)-Based Metal–Organic Frameworks and Reduced Graphene Oxide for Electrochemically Sensing Ciprofloxacin in Water Fang, Xian; Chen, Xiaoyan; Liu, Ying ACS Applied Nano Materials, Vol. 2, Issue 4 https://doi.org/10.1021/acsanm.9b00243	journal	March 2019
Strategies for Characterization of Large-Pore Metal-Organic Frameworks by Combined Experimental and Computational Methods Bae, Youn-Sang; Dubbeldam, David; Nelson, Andrew Chemistry of Materials, Vol. 21, Issue 20 https://doi.org/10.1021/cm803218f	journal	October 2009
Luminescent Functional Metal–Organic Frameworks Cui, Yuanjing; Yue, Yanfeng; Qian, Guodong Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200101d	journal	June 2011
A local density functional study of the structure and vibrational frequencies of molecular transition-metal compounds Sosa, Carlos; Andzelm, Jan; Elkin, Brad C. The Journal of Physical Chemistry, Vol. 96, Issue 16 https://doi.org/10.1021/j100195a022	journal	August 1992
Selective Turn-On Ammonia Sensing Enabled by High-Temperature Fluorescence in Metal–Organic Frameworks with Open Metal Sites Shustova, Natalia B.; Cozzolino, Anthony F.; Reineke, Sebastian Journal of the American Chemical Society, Vol. 135, Issue 36 https://doi.org/10.1021/ja407778a	journal	August 2013
Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement Wei, Zhangwen; Gu, Zhi-Yuan; Arvapally, Ravi K. Journal of the American Chemical Society, Vol. 136, Issue 23 https://doi.org/10.1021/ja5006866	journal	May 2014
Two-Dimensional Metal–Organic Framework with Wide Channels and Responsive Turn-On Fluorescence for the Chemical Sensing of Volatile Organic Compounds Zhang, Mei; Feng, Guangxue; Song, Zhegang Journal of the American Chemical Society, Vol. 136, Issue 20 https://doi.org/10.1021/ja502643p	journal	May 2014
Solution Processable MOF Yellow Phosphor with Exceptionally High Quantum Efficiency Gong, Qihan; Hu, Zhichao; Deibert, Benjamin J. Journal of the American Chemical Society, Vol. 136, Issue 48 https://doi.org/10.1021/ja509446h	journal	November 2014
Ultrabright Luminescence from Gold Nanoclusters: Rigidifying the Au(I)–Thiolate Shell Pyo, Kyunglim; Thanthirige, Viraj Dhanushka; Kwak, Kyuju Journal of the American Chemical Society, Vol. 137, Issue 25 https://doi.org/10.1021/jacs.5b04210	journal	June 2015
Twist Angles and Rotational Energy Barriers of Biphenyl and Substituted Biphenyls Grein, Friedrich The Journal of Physical Chemistry A, Vol. 106, Issue 15 https://doi.org/10.1021/jp0122124	journal	April 2002
Hypersensitive dual-function luminescence switching of a silver-chalcogenolate cluster-based metal–organic framework Huang, Ren-Wu; Wei, Yong-Sheng; Dong, Xi-Yan Nature Chemistry, Vol. 9, Issue 7 https://doi.org/10.1038/nchem.2718	journal	February 2017
Molecular decoding using luminescence from an entangled porous framework Takashima, Yohei; Martínez, Virginia Martínez; Furukawa, Shuhei Nature Communications, Vol. 2, Issue 1 https://doi.org/10.1038/ncomms1170	journal	January 2011
Hydrogen-bond rigidified BODIPY dyes Jacobsen, Jennifer A.; Stork, Jay R.; Magde, Douglas Dalton Trans., Vol. 39, Issue 3 https://doi.org/10.1039/B921772J	journal	January 2010
Achieving exceptionally high luminescence quantum efficiency by immobilizing an AIE molecular chromophore into a metal–organic framework Hu, Zhichao; Huang, Guangxi; Lustig, William P. Chemical Communications, Vol. 51, Issue 15 https://doi.org/10.1039/C4CC07642G	journal	January 2015
Luminescent metal–organic frameworks for chemical sensing and explosive detection Hu, Zhichao; Deibert, Benjamin J.; Li, Jing Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00010B	journal	January 2014
Chromophore-immobilized luminescent metal–organic frameworks as potential lighting phosphors and chemical sensors Wang, Fangming; Liu, Wei; Teat, Simon J. Chemical Communications, Vol. 52, Issue 67 https://doi.org/10.1039/C6CC05290H	journal	January 2016
Metal–organic frameworks: functional luminescent and photonic materials for sensing applications Lustig, William P.; Mukherjee, Soumya; Rudd, Nathan D. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C6CS00930A	journal	January 2017
A heterometallic sodium–europium-cluster-based metal–organic framework as a versatile and water-stable chemosensor for antibiotics and explosives Han, Min-Le; Wen, Guo-Xuan; Dong, Wen-Wen Journal of Materials Chemistry C, Vol. 5, Issue 33 https://doi.org/10.1039/C7TC02885G	journal	January 2017
Strategies to fabricate metal–organic framework (MOF)-based luminescent sensing platforms Liu, Yang; Xie, Xiao-Yu; Cheng, Chen Journal of Materials Chemistry C, Vol. 7, Issue 35 https://doi.org/10.1039/C9TC03208H	journal	January 2019
Luminescent metal–organic frameworks Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K. Chemical Society Reviews, Vol. 38, Issue 5 https://doi.org/10.1039/b802352m	journal	January 2009
Self‐consistent molecular orbital methods 25. Supplementary functions for Gaussian basis sets Frisch, Michael J.; Pople, John A.; Binkley, J. Stephen The Journal of Chemical Physics, Vol. 80, Issue 7 https://doi.org/10.1063/1.447079	journal	April 1984
A new mixing of Hartree–Fock and local density‐functional theories Becke, Axel D. The Journal of Chemical Physics, Vol. 98, Issue 2 https://doi.org/10.1063/1.464304	journal	January 1993
Density-functional exchange-energy approximation with correct asymptotic behavior Becke, A. D. Physical Review A, Vol. 38, Issue 6 https://doi.org/10.1103/PhysRevA.38.3098	journal	September 1988
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density Lee, Chengteh; Yang, Weitao; Parr, Robert G. Physical Review B, Vol. 37, Issue 2 https://doi.org/10.1103/PhysRevB.37.785	journal	January 1988
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density Robert, Parr,; Chengteh, Lee,; Weitao, Yang, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/zrp0-ry04	text	January 1988

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