Improving LMOF luminescence quantum yield through guest-mediated rigidification

Lustig, William P.; Teat, Simon J.; Li, Jing

doi:10.1039/c9tc05216j

Title: Improving LMOF luminescence quantum yield through guest-mediated rigidification

Journal Article · Fri Nov 08 00:00:00 EST 2019 · Journal of Materials Chemistry C

DOI:https://doi.org/10.1039/c9tc05216j· OSTI ID:1581599

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Rutgers Univ..Piscataway, NJ (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Luminescent metal–organic frameworks (LMOFs) are among the fastest growing solid-state optical materials and have been studied for a wide variety of applications. However, when developing a new LMOF, it can be challenging to balance a strong luminescence quantum yield with all other important properties required by the intended application (appropriate excitation/emission wavelengths, chemical and physical stability, low toxicity, etc.). Being able to post-synthetically improve a LMOF's quantum yield is valuable, as it offers additional tunability in materials design and modification. As framework flexibility can limit quantum yield, post-synthetic methods of rigidifying an LMOF have the potential to improve its performance. This paper discusses a pair of nearly identical isoreticular LMOFs, and uses them as a model system to investigate how framework flexibility affects quantum yield. Finally, introducing optically-inactive guests into a LMOF pore is shown to be an effective method for rigidifying the framework, improving the quantum yield of a flexible LMOF from 12.2% to 59.3%—an improvement of nearly 400%.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC02-05CH11231; DMR-1507210

OSTI ID:: 1581599

Alternate ID(s):: OSTI ID: 1576034

Journal Information:: Journal of Materials Chemistry C, Vol. 7, Issue 46; ISSN 2050-7526

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 12 works

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