Joint charge storage for high-rate aqueous zinc-manganese dioxide batteries

Jin, Yan; Zou, Lianfeng; Liu, Lili; Engelhard, Mark H.; Patel, Rajankumar L.; Nie, Zimin; Han, Kee Sung; Shao, Yuyan; Wang, Chongmin; Zhu, Jia; Pan, Huilin; Liu, Jun

doi:10.1002/adma.201900567

Title: Joint charge storage for high-rate aqueous zinc-manganese dioxide batteries

Journal Article · Fri Jul 19 00:00:00 EDT 2019 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201900567· OSTI ID:1578029

Jin, Yan ^[1]; Zou, Lianfeng ^[2];

^[2];

^[2]; Nie, Zimin ^[2]; Han, Kee Sung ^[2];

^[2];

^[2]; Zhu, Jia ^[3]; Pan, Huilin ^[2]; Liu, Jun ^[2]

UNIVERSITY PROGRAMS
BATTELLE (PACIFIC NW LAB)
Chinese Academy of Sciences

Aqueous rechargeable zinc-manganese dioxide batteries have great promise for large-scale energy storage due to the use of environmental friendly, abundant, and rechargeable Zn metal anode and MnO2 cathode. In the literature various intercalation and conversion reaction mechanisms have been reported depending on the origin of the starting materials, but it is not clear how these mechanisms can be simultaneously manipulated to improve the charge storage and transport properties. Here, we report a systematical study to understand the electrolyte controlled charge-storage mechanisms in layered d-MnO2. A joint Zn2+ intercalation pseudocapacitance in bulky d-MnO2 and H+ conversion reaction pathway in a wide C-rate charge-discharge range facilitates the high rate performance of high capacity d-MnO2 cathodes. The Zn-d-MnO2 system delivers discharge capacity of 136.9 mAh g-1 at 20 C and capacity retention of 92% over 4,000 cycles with joint charge storage mechanisms.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1578029

Report Number(s):: PNNL-SA-140329

Journal Information:: Advanced Materials, Vol. 31, Issue 29

Country of Publication:: United States

Language:: English

References (37)

Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
Opportunities and challenges for a sustainable energy future Chu, Steven; Majumdar, Arun Nature, Vol. 488, Issue 7411, p. 294-303 https://doi.org/10.1038/nature11475	journal	August 2012
Materials Science and Materials Chemistry for Large Scale Electrochemical Energy Storage: From Transportation to Electrical Grid Liu, Jun; Zhang, Ji-Guang; Yang, Zhenguo Advanced Functional Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adfm.201200690	journal	June 2012
Towards greener and more sustainable batteries for electrical energy storage Larcher, D.; Tarascon, J-M. Nature Chemistry, Vol. 7, Issue 1 https://doi.org/10.1038/nchem.2085	journal	November 2014
The path towards sustainable energy Chu, Steven; Cui, Yi; Liu, Nian Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4834	journal	December 2016
Electricity storage for intermittent renewable sources Rugolo, Jason; Aziz, Michael J. Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee02542f	journal	January 2012
Manganese oxide-based materials as electrochemical supercapacitor electrodes Wei, Weifeng; Cui, Xinwei; Chen, Weixing Chem. Soc. Rev., Vol. 40, Issue 3 https://doi.org/10.1039/C0CS00127A	journal	January 2011
Carbon-based materials as supercapacitor electrodes Zhang, Li Li; Zhao, X. S. Chemical Society Reviews, Vol. 38, Issue 9 https://doi.org/10.1039/b813846j	journal	January 2009
Materials for electrochemical capacitors Simon, Patrice; Gogotsi, Yury Nature Materials, Vol. 7, Issue 11 https://doi.org/10.1038/nmat2297	journal	November 2008
Pseudocapacitive oxide materials for high-rate electrochemical energy storage Augustyn, Veronica; Simon, Patrice; Dunn, Bruce Energy & Environmental Science, Vol. 7, Issue 5 https://doi.org/10.1039/c3ee44164d	journal	January 2014
Investigation of Pseudocapacitive Charge-Storage Reaction of MnO[sub 2]⋅nH[sub 2]O Supercapacitors in Aqueous Electrolytes Kuo, Shin-Liang; Wu, Nae-Lih Journal of The Electrochemical Society, Vol. 153, Issue 7 https://doi.org/10.1149/1.2197667	journal	January 2006
Asymmetric Supercapacitors Based on Graphene/MnO2 and Activated Carbon Nanofiber Electrodes with High Power and Energy Density Fan, Zhuangjun; Yan, Jun; Wei, Tong Advanced Functional Materials, Vol. 21, Issue 12 https://doi.org/10.1002/adfm.201100058	journal	April 2011
Graphene-based in-plane micro-supercapacitors with high power and energy densities Wu, Zhong–Shuai; Parvez, Khaled; Feng, Xinliang Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3487	journal	September 2013
Recent Advances in Zn-Ion Batteries Song, Ming; Tan, Hua; Chao, Dongliang Advanced Functional Materials, Vol. 28, Issue 41 https://doi.org/10.1002/adfm.201802564	journal	August 2018
Polyaniline-intercalated manganese dioxide nanolayers as a high-performance cathode material for an aqueous zinc-ion battery Huang, Jianhang; Wang, Zhuo; Hou, Mengyan Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04949-4	journal	July 2018
Reversible aqueous zinc/manganese oxide energy storage from conversion reactions Pan, Huilin; Shao, Yuyan; Yan, Pengfei Nature Energy, Vol. 1, Issue 5 https://doi.org/10.1038/nenergy.2016.39	journal	April 2016
Zn/MnO ₂ Battery Chemistry With H ⁺ and Zn ²⁺ Coinsertion Sun, Wei; Wang, Fei; Hou, Singyuk Journal of the American Chemical Society, Vol. 139, Issue 29 https://doi.org/10.1021/jacs.7b04471	journal	July 2017
Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities Zhang, Ning; Cheng, Fangyi; Liu, Junxiang Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00467-x	journal	September 2017
Mechanism of Zn Insertion into Nanostructured δ-MnO ₂ : A Nonaqueous Rechargeable Zn Metal Battery Han, Sang-Don; Kim, Soojeong; Li, Dongguo Chemistry of Materials, Vol. 29, Issue 11 https://doi.org/10.1021/acs.chemmater.7b00852	journal	May 2017
Ultrafast Zn ²⁺ Intercalation and Deintercalation in Vanadium Dioxide Ding, Junwei; Du, Zhiguo; Gu, Linqing Advanced Materials, Vol. 30, Issue 26 https://doi.org/10.1002/adma.201800762	journal	May 2018
A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode Kundu, Dipan; Adams, Brian D.; Duffort, Victor Nature Energy, Vol. 1, Issue 10 https://doi.org/10.1038/nenergy.2016.119	journal	August 2016
Aqueous rechargeable zinc/sodium vanadate batteries with enhanced performance from simultaneous insertion of dual carriers Wan, Fang; Zhang, Linlin; Dai, Xi Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04060-8	journal	April 2018
An Aqueous Zinc-Ion Battery Based on Copper Hexacyanoferrate Trócoli, Rafael; La Mantia, Fabio ChemSusChem, Vol. 8, Issue 3 https://doi.org/10.1002/cssc.201403143	journal	December 2014
Towards High-Voltage Aqueous Metal-Ion Batteries Beyond 1.5 V: The Zinc/Zinc Hexacyanoferrate System Zhang, Leyuan; Chen, Liang; Zhou, Xufeng Advanced Energy Materials, Vol. 5, Issue 2 https://doi.org/10.1002/aenm.201400930	journal	September 2014
Cation-Deficient Spinel ZnMn ₂ O ₄ Cathode in Zn(CF ₃ SO ₃ ) ₂ Electrolyte for Rechargeable Aqueous Zn-Ion Battery Zhang, Ning; Cheng, Fangyi; Liu, Yongchang Journal of the American Chemical Society, Vol. 138, Issue 39 https://doi.org/10.1021/jacs.6b05958	journal	September 2016
Towards polyvalent ion batteries: A zinc-ion battery based on NASICON structured Na3V2(PO4)3 Li, Guolong; Yang, Ze; Jiang, Yan Nano Energy, Vol. 25 https://doi.org/10.1016/j.nanoen.2016.04.051	journal	July 2016
Energetic Zinc Ion Chemistry: The Rechargeable Zinc Ion Battery Xu, Chengjun; Li, Baohua; Du, Hongda Angewandte Chemie, Vol. 124, Issue 4 https://doi.org/10.1002/ange.201106307	journal	December 2011
A layered δ-MnO 2 nanoflake cathode with high zinc-storage capacities for eco-friendly battery applications Alfaruqi, Muhammad Hilmy; Gim, Jihyeon; Kim, Sungjin Electrochemistry Communications, Vol. 60 https://doi.org/10.1016/j.elecom.2015.08.019	journal	November 2015
Elucidating the intercalation mechanism of zinc ions into α-MnO ₂ for rechargeable zinc batteries Lee, Boeun; Lee, Hae Ri; Kim, Haesik Chemical Communications, Vol. 51, Issue 45 https://doi.org/10.1039/C5CC02585K	journal	January 2015
Electrochemically Induced Structural Transformation in a γ-MnO ₂ Cathode of a High Capacity Zinc-Ion Battery System Alfaruqi, Muhammad H.; Mathew, Vinod; Gim, Jihyeon Chemistry of Materials, Vol. 27, Issue 10 https://doi.org/10.1021/cm504717p	journal	May 2015
Regenerable Cu-intercalated MnO2 layered cathode for highly cyclable energy dense batteries Yadav, Gautam G.; Gallaway, Joshua W.; Turney, Damon E. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14424	journal	March 2017
Layered δ-MnO2 as positive electrode for lithium intercalation Du, Guodong; Wang, Jieqiang; Guo, Zaiping Materials Letters, Vol. 65, Issue 9 https://doi.org/10.1016/j.matlet.2011.01.073	journal	May 2011
High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance Augustyn, Veronica; Come, Jérémy; Lowe, Michael A. Nature Materials, Vol. 12, Issue 6 https://doi.org/10.1038/nmat3601	journal	April 2013
Behavior of Molybdenum Nitrides as Materials for Electrochemical Capacitors Liu, T. -C. Journal of The Electrochemical Society, Vol. 145, Issue 6 https://doi.org/10.1149/1.1838571	journal	January 1998
Ab Initio Study of the Charge-Storage Mechanisms in RuO ₂ -Based Electrochemical Ultracapacitors Liu, Yongduo; Zhou, Fei; Ozolins, Vidvuds The Journal of Physical Chemistry C, Vol. 116, Issue 1 https://doi.org/10.1021/jp207616s	journal	December 2011
Calcium Ion Coordination: A Comparison with That of Beryllium, Magnesium, and Zinc Katz, Amy Kaufman; Glusker, Jenny P.; Beebe, Scott A. Journal of the American Chemical Society, Vol. 118, Issue 24 https://doi.org/10.1021/ja953943i	journal	January 1996
Facile construction of Mn3O4-MnO2 hetero-nanorods/graphene nanocomposite for highly sensitive electrochemical detection of hydrogen peroxide Zeng, Fanyan; Pan, Yang; Yang, Yong Electrochimica Acta, Vol. 196 https://doi.org/10.1016/j.electacta.2016.03.031	journal	April 2016

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