Using in situ and operando methods to characterize phase changes in charged lithium nickel cobalt aluminum oxide cathode materials

Hwang, Sooyeon; Stach, Eric

doi:10.1088/1361-6463/ab60ea

Title: Using in situ and operando methods to characterize phase changes in charged lithium nickel cobalt aluminum oxide cathode materials

Journal Article · Wed Dec 11 00:00:00 EST 2019 · Journal of Physics. D, Applied Physics

DOI:https://doi.org/10.1088/1361-6463/ab60ea· OSTI ID:1580237

^[1]; Stach, Eric ^[2]

Brookhaven National Lab. (BNL), Upton, NY (United States)
Univ. of Pennsylvania, Philadelphia, PA (United States)

Lithium ion batteries have been extensively explored in recent decades in order to improve their electrochemical performance, address safety concerns, and reduce costs in larger-scale applications. Electrode materials are key components which govern the properties of the battery at the system level. Cathode materials are of particular importance as they are a limiting factor for achieving high energy density. Lithium nickel cobalt aluminum oxide (LiNi_0.8Co_0.15Al_0.05O₂, referred to subsequently as NCA) is one of successful cathode materials since it can deliver higher capacity than other cathode materials such as lithium cobalt oxide or lithium iron phosphate. However, structural instabilities that occur NCA during charging or at high temperatures is believed to be the primary reason for performance degradation as well as a possible safety threat. Furthermore, understanding the structural evolution that occurs in NCA is of importance to acquire fundamental insights for taking full advantage of the high capacity of NCA materials. Beyond static information, in situ and operando characterization approaches allow us to observe structural changes under external stimulus or in a working condition, providing a deeper understanding of the routes by which structure evolve. In this review, we will describe the use of both in situ and operando characterization performed with both synchrotron X-ray based techniques and advanced electron microscopy, as the combination of these techniques have been shown to be particularly effective at providing structural information at complementary length scales.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1580237

Report Number(s):: BNL-212466-2019-JAAM

Journal Information:: Journal of Physics. D, Applied Physics, Vol. 53, Issue 11; ISSN 0022-3727

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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References (134)

Probing three-dimensional sodiation–desodiation equilibrium in sodium-ion batteries by in situ hard X-ray nanotomography Wang, Jiajun; Eng, Christopher; Chen-Wiegart, Yu-chen Karen Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8496	journal	June 2015
Tuning the Activity of Oxygen in LiNi _0.8 Co _0.15 Al _0.05 O ₂ Battery Electrodes Karki, Khim; Huang, Yiqing; Hwang, Sooyeon ACS Applied Materials & Interfaces, Vol. 8, Issue 41 https://doi.org/10.1021/acsami.6b09585	journal	October 2016
Microscopy and Spectroscopy of Lithium Nickel Oxide-Based Particles Used in High Power Lithium-Ion Cells Abraham, D. P.; Twesten, R. D.; Balasubramanian, M. Journal of The Electrochemical Society, Vol. 150, Issue 11 https://doi.org/10.1149/1.1613291	journal	January 2003
Performance and cost of materials for lithium-based rechargeable automotive batteries Schmuch, Richard; Wagner, Ralf; Hörpel, Gerhard Nature Energy, Vol. 3, Issue 4 https://doi.org/10.1038/s41560-018-0107-2	journal	April 2018
Lithium Batteries and Cathode Materials Whittingham, M. Stanley Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302 https://doi.org/10.1021/cr020731c	journal	October 2004
Rapid Mapping of Lithiation Dynamics in Transition Metal Oxide Particles with Operando X-ray Absorption Spectroscopy Nowack, Lea; Grolimund, Daniel; Samson, Vallerie Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep21479	journal	February 2016
High-Capacity Concentration Gradient Li[Ni _0.865 Co _0.120 Al _0.015 ]O ₂ Cathode for Lithium-Ion Batteries Park, Kang-Joon; Choi, Min-Jae; Maglia, Filippo Advanced Energy Materials, Vol. 8, Issue 19 https://doi.org/10.1002/aenm.201703612	journal	March 2018
First In Situ Observation of the LiCoO ₂ Electrode/Electrolyte Interface by Total-Reflection X-ray Absorption Spectroscopy Takamatsu, Daiko; Koyama, Yukinori; Orikasa, Yuki Angewandte Chemie, Vol. 124, Issue 46 https://doi.org/10.1002/ange.201203910	journal	October 2012
Structural and electrochemical properties of LiNi0.70Co0.15Al0.15O2 Guilmard, M. Solid State Ionics, Vol. 160, Issue 1-2 https://doi.org/10.1016/S0167-2738(03)00106-1	journal	May 2003
