Amino Acid Immobilization of Copper Surface Diffusion on Cu(111)

Guisinger, Nathan P.; Mannix, Andrew J.; Rankin, Rees B.; Kiraly, Brian; Phillips, Jesse A.; Darling, Seth B.; Fisher, Brandon L.; Hersam, Mark C.; Iski, Erin V.

doi:10.1002/admi.201900021

Amino Acid Immobilization of Copper Surface Diffusion on Cu(111)

Journal Article · Tue Mar 12 00:00:00 EDT 2019 · Advanced Materials Interfaces

DOI:https://doi.org/10.1002/admi.201900021· OSTI ID:1576752

Guisinger, Nathan P. ^[1]; Mannix, Andrew J. ^[2]; Rankin, Rees B. ^[3]; Kiraly, Brian ^[2]; Phillips, Jesse A. ^[4]; Darling, Seth B. ^[5]; Fisher, Brandon L. ^[1]; Hersam, Mark C. ^[6]; ^[4]

Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials
Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials; Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering
Villanova Univ., Villanova, PA (United States). Dept. of Chemical Engineering
The Univ. of Tulsa, Tulsa, OK (United States). Dept. of Chemistry and Biochemistry
Argonne National Lab. (ANL), Lemont, IL (United States). Chemical Sciences & Engineering Div. and Inst for Molecular Engineering; Univ. of Chicago, Chicago, IL (United States). Inst. for Molecular Engineering
Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering and Dept. of Chemistry

Surface diffusion and molecular self-assembly are two critically important processes in chemistry and nature. Amino acids deposited on a Cu(111) surface driving a separation at the 2D limit between self-assembling molecules and diffusing copper atoms is reported. Since the self-assembling amino acids prefer non-planar, tridentate bonding with neighboring adatoms, they attach to and immobilize diffusing copper adatoms on the surface. This chemical interaction freezes out the copper diffusion causing the condensation of solid copper adatom islands on the surface. Such separation and immobilization are observed for eight different amino acids, suggesting the generality of this phenomenon beyond a single amino acid species. Furthermore, at elevated temperatures, a disruption of the prototypical Ostwald ripening of adatom islands is also observed. Here, these results provide fundamental insight into chiral molecular self-assembly and its interplay with metal atom surface diffusion.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); Office of Naval Research

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1576752

Alternate ID(s):: OSTI ID: 1499076

Journal Information:: Advanced Materials Interfaces, Journal Name: Advanced Materials Interfaces Journal Issue: 7 Vol. 6; ISSN 2196-7350

Publisher:: Wiley-VCHCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

36 MATERIALS SCIENCE
Cu(111)
LT UHV-STM
adatoms
amino acids
metal surface diffusion
metal transport
molecular assembly
self-assembly

Amino Acid Immobilization of Copper Surface Diffusion on Cu(111)

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Cited By (1)

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