Chiral Carbon Dots Synthesized on Cellulose Nanocrystals

Chekini, Mahshid; Prince, Elisabeth; Zhao, Lily; Mundoor, Haridas; Smalyukh, Ivan I.; Kumacheva, Eugenia

doi:10.1002/adom.201901911

Chiral Carbon Dots Synthesized on Cellulose Nanocrystals

Journal Article · Wed Dec 18 00:00:00 EST 2019 · Advanced Optical Materials

DOI:https://doi.org/10.1002/adom.201901911· OSTI ID:1803667

Chekini, Mahshid ^[1]; Prince, Elisabeth ^[2]; Zhao, Lily ^[2]; Mundoor, Haridas ^[3]; Smalyukh, Ivan I. ^[4]; ^[5]

Univ. of Toronto, ON (Canada). Dept. of Chemistry; OSTI
Univ. of Toronto, ON (Canada). Dept. of Chemistry
Univ. of Colorado, Boulder, CO (United States). Dept. of Physics. Soft Materials Research Center
Univ. of Colorado, Boulder, CO (United States). Dept. of Physics. Soft Materials Research Center. Dept. of Electrical, Computer, and Energy Engineering. Materials Science and Engineering Program
Univ. of Toronto, ON (Canada). Dept. of Chemistry. Dept. of Chemical Engineering and Applied Chemistry

Hybrid nanoparticles composed of cellulose nanocrystals (CNCs) and carbon-dots (C-dots) have promising applications in chemistry, biology, and nanomedicine, owing to the photoluminescence, sensory properties, and cytocompatibility of C-dots, and chirality, cytobiocompatibility, and high cellular uptake of CNCs. The possibility of circularly polarized luminescence in such nanoparticles is particularly attractive. Herein, scalable and straightforward hydrothermal synthesis of nitrogen-doped fluorescent C-dots under reflux condition by using CNCs as a carbon source and chiral substrate is reported. Under ultraviolet irradiation, hybrid C-dot/CNC nanoparticles exhibit stronger emission of left-handed, than right-handed, circularly polarized light, with high dissymmetry factor up to 0.2. The nanoparticles are biocompatible: the normalized proliferation index above 100% is determined for MCF 7 cells cultured in the suspension of C-dot/CNC nanoparticles. These hybrid nanoparticles can find applications as biotags for labeling, sensing, and therapeutics and as building blocks of photoluminescent cholesteric CNC films with photonic applications.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Colorado, Boulder, CO (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019293

OSTI ID:: 1803667

Alternate ID(s):: OSTI ID: 1579969

Journal Information:: Advanced Optical Materials, Journal Name: Advanced Optical Materials Journal Issue: 4 Vol. 8; ISSN 2195-1071

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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