Capacity fade of LiNi (1−x−y) Co x Al y O 2 cathode for lithium-ion batteries during accelerated calendar and cycle life test. I. Comparison analysis between LiNi (1−x−y) Co x Al y O 2 and LiCoO 2 cathodes in cylindrical lithium-ion cells during long term storage test Watanabe, Shoichiro; Kinoshita, Masahiro; Nakura, Kensuke Journal of Power Sources, Vol. 247 https://doi.org/10.1016/j.jpowsour.2013.08.079	journal	February 2014
Degradation analysis of a Ni-based layered positive-electrode active material cycled at elevated temperatures studied by scanning transmission electron microscopy and electron energy-loss spectroscopy Kojima, Y.; Muto, S.; Tatsumi, K. Journal of Power Sources, Vol. 196, Issue 18 https://doi.org/10.1016/j.jpowsour.2011.05.017	journal	September 2011
The Effect of Pre-Analysis Washing on the Surface Film of Graphite Electrodes Somerville, L.; Bareño, J.; Jennings, P. Electrochimica Acta, Vol. 206 https://doi.org/10.1016/j.electacta.2016.04.133	journal	July 2016
In Situ TEM Observation of Electrochemical Lithiation of Sulfur Confined within Inner Cylindrical Pores of Carbon Nanotubes Kim, Hyea; Lee, Jung Tae; Magasinski, Alexandre Advanced Energy Materials, Vol. 5, Issue 24 https://doi.org/10.1002/aenm.201501306	journal	October 2015
Thermal Stability of Li ₂ O ₂ and Li ₂ O for Li-Air Batteries: In Situ XRD and XPS Studies Yao, Koffi P. C.; Kwabi, David G.; Quinlan, Ronald A. Journal of The Electrochemical Society, Vol. 160, Issue 6 https://doi.org/10.1149/2.069306jes	journal	January 2013
Activation Mechanism of LiNi _0.80 Co _0.15 Al _0.05 O ₂ : Surface and Bulk Operando Electrochemical, Differential Electrochemical Mass Spectrometry, and X-ray Diffraction Analyses Robert, Rosa; Bünzli, Christa; Berg, Erik J. Chemistry of Materials, Vol. 27, Issue 2 https://doi.org/10.1021/cm503833b	journal	January 2015
Multi-scale study of thermal stability of lithiated graphite Chen, Zonghai; Qin, Yan; Ren, Yang Energy & Environmental Science, Vol. 4, Issue 10 https://doi.org/10.1039/c1ee01786a	journal	January 2011
Demonstration of an Electrochemical Liquid Cell for Operando Transmission Electron Microscopy Observation of the Lithiation/Delithiation Behavior of Si Nanowire Battery Anodes Gu, Meng; Parent, Lucas R.; Mehdi, B. Layla Nano Letters, Vol. 13, Issue 12 https://doi.org/10.1021/nl403402q	journal	November 2013
Application of Synchrotron Radiation Technologies to Electrode Materials for Li- and Na-Ion Batteries Huang, Weifeng; Marcelli, Augusto; Xia, Dingguo Advanced Energy Materials, Vol. 7, Issue 21 https://doi.org/10.1002/aenm.201700460	journal	July 2017
In Situ Observation of the Electrochemical Lithiation of a Single SnO₂ Nanowire Electrode Huang, J. Y.; Zhong, L.; Wang, C. M. Science, Vol. 330, Issue 6010, p. 1515-1520 https://doi.org/10.1126/science.1195628	journal	December 2010
Lithium Electrodeposition Dynamics in Aprotic Electrolyte Observed in Situ via Transmission Electron Microscopy Leenheer, Andrew J.; Jungjohann, Katherine L.; Zavadil, Kevin R. ACS Nano, Vol. 9, Issue 4 https://doi.org/10.1021/acsnano.5b00876	journal	February 2015
Thermal Stability of the Li(Ni[sub 0.8]Co[sub 0.15]Al[sub 0.05])O[sub 2] Cathode in the Presence of Cell Components Belharouak, I.; Vissers, D.; Amine, K. Journal of The Electrochemical Society, Vol. 153, Issue 11 https://doi.org/10.1149/1.2336994	journal	January 2006
Nanoscale Morphological and Chemical Changes of High Voltage Lithium–Manganese Rich NMC Composite Cathodes with Cycling Yang, Feifei; Liu, Yijin; Martha, Surendra K. Nano Letters, Vol. 14, Issue 8 https://doi.org/10.1021/nl502090z	journal	July 2014
Electronic structural changes of the electrochemically Li-ion deintercalated LiNi0.8Co0.15Al0.05O2 cathode material investigated by X-ray absorption spectroscopy Yoon, Won-Sub; Chung, Kyung Yoon; McBreen, James Journal of Power Sources, Vol. 174, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.06.214	journal	December 2007
Thermal runaway caused fire and explosion of lithium ion battery Wang, Qingsong; Ping, Ping; Zhao, Xuejuan Journal of Power Sources, Vol. 208 https://doi.org/10.1016/j.jpowsour.2012.02.038	journal	June 2012
Investigating Local Degradation and Thermal Stability of Charged Nickel-Based Cathode Materials through Real-Time Electron Microscopy Hwang, Sooyeon; Kim, Seung Min; Bak, Seong-Min ACS Applied Materials & Interfaces, Vol. 6, Issue 17 https://doi.org/10.1021/am503278f	journal	August 2014
