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Title: A multi-scale experimental investigation of flow properties in coarse-grained hydrate reservoirs during production (Final Scientific/Technical Report)

Technical Report ·
DOI:https://doi.org/10.2172/1579563· OSTI ID:1579563

In this project, “A multi-scale experimental investigation of flow properties in coarse-grained hydrate reservoirs during production” we explored the relative permeability and dissipation behavior of hydrate-bearing coarse-grained sediment at the core scale and we observed the formation and dissociation of these materials at the pore scale with micro-CT and Raman experiments. The 3-year project results inform reservoir simulation efforts, critical to determining the viability of the coarse-grained hydrate reservoir as an energy resource. We performed the first 3 phase relative permeability experiments in a hydrate-bearing medium using the steady state method (gas and water flow in the presence of hydrate). Results support a model where water is the most wetting phase, hydrate is the intermediate wetting phase, and gas is the least wetting phase. This model can be used to predict relative permeability of gas and water in the presence of hydrate. We showed that when hydrate dissociates, it does so at a pressure and temperature predicted for fresh water (no salinity) conditions. At the scale of a grid block, reservoir simulation models should assume that hydrate dissociates at the freshwater phase boundary. We observed that the chemistry and the pore habit of methane hydrates change dramatically over the timescales of experiments (hours to weeks). It takes weeks to months for hydrates to evolve from a non-stoichiometric to stoichiometric compound with 3:1 large cage vs small cage occupancy. We documented hydrates forming initially in small clayey silt surfaces but gradually concentrated in large pores in sand-sized sediment.

Research Organization:
University of Texas
Sponsoring Organization:
USDOE Office of Fossil Energy (FE), Oil & Natural Gas
Contributing Organization:
University of Texas
DOE Contract Number:
FE0028967
OSTI ID:
1579563
Report Number(s):
DOE-UT-0028967-Final-report
Country of Publication:
United States
Language:
English