Enhancement of magnetodielectric coupling in 6H-perovskites Ba3RRu2O9 for heavier rare-earth cations (R=Ho,Tb)

Basu, Tathamay; Caignaert, Vincent; Ghara, Somnath; Ke, Xianglin; Pautrat, Alain; Krohns, Stephan; Loidl, Alois; Raveau, Bernard

doi:10.1103/PhysRevMaterials.3.114401

Title: Enhancement of magnetodielectric coupling in 6H-perovskites ${Ba}_{3} R {Ru}_{2} O_{9}$ for heavier rare-earth cations ( $R = Ho, Tb$ )

Journal Article · Fri Nov 01 00:00:00 EDT 2019 · Physical Review Materials

DOI:https://doi.org/10.1103/PhysRevMaterials.3.114401· OSTI ID:1572689

^[1]; Caignaert, Vincent ^[2]; Ghara, Somnath ^[3]; Ke, Xianglin ^[4]; Pautrat, Alain ^[2];

^[4];

^[3]; Raveau, Bernard ^[2]

Lab. CRISMAT, Caen (France); Michigan State Univ., East Lansing, MI (United States); Univ. of Augsburg, Augsburg (Germany)
Lab. CRISMAT, Caen (France)
Univ. of Augsburg, Augsburg (Germany)
Michigan State Univ., East Lansing, MI (United States)

The role of rare-earth (R) ions in magnetodielectric (MD) coupling is always intriguing and markedly different for different systems. Although many reports are available concerning this aspect in frustrated 3d-transition metal oxides, no such reports exist on higher d (4d/5d)-orbital based systems due to the rare availability of highly insulating 4d/5d systems. Here, we systematically investigated the magnetic, dielectric, ferroelectric, and magnetodielectric behavior of the 6H-perovskites Ba₃RRu₂O₉ for different R-ions, namely R = Sm, Tb, and Ho, which magnetically order at 12, 9.5, and 10.2 K, respectively. For R = Tb and Ho, the temperature and magnetic-field-dependent complex dielectric constant traces the magnetic features, which manifests MD coupling in this system. A weak magnetic-field (H) induced transition is observed for ~30 kOe, which is clearly captured in H-dependent dielectric measurements. No MD coupling is observed for Ba₃SmRu₂O₉. The MD coupling is enhanced by a factor of 3 and 20 times for R = Tb and Ho, respectively, when compared to that of the Nd-counterpart. Here, these results evidence the gradual enhancement of MD coupling with the introduction of heavier R-ions in this series, which is attributed to their larger moment values. Our investigation establishes dominating 4d(Ru)-4ƒ(R) magnetic correlation in this series for the heavier R-members.

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Research Organization:: Michigan State Univ., East Lansing, MI (United States). Dept. of Physics and Astronomy

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: SC0019259

OSTI ID:: 1572689

Journal Information:: Physical Review Materials, Vol. 3, Issue 11; ISSN 2475-9953

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 7 works

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36 MATERIALS SCIENCE
Magnetic
Multiferroic
magnetoelectric
Ru-based system

Title: Enhancement of magnetodielectric coupling in 6H-perovskites Ba 3 R Ru 2 O 9 for heavier rare-earth cations ( R = Ho , Tb )

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References (50)

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Title: Enhancement of magnetodielectric coupling in 6H-perovskites ${Ba}_{3} R {Ru}_{2} O_{9}$ for heavier rare-earth cations ( $R = Ho, Tb$ )