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Title: Tuning two-dimensional phase formation through epitaxial strain and growth conditions: silica and silicate on Ni x Pd 1−x (111) alloy substrates

Journal Article · · Nanoscale
DOI:https://doi.org/10.1039/C9NR05944J· OSTI ID:1572588
ORCiD logo [1];  [2]; ORCiD logo [3];  [3]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [4]; ORCiD logo [5]; ORCiD logo [6]; ORCiD logo [3]
  1. Department of Mechanical Engineering and Materials Science, Yale University, New Haven, USA
  2. Department of Applied Physics, Yale University, New Haven, USA
  3. Department of Chemical and Environmental Engineering, Yale University, New Haven, USA
  4. Department of Applied Physics, Yale University, New Haven, USA, Energy Sciences Institute
  5. Department of Mechanical Engineering and Materials Science, Yale University, New Haven, USA, Department of Chemical and Environmental Engineering
  6. Department of Mechanical Engineering and Materials Science, Yale University, New Haven, USA, Department of Applied Physics

The combined experimental and theoretical results demonstrate the manipulation of 2D VDW silica and 2D Ni silicate through growth conditions, and the determination of the maximum epitaxial strain imparted to the 2D system through alloy substrate.

Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0012704; SC0014414
OSTI ID:
1572588
Journal Information:
Nanoscale, Journal Name: Nanoscale Vol. 11 Journal