Silver-Containing α-MnO2 Nanorods: Electrochemistry in Rechargeable Aqueous Zn-MnO2 Batteries

Wang, Lei; Wu, Qiyuan; Abraham, Alyson; West, Patrick J.; Housel, Lisa M.; Singh, Gurpreet; Sadique, Nahian; Quilty, Calvin D.; Wu, Daren; Takeuchi, Esther S.; Marschilok, Amy C.; Takeuchi, Kenneth J.

doi:10.1149/2.0101915jes

Title: Silver-Containing α-MnO₂ Nanorods: Electrochemistry in Rechargeable Aqueous Zn-MnO₂ Batteries

Journal Article · Wed Oct 23 00:00:00 EDT 2019 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0101915jes· OSTI ID:1575426

^[1]; Wu, Qiyuan ^[1];

^[2];

^[3]; Housel, Lisa M. ^[2]; Singh, Gurpreet ^[2]; Sadique, Nahian ^[2]; Quilty, Calvin D. ^[2]; Wu, Daren ^[3];

^[4];

^[5]

Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate
Stony Brook Univ., Stony Brook, NY (United States). Dept. of Chemistry
Stony Brook Univ., Stony Brook, NY (United States). Dept. of Materials Science and Chemical Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate; Stony Brook Univ., Stony Brook, NY (United States). Dept. of Chemistry and Dept. of Materials Science and Chemical Engineering
Stony Brook Univ., Stony Brook, NY (United States). Dept. of Chemistry and Dept. of Materials Science and Chemical Engineering

The reduction and subsequent oxidation of silver hollandite nanorods, Ag_1.5Mn₈O₁₆, were explored in aqueous ZnSO₄ electrolyte for the first time. The impact of reduction on the electrodes was probed where images of recovered cathodes were collected to evaluate the changes in morphology, structural, and electrochemical properties as a function of varying potential. Ag metal particle formation upon reduction was observed on reduction through a reduction-displacement reaction as confirmed by SEM/EDS, XRD, and XAS results accompanied by a decrease in charge transfer impedance, as determined by electrochemical impedance spectroscopy. On charge, in contrast to the reduction/oxidation electrochemistry in non-aqueous media where irreversible formation of silver metal was observed, disappearance of the silver metal is observed indicating oxidation of the silver centers is facilitated in aqueous electrolyte.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1575426

Report Number(s):: BNL-212371-2019-JAAM

Journal Information:: Journal of the Electrochemical Society, Vol. 166, Issue 15; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 19 works

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Title: Silver-Containing α-MnO₂ Nanorods: Electrochemistry in Rechargeable Aqueous Zn-MnO₂ Batteries