Single-source synthesis of ceramic oxide nanoparticles

Patent · Tue Sep 10 00:00:00 EDT 2019

OSTI ID:1576326

Boyle, Timothy J.; Chan, Rana; Sears, Jeremiah Matthew; Hernandez-Sanchez, Bernadette A.

The tris(trimethylsilyl)silanol (H-SST) ligand can be reacted with a Group 4 or 5 metal alkoxides in a solvent to form an SST-modified metal alkoxide precursor. Exemplary Group 4 precursors include [Ti(SST)2(OR)2] (OR=OPri, OBut, ONep); [Ti(SST)3(OBun)]; [Zr(SST)2(OBut)2(py)]; [Zr(SST)3(OR)] (OR=OBut, ONep); [Hf(SST)2(OBut)2]; and [Hf(SST)2(ONep)2(py)n] (n=1, 2), where OPri=OCH(CH3)2, OBut=OC(CH3)3, OBun=O(CH2)3CH3, ONep=OCH2C(CH3)3, and py=pyridine. Exemplary Group 5 precursors include [V(SST)3(py)2]; [Nb(SST)3(OEt)2]; [Nb(O)(SST)3(py)]; 2[H][(Nb(μ-O)2(SST))6(μ6-O)]; [Nb8O10(OEt)18(SST)2.⅕Na2O]; [Ta(SST)(μ-OEt)(OEt)3]2; and [Ta(SST)3(OEt)2]; where OEt=OCH2CH3. When thermally processed, the precursors can form unusual core-shell nanoparticles. For example, HfO2/SiO2 core/shell nanoparticles have demonstrated resistance to damage in extreme irradiation and thermal environments.

• Research Organization: National Technology & Engineering Solutions of Sandia, LLC, Albuquerque, NM (United States)
• Sponsoring Organization: USDOE
• DOE Contract Number: NA0003525
• Assignee: National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)
• Patent Number(s): 10,407,347
• Application Number: 15/901,776
• OSTI ID: 1576326
• Country of Publication: United States
• Language: English