In situ synchrotron X-ray diffraction studies of lithium oxygen batteries Ryan, Kate R.; Trahey, Lynn; Okasinski, John S. Journal of Materials Chemistry A, Vol. 1, Issue 23 https://doi.org/10.1039/c3ta10361g	journal	January 2013
Heating-Induced Transformations of Atmospheric Particles: Environmental Transmission Electron Microscopy Study Veghte, Daniel P.; China, Swarup; Weis, Johannes Analytical Chemistry, Vol. 90, Issue 16 https://doi.org/10.1021/acs.analchem.8b01410	journal	July 2018
In Situ Transmission Electron Microscopy Observations of Electrochemical Oxidation of Li ₂ O ₂ Zhong, Li; Mitchell, Robert R.; Liu, Yang Nano Letters, Vol. 13, Issue 5 https://doi.org/10.1021/nl400731w	journal	April 2013
Multistep Lithiation of Tin Sulfide: An Investigation Using in Situ Electron Microscopy Hwang, Sooyeon; Yao, Zhenpeng; Zhang, Lei ACS Nano, Vol. 12, Issue 4 https://doi.org/10.1021/acsnano.8b00758	journal	March 2018
Rapid mapping of lithiation dynamics in transition metal oxide particles with operando X-ray absorption spectroscopy Nowack, Lea; Grolimund, Daniel; Samson, Vallerie ETH Zurich https://doi.org/10.3929/ethz-a-010820347	text	January 2016
Lithium-ion rechargeable batteries with LiCoO2 and carbon electrodes: the LiCoO2/C system Ozawa, K. Solid State Ionics, Vol. 69, Issue 3-4 https://doi.org/10.1016/0167-2738(94)90411-1	journal	August 1994
Aluminum-doped lithium nickel cobalt oxide electrodes for high-power lithium-ion batteries Chen, C. H.; Liu, J.; Stoll, M. E. Journal of Power Sources, Vol. 128, Issue 2 https://doi.org/10.1016/j.jpowsour.2003.10.009	journal	April 2004
Li(Ni,Co,Al)O ₂ Cathode Delithiation: A Combination of Topological Analysis, Density Functional Theory, Neutron Diffraction, and Machine Learning Techniques Eremin, Roman A.; Zolotarev, Pavel N.; Ivanshina, Olga Yu. The Journal of Physical Chemistry C, Vol. 121, Issue 51 https://doi.org/10.1021/acs.jpcc.7b09760	journal	December 2017
High-Rate Charging Induced Intermediate Phases and Structural Changes of Layer-Structured Cathode for Lithium-Ion Batteries Zhou, Yong-Ning; Yue, Ji-Li; Hu, Enyuan Advanced Energy Materials, Vol. 6, Issue 21 https://doi.org/10.1002/aenm.201600597	journal	August 2016
Direct Observation of the Redistribution of Sulfur and Polysufides in Li-S Batteries During the First Cycle by In Situ X-Ray Fluorescence Microscopy Yu, Xiqian; Pan, Huilin; Zhou, Yongning Advanced Energy Materials, Vol. 5, Issue 16 https://doi.org/10.1002/aenm.201500072	journal	March 2015
Investigating the Kinetic Effect on Structural Evolution of Li _x Ni _0.8 Co _0.15 Al _0.05 O ₂ Cathode Materials during the Initial Charge/Discharge Jo, Eunmi; Hwang, Sooyeon; Kim, Seung Min Chemistry of Materials, Vol. 29, Issue 7 https://doi.org/10.1021/acs.chemmater.6b03282	journal	March 2017
Understanding voltage decay in lithium-excess layered cathode materials through oxygen-centred structural arrangement Myeong, Seungjun; Cho, Woongrae; Jin, Wooyoung Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05802-4	journal	August 2018
Operando X-ray Absorption Study of the Redox Processes Involved upon Cycling of the Li-Rich Layered Oxide Li _1.20 Mn _0.54 Co _0.13 Ni _0.13 O ₂ in Li Ion Batteries Koga, H.; Croguennec, L.; Ménétrier, M. The Journal of Physical Chemistry C, Vol. 118, Issue 11 https://doi.org/10.1021/jp412197z	journal	March 2014
Sulfur Speciation in Li–S Batteries Determined by Operando X-ray Absorption Spectroscopy Cuisinier, Marine; Cabelguen, Pierre-Etienne; Evers, Scott The Journal of Physical Chemistry Letters, Vol. 4, Issue 19 https://doi.org/10.1021/jz401763d	journal	September 2013
Review—Post-Mortem Analysis of Aged Lithium-Ion Batteries: Disassembly Methodology and Physico-Chemical Analysis Techniques Waldmann, Thomas; Iturrondobeitia, Amaia; Kasper, Michael Journal of The Electrochemical Society, Vol. 163, Issue 10 https://doi.org/10.1149/2.1211609jes	journal	January 2016
Nature of Li ₂ O ₂ Oxidation in a Li–O ₂ Battery Revealed by Operando X-ray Diffraction Ganapathy, Swapna; Adams, Brian D.; Stenou, Georgiana Journal of the American Chemical Society, Vol. 136, Issue 46 https://doi.org/10.1021/ja508794r	journal	November 2014
Atomic Insight into the Layered/Spinel Phase Transformation in Charged LiNi _0.80 Co _0.15 Al _0.05 O ₂ Cathode Particles Zhang, Hanlei; Karki, Khim; Huang, Yiqing The Journal of Physical Chemistry C, Vol. 121, Issue 3 https://doi.org/10.1021/acs.jpcc.6b10220	journal	January 2017
Atomic-Resolution Visualization of Distinctive Chemical Mixing Behavior of Ni, Co, and Mn with Li in Layered Lithium Transition-Metal Oxide Cathode Materials Yan, Pengfei; Zheng, Jianming; Lv, Dongping Chemistry of Materials, Vol. 27, Issue 15 https://doi.org/10.1021/acs.chemmater.5b02016	journal	July 2015
