Structural Evolution During Perovskite Crystal Formation and Degradation: In Situ and Operando X–Ray Diffraction Studies

Mundt, Laura E.; Schelhas, Laura T.

doi:10.1002/aenm.201903074

Structural Evolution During Perovskite Crystal Formation and Degradation: In Situ and Operando X–Ray Diffraction Studies

Journal Article · Mon Nov 25 00:00:00 UTC 2019 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201903074· OSTI ID:1596308

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SLAC National Accelerator Lab., Menlo Park, CA (United States)

This review provides an update on the progress in understanding formation and degradation mechanisms in halide perovskites for photovoltaic applications, as supported by in situ and operando X–ray scattering techniques. The value of these real–time analyses is particularly high for gaining insights into the structural evolution during crystal formation and decomposition upon exposure to external stress factors. This type of analysis reveals the pathways between starting and end points of a process rather than being limited to comparing states before and after the process. Special attention is put on the successful efforts toward upscaling including deposition techniques that are compatible to roll–to–roll processing. These processes are realized using fast annealing procedures. The development of these processes strongly benefited from in situ studies exploring the direct transition from precursor to perovskite without going through observable crystalline intermediate phases. A particular focus of this review is the benefit of using in situ and operando X–ray scattering techniques to better understand and ultimately improve device stability. In conclusion, the difference between structural stability of thin films and structural stability under device operation is highlighted, convincingly demonstrating the indispensability of operando studies.

View Accepted Manuscript (DOE)

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Solar Energy Technologies Office (EE-4S)

Grant/Contract Number:: AC02-76SF00515; AC36-08GO28308

OSTI ID:: 1596308

Alternate ID(s):: OSTI ID: 1575780

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 26 Vol. 10; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Technical Report · Sat Jul 17 04:00:00 UTC 2021 · OSTI ID:1885159

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36 MATERIALS SCIENCE
X‐ray scattering
halide perovskites
in situ

Structural Evolution During Perovskite Crystal Formation and Degradation: In Situ and Operando X–Ray Diffraction Studies

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