Lithium Batteries and Cathode Materials Whittingham, M. Stanley ChemInform, Vol. 35, Issue 50 https://doi.org/10.1002/chin.200450266	journal	December 2004
In Situ Atomic-Scale Imaging of Phase Boundary Migration in FePO ₄ Microparticles During Electrochemical Lithiation Zhu, Yujie; Wang, Jiang Wei; Liu, Yang Advanced Materials, Vol. 25, Issue 38 https://doi.org/10.1002/adma.201301374	journal	July 2013
Combining In Situ Synchrotron X-Ray Diffraction and Absorption Techniques with Transmission Electron Microscopy to Study the Origin of Thermal Instability in Overcharged Cathode Materials for Lithium-Ion Batteries Nam, Kyung-Wan; Bak, Seong-Min; Hu, Enyuan Advanced Functional Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adfm.201200693	journal	June 2012
Intergranular Cracking as a Major Cause of Long-Term Capacity Fading of Layered Cathodes Liu, Hao; Wolf, Mark; Karki, Khim Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b00379	journal	May 2017
Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries Yan, Pengfei; Zheng, Jianming; Gu, Meng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14101	journal	January 2017
Runaway risk of forming toxic compounds Hammami, Amer; Raymond, Nathalie; Armand, Michel Nature, Vol. 424, Issue 6949 https://doi.org/10.1038/424635b	journal	August 2003
In situ/operando synchrotron-based X-ray techniques for lithium-ion battery research Bak, Seong-Min; Shadike, Zulipiya; Lin, Ruoqian NPG Asia Materials, Vol. 10, Issue 7 https://doi.org/10.1038/s41427-018-0056-z	journal	July 2018
Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging Singer, A.; Zhang, M.; Hy, S. Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0184-2	journal	July 2018
In situ soft XAS study on nickel-based layered cathode material at elevated temperatures: A novel approach to study thermal stability Yoon, Won-Sub; Haas, Otto; Muhammad, Shoaib Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06827	journal	October 2014
Coherent lensless X-ray imaging Chapman, Henry N.; Nugent, Keith A. Nature Photonics, Vol. 4, Issue 12 https://doi.org/10.1038/nphoton.2010.240	journal	November 2010
A comparative study on structural changes of LiCo1/3Ni1/3Mn1/3O2 and LiNi0.8Co0.15Al0.05O2 during first charge using in situ XRD Yoon, Won-Sub; Chung, Kyung Yoon; McBreen, James Electrochemistry Communications, Vol. 8, Issue 8 https://doi.org/10.1016/j.elecom.2006.06.005	journal	August 2006
Thermal behavior of Li1−yNiO2 and the decomposition mechanism Arai, H. Solid State Ionics, Vol. 109, Issue 3-4 https://doi.org/10.1016/S0167-2738(98)00075-7	journal	June 1998
Dynamic Structural Changes at LiMn ₂ O ₄ /Electrolyte Interface during Lithium Battery Reaction Hirayama, Masaaki; Ido, Hedekazu; Kim, KyungSu Journal of the American Chemical Society, Vol. 132, Issue 43 https://doi.org/10.1021/ja105389t	journal	November 2010
The AMPIX electrochemical cell: a versatile apparatus for in situ X-ray scattering and spectroscopic measurements Borkiewicz, Olaf J.; Shyam, Badri; Wiaderek, Kamila M. Journal of Applied Crystallography, Vol. 45, Issue 6 https://doi.org/10.1107/S0021889812042720	journal	November 2012
Reaction Heterogeneity in LiNi _0.8 Co _0.15 Al _0.05 O ₂ Induced by Surface Layer Grenier, Antonin; Liu, Hao; Wiaderek, Kamila M. Chemistry of Materials, Vol. 29, Issue 17 https://doi.org/10.1021/acs.chemmater.7b02236	journal	August 2017
In situ high-energy X-ray diffraction to study overcharge abuse of 18650-size lithium-ion battery Lin, Chi-Kai; Ren, Yang; Amine, Khalil Journal of Power Sources, Vol. 230 https://doi.org/10.1016/j.jpowsour.2012.12.032	journal	May 2013
In-Situ X-ray Absorption Spectroscopic Study on Variation of Electronic Transitions and Local Structure of LiNi _1/3 Co _1/3 Mn _1/3 O ₂ Cathode Material during Electrochemical Cycling Tsai, Y. W.; Hwang, B. J.; Ceder, G. Chemistry of Materials, Vol. 17, Issue 12 https://doi.org/10.1021/cm048027v	journal	June 2005
Study of Thermal Decomposition of Li _1-x (Ni _1/3 Mn _1/3 Co _1/3 ) _0.9 O ₂ Using In-Situ High-Energy X-Ray Diffraction Chen, Zonghai; Ren, Yang; Lee, Eungje Advanced Energy Materials, Vol. 3, Issue 6 https://doi.org/10.1002/aenm.201201059	journal	March 2013
Thermal Stability of Lithium Nickel Oxide Derivatives. Part II: Li _x Ni _0.70 Co _0.15 Al _0.15 O ₂ and Li _x Ni _0.90 Mn _0.10 O ₂ ( x = 0.50 and 0.30). Comparison with Li _x Ni _1.02 O ₂ and Li _x Ni _0.89 Al _0.16 O ₂ Guilmard, M.; Croguennec, L.; Delmas, C. Chemistry of Materials, Vol. 15, Issue 23 https://doi.org/10.1021/cm030340u	journal	November 2003
Time-resolved XRD study on the thermal decomposition of nickel-based layered cathode materials for Li-ion batteries Yoon, Won-Sub; Chung, Kyung Yoon; Balasubramanian, Mahalingam Journal of Power Sources, Vol. 163, Issue 1 https://doi.org/10.1016/j.jpowsour.2006.01.043	journal	December 2006
The cycling properties of the LixNi1−yCoyO2 electrode Delmas, C.; Saadoune, I.; Rougier, A. Journal of Power Sources, Vol. 44, Issue 1-3 https://doi.org/10.1016/0378-7753(93)80208-7	journal	April 1993
Formation of the Spinel Phase in the Layered Composite Cathode Used in Li-Ion Batteries Gu, Meng; Belharouak, Ilias; Zheng, Jianming ACS Nano, Vol. 7, Issue 1 https://doi.org/10.1021/nn305065u	journal	December 2012
Comparative Study of Ni-Rich Layered Cathodes for Rechargeable Lithium Batteries: Li[Ni _0.85 Co _0.11 Al _0.04 ]O ₂ and Li[Ni _0.84 Co _0.06 Mn _0.09 Al _0.01 ]O ₂ with Two-Step Full Concentration Gradients Lim, Byung-Beom; Myung, Seung-Taek; Yoon, Chong S. ACS Energy Letters, Vol. 1, Issue 1 https://doi.org/10.1021/acsenergylett.6b00150	journal	June 2016
Surface Structure and High-Voltage Charge/Discharge Characteristics of Al-Oxide Coated LiNi _1/3 Co _1/3 Mn _1/3 O ₂ Cathodes Yano, Akira; Aoyama, Shigeo; Shikano, Masahiro Journal of The Electrochemical Society, Vol. 162, Issue 2 https://doi.org/10.1149/2.0131502jes	journal	January 2015
Diagnostic Analysis of Electrodes from High-Power Lithium-Ion Cells Cycled under Different Conditions Striebel, K. A.; Shim, J.; Cairns, E. J. Journal of The Electrochemical Society, Vol. 151, Issue 6 https://doi.org/10.1149/1.1710514	journal	January 2004
Structural Changes and Thermal Stability of Charged LiNi _x Mn _y Co _z O ₂ Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning ACS Applied Materials & Interfaces, Vol. 6, Issue 24 https://doi.org/10.1021/am506712c	journal	December 2014
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes Sathiya, M.; Rousse, G.; Ramesha, K. Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3699	journal	July 2013
Effects of aluminum on the structural and electrochemical properties of LiNiO2 Guilmard, M. Journal of Power Sources, Vol. 115, Issue 2 https://doi.org/10.1016/S0378-7753(03)00012-0	journal	April 2003
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Li ⁺ -Ion Extraction/Insertion of Ni-Rich Li _{1+ x} (Ni _y Co _z Mn _z ) _w O ₂ (0.005< x <0.03; y : z =8:1, w ≈1) Electrodes: In Situ XRD and Raman Spectroscopy Study Ghanty, Chandan; Markovsky, Boris; Erickson, Evan M. ChemElectroChem, Vol. 2, Issue 10 https://doi.org/10.1002/celc.201500160	journal	July 2015
LiNi _1–y Co _y O ₂ positive electrode materials: relationships between the structure, physical properties and electrochemical behaviour Saadoune, Ismael; Delmas, Claude J. Mater. Chem., Vol. 6, Issue 2 https://doi.org/10.1039/JM9960600193	journal	January 1996
Compositionally and structurally redesigned high-energy Ni-rich layered cathode for next-generation lithium batteries Kim, Un-Hyuck; Kim, Jae-Hyung; Hwang, Jang-Yeon Materials Today, Vol. 23 https://doi.org/10.1016/j.mattod.2018.12.004	journal	March 2019
Cationic Ordering Coupled to Reconstruction of Basic Building Units during Synthesis of High-Ni Layered Oxides Zhang, Ming-Jian; Teng, Gaofeng; Chen-Wiegart, Yu-chen Karen Journal of the American Chemical Society, Vol. 140, Issue 39 https://doi.org/10.1021/jacs.8b06150	journal	August 2018
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries Lin, Feng; Markus, Isaac M.; Nordlund, Dennis Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4529	journal	March 2014
A New Coating Method for Alleviating Surface Degradation of LiNi _0.6 Co _0.2 Mn _0.2 O ₂ Cathode Material: Nanoscale Surface Treatment of Primary Particles Kim, Hyejung; Kim, Min Gyu; Jeong, Hu Young Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/acs.nanolett.5b00045	journal	February 2015
Nanoscale Imaging of Lithium Ion Distribution During In Situ Operation of Battery Electrode and Electrolyte Holtz, Megan E.; Yu, Yingchao; Gunceler, Deniz Nano Letters, Vol. 14, Issue 3 https://doi.org/10.1021/nl404577c	journal	February 2014
In Situ Atomic-Scale Observation of Electrochemical Delithiation Induced Structure Evolution of LiCoO ₂ Cathode in a Working All-Solid-State Battery Gong, Yue; Zhang, Jienan; Jiang, Liwei Journal of the American Chemical Society, Vol. 139, Issue 12 https://doi.org/10.1021/jacs.6b13344	journal	March 2017
Using Real-Time Electron Microscopy To Explore the Effects of Transition-Metal Composition on the Local Thermal Stability in Charged Li _x Ni _y Mn _z Co _{1– y – z} O ₂ Cathode Materials Hwang, Sooyeon; Kim, Seung Min; Bak, Seong-Min Chemistry of Materials, Vol. 27, Issue 11 https://doi.org/10.1021/acs.chemmater.5b00709	journal	May 2015
Capacity-Fading Mechanisms of LiNiO[sub 2]-Based Lithium-Ion Batteries Muto, Shunsuke; Sasano, Yusuke; Tatsumi, Kazuyoshi Journal of The Electrochemical Society, Vol. 156, Issue 5 https://doi.org/10.1149/1.3076137	journal	January 2009
Tracking lithium transport and electrochemical reactions in nanoparticles Wang, Feng; Yu, Hui-Chia; Chen, Min-Hua Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms2185	journal	January 2012
In-situ X-ray diffraction studies of lithium–sulfur batteries Cañas, Natalia A.; Wolf, Steffen; Wagner, Norbert Journal of Power Sources, Vol. 226 https://doi.org/10.1016/j.jpowsour.2012.10.092	journal	March 2013
Thermal behavior of delithiated Li(Ni0.8Co0.15Al0.05)O2 and Li1.1(Ni1/3Co1/3Mn1/3)0.9O2 powders Belharouak, Ilias; Lu, Wenquan; Liu, Jun Journal of Power Sources, Vol. 174, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.06.092	journal	December 2007
Cation Ordering in Li[Ni _x Mn _x Co _{(1–2 x )} ]O ₂ -Layered Cathode Materials: A Nuclear Magnetic Resonance (NMR), Pair Distribution Function, X-ray Absorption Spectroscopy, and Electrochemical Study Zeng, Dongli; Cabana, Jordi; Bréger, Julien Chemistry of Materials, Vol. 19, Issue 25 https://doi.org/10.1021/cm702241a	journal	December 2007
Complex structural dynamics of nanocatalysts revealed in Operando conditions by correlated imaging and spectroscopy probes Li, Y.; Zakharov, D.; Zhao, S. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8583	journal	June 2015
Nanoscale Zirconium-Abundant Surface Layers on Lithium- and Manganese-Rich Layered Oxides for High-Rate Lithium-Ion Batteries Ahn, Juhyeon; Kim, Jong Hak; Cho, Byung Won Nano Letters, Vol. 17, Issue 12 https://doi.org/10.1021/acs.nanolett.7b04158	journal	November 2017
Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study Xu, Bo; Fell, Christopher R.; Chi, Miaofang Energy & Environmental Science, Vol. 4, Issue 6 https://doi.org/10.1039/c1ee01131f	journal	January 2011
First In Situ Observation of the LiCoO ₂ Electrode/Electrolyte Interface by Total-Reflection X-ray Absorption Spectroscopy Takamatsu, Daiko; Koyama, Yukinori; Orikasa, Yuki Angewandte Chemie International Edition, Vol. 51, Issue 46 https://doi.org/10.1002/anie.201203910	journal	October 2012
Origin of voltage decay in high-capacity layered oxide electrodes Sathiya, M.; Abakumov, A. M.; Foix, D. Nature Materials, Vol. 14, Issue 2 https://doi.org/10.1038/nmat4137	journal	December 2014
In Situ TEM Observation of Local Phase Transformation in a Rechargeable LiMn ₂ O ₄ Nanowire Battery Lee, Soyeon; Oshima, Yoshifumi; Hosono, Eiji The Journal of Physical Chemistry C, Vol. 117, Issue 46 https://doi.org/10.1021/jp409032r	journal	November 2013
Investigation of inorganic compounds on the surface of cathode materials using Li and O K-edge XANES Kobayashi, Hironori; Emura, Shuichi; Arachi, Yoshinori Journal of Power Sources, Vol. 174, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.06.135	journal	December 2007
Investigation of Changes in the Surface Structure of Li _x Ni _0.8 Co _0.15 Al _0.05 O ₂ Cathode Materials Induced by the Initial Charge Hwang, Sooyeon; Chang, Wonyoung; Kim, Seung Min Chemistry of Materials, Vol. 26, Issue 2 https://doi.org/10.1021/cm403332s	journal	December 2013
Phase Boundary Propagation in Li-Alloying Battery Electrodes Revealed by Liquid-Cell Transmission Electron Microscopy Leenheer, Andrew J.; Jungjohann, Katherine L.; Zavadil, Kevin R. ACS Nano, Vol. 10, Issue 6 https://doi.org/10.1021/acsnano.6b02200	journal	May 2016
Profiling the nanoscale gradient in stoichiometric layered cathode particles for lithium-ion batteries Lin, Feng; Nordlund, Dennis; Markus, Isaac M. Energy & Environmental Science, Vol. 7, Issue 9 https://doi.org/10.1039/C4EE01400F	journal	January 2014
Comprehensive Insights into the Structural and Chemical Changes in Mixed-Anion FeOF Electrodes by Using Operando PDF and NMR Spectroscopy Wiaderek, Kamila M.; Borkiewicz, Olaf J.; Castillo-Martínez, Elizabeth Journal of the American Chemical Society, Vol. 135, Issue 10 https://doi.org/10.1021/ja400229v	journal	March 2013
Studies of local degradation phenomena in composite cathodes for lithium-ion batteries Kerlau, Marie; Marcinek, Marek; Srinivasan, Venkat Electrochimica Acta, Vol. 52, Issue 17 https://doi.org/10.1016/j.electacta.2007.02.085	journal	May 2007
Observation of Microstructural Evolution in Li Battery Cathode Oxide Particles by In Situ Electron Microscopy Miller, Dean J.; Proff, Christian; Wen, J. G. Advanced Energy Materials, Vol. 3, Issue 8 https://doi.org/10.1002/aenm.201300015	journal	May 2013
Conflicting Roles of Nickel in Controlling Cathode Performance in Lithium Ion Batteries Gu, Meng; Belharouak, Ilias; Genc, Arda Nano Letters, Vol. 12, Issue 10 https://doi.org/10.1021/nl302249v	journal	September 2012
Coupling of electrochemically triggered thermal and mechanical effects to aggravate failure in a layered cathode Yan, Pengfei; Zheng, Jianming; Chen, Tianwu Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04862-w	journal	June 2018
Investigation of the Charge Compensation Mechanism on the Electrochemically Li-Ion Deintercalated Li ₁ _- _x Co _1/3 Ni _1/3 Mn _1/3 O ₂ Electrode System by Combination of Soft and Hard X-ray Absorption Spectroscopy Yoon, Won-Sub; Balasubramanian, Mahalingam; Chung, Kyung Yoon Journal of the American Chemical Society, Vol. 127, Issue 49 https://doi.org/10.1021/ja0530568	journal	December 2005
A New High Power LiNi _0.81 Co _0.1 Al _0.09 O ₂ Cathode Material for Lithium-Ion Batteries Jo, Minki; Noh, Mijung; Oh, Pilgun Advanced Energy Materials, Vol. 4, Issue 13 https://doi.org/10.1002/aenm.201301583	journal	April 2014
Visualization of anisotropic-isotropic phase transformation dynamics in battery electrode particles Wang, Jiajun; Karen Chen-Wiegart, Yu-chen; Eng, Christopher Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12372	journal	August 2016
Direct observation of microstructural evolution in Li battery cathode oxide particles during electrochemical cycling by in situ electron microscopy Miller, D.; Proff, C.; Wen, J. Microscopy and Microanalysis, Vol. 18, Issue S2 https://doi.org/10.1017/S1431927612007398	journal	July 2012
Surface Characterization of Electrodes from High Power Lithium-Ion Batteries Andersson, A. M.; Abraham, D. P.; Haasch, R. Journal of The Electrochemical Society, Vol. 149, Issue 10 https://doi.org/10.1149/1.1505636	journal	January 2002
Thermally-driven mesopore formation and oxygen release in delithiated NCA cathode particles Besli, Münir M.; Shukla, Alpesh Khushalchand; Wei, Chenxi Journal of Materials Chemistry A, Vol. 7, Issue 20 https://doi.org/10.1039/C9TA01720H	journal	January 2019
Ni and Co Segregations on Selective Surface Facets and Rational Design of Layered Lithium Transition-Metal Oxide Cathodes Yan, Pengfei; Zheng, Jianming; Zheng, Jiaxin Advanced Energy Materials, Vol. 6, Issue 9 https://doi.org/10.1002/aenm.201502455	journal	February 2016
Atomic-Scale Observation of Electrochemically Reversible Phase Transformations in SnSe ₂ Single Crystals Kim, Sungkyu; Yao, Zhenpeng; Lim, Jin-Myoung Advanced Materials, Vol. 30, Issue 51 https://doi.org/10.1002/adma.201804925	journal	October 2018
Origin and hysteresis of lithium compositional spatiodynamics within battery primary particles Lim, Jongwoo; Li, Yiyang; Alsem, Daan Hein Science, Vol. 353, Issue 6299 https://doi.org/10.1126/science.aaf4914	journal	August 2016
3D analysis of a LiCoO2–Li(Ni1/3Mn1/3Co1/3)O2 Li-ion battery positive electrode using x-ray nano-tomography Chen-Wiegart, Yu-chen Karen; Liu, Zhao; Faber, Katherine T. Electrochemistry Communications, Vol. 28 https://doi.org/10.1016/j.elecom.2012.12.021	journal	March 2013
Fracture of electrodes in lithium-ion batteries caused by fast charging Zhao, Kejie; Pharr, Matt; Vlassak, Joost J. Journal of Applied Physics, Vol. 108, Issue 7 https://doi.org/10.1063/1.3492617	journal	October 2010
Investigating the Reversibility of Structural Modifications of Li _x Ni _y Mn _z Co _{1– y – z} O ₂ Cathode Materials during Initial Charge/Discharge, at Multiple Length Scales Hwang, Sooyeon; Kim, Seung Min; Bak, Seong-Min Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b02457	journal	August 2015
Cooling Induced Surface Reconstruction during Synthesis of High‐Ni Layered Oxides Zhang, Ming‐Jian; Hu, Xiaobing; Li, Maofan Advanced Energy Materials, Vol. 9, Issue 43 https://doi.org/10.1002/aenm.201901915	journal	October 2019
Studying the Charging Process of a Lithium-Ion Battery toward 10 V by In Situ X-ray Absorption and Diffraction: Lithium Insertion/Extraction with Side Reactions at Positive and Negative Electrodes Makimura, Yoshinari; Sasaki, Tsuyoshi; Oka, Hideaki Journal of The Electrochemical Society, Vol. 163, Issue 7 https://doi.org/10.1149/2.1171607jes	journal	January 2016
Understanding the Degradation Mechanisms of LiNi _0.5 Co _0.2 Mn _0.3 O ₂ Cathode Material in Lithium Ion Batteries Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun Advanced Energy Materials, Vol. 4, Issue 1 https://doi.org/10.1002/aenm.201300787	journal	August 2013
Conversion Reaction Mechanisms in Lithium Ion Batteries: Study of the Binary Metal Fluoride Electrodes Wang, Feng; Robert, Rosa; Chernova, Natasha A. Journal of the American Chemical Society, Vol. 133, Issue 46 https://doi.org/10.1021/ja206268a	journal	November 2011
In situ x-ray absorption spectroscopic study of the Li[Ni1∕3Co1∕3Mn1∕3]O2 cathode material Deb, Aniruddha; Bergmann, Uwe; Cramer, Stephen P. Journal of Applied Physics, Vol. 97, Issue 11 https://doi.org/10.1063/1.1921328	journal	June 2005
Microstructural Changes in LiNi0.8Co0.15Al0.05O2 Positive Electrode Material during the First Cycle Zheng, Shijian; Huang, Rong; Makimura, Yoshinari Journal of The Electrochemical Society, Vol. 158, Issue 4 https://doi.org/10.1149/1.3544843	journal	January 2011
Distinct charge dynamics in battery electrodes revealed by in situ and operando soft X-ray spectroscopy Liu, Xiaosong; Wang, Dongdong; Liu, Gao Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3568	journal	October 2013
Nickel-Rich Layered Cathode Materials for Automotive Lithium-Ion Batteries: Achievements and Perspectives Myung, Seung-Taek; Maglia, Filippo; Park, Kang-Joon ACS Energy Letters, Vol. 2, Issue 1 https://doi.org/10.1021/acsenergylett.6b00594	journal	December 2016
Atomic resolution of lithium ions in LiCoO2 Shao-Horn, Yang; Croguennec, Laurence; Delmas, Claude Nature Materials, Vol. 2, Issue 7 https://doi.org/10.1038/nmat922	journal	June 2003
Correlating Structural Changes and Gas Evolution during the Thermal Decomposition of Charged Li _x Ni _0.8 Co _0.15 Al _0.05 O ₂ Cathode Materials Bak, Seong-Min; Nam, Kyung-Wan; Chang, Wonyoung Chemistry of Materials, Vol. 25, Issue 3 https://doi.org/10.1021/cm303096e	journal	January 2013
Revealing the reaction mechanisms of Li–O2 batteries using environmental transmission electron microscopy Luo, Langli; Liu, Bin; Song, Shidong Nature Nanotechnology, Vol. 12, Issue 6 https://doi.org/10.1038/nnano.2017.27	journal	March 2017
Structural and electrochemical characteristics of Co and Al co-doped lithium nickelate cathode materials for lithium-ion batteries Cao, Hui; Xia, Baojia; Xu, Naixin Journal of Alloys and Compounds, Vol. 376, Issue 1-2 https://doi.org/10.1016/j.jallcom.2004.01.008	journal	August 2004
TEM Study of Electrochemical Cycling-Induced Damage and Disorder in LiCoO[sub 2] Cathodes for Rechargeable Lithium Batteries Wang, Haifeng Journal of The Electrochemical Society, Vol. 146, Issue 2 https://doi.org/10.1149/1.1391631	journal	January 1999
In situ X-ray absorption spectroscopic study of Li-rich layered cathode material Li[Ni0.17Li0.2Co0.07Mn0.56]O2 Ito, Atsushi; Sato, Yuichi; Sanada, Takashi Journal of Power Sources, Vol. 196, Issue 16 https://doi.org/10.1016/j.jpowsour.2010.09.105	journal	August 2011
Electrochemical Properties and Thermal Stability of Li[sub a]Ni[sub 1−x]CO[sub x]O[sub 2] Cathode Materials Cho, Jaephil; Jung, HyunSook; Park, YoungChul Journal of The Electrochemical Society, Vol. 147, Issue 1 https://doi.org/10.1149/1.1393137	journal	January 2000
Surface-to-Bulk Redox Coupling through Thermally Driven Li Redistribution in Li- and Mn-Rich Layered Cathode Materials Li, Shaofeng; Lee, Sang-Jun; Wang, Xuelong Journal of the American Chemical Society, Vol. 141, Issue 30 https://doi.org/10.1021/jacs.9b05349	journal	July 2019
Prevention of the Micro Cracks Generation in LiNiCoAlO ₂ Cathode by the Restriction of ΔDOD Watanabe, Shoichiro; Hosokawa, Takashi; Morigaki, Ken'ichi ECS Transactions, Vol. 41, Issue 41 https://doi.org/10.1149/1.4717964	journal	May 2012
Rapid mapping of lithiation dynamics in transition metal oxide particles with operando X-ray absorption spectroscopy Marone, Federica; Grolimund, Daniel; Wood, Vanessa ETH Zurich https://doi.org/10.3929/ethz-b-000114146	text	January 2016
Investigation of the Charge Compensation Mechanism on the Electrochemically Li-Ion Deintercalated Li1-xCo1/3Ni1/3Mn1/3O2 Electrode System by Combination of Soft and Hard X-Ray Absorption Spectroscopy. Yoon, Won-Sub; Balasubramanian, Mahalingam; Chung, Kyung Yoon ChemInform, Vol. 37, Issue 13 https://doi.org/10.1002/chin.200613019	journal	March 2006
Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging Singer, A.; Zhang, M.; Hy, S. Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2018-02753	text	January 2018
Nanoscale Imaging of Lithium Ion Distribution During In Situ Operation of Battery Electrode and Electrolyte Holtz, Megan E.; Yu, Yingchao; Gunceler, Deniz arXiv https://doi.org/10.48550/arxiv.1311.6490	text	January 2013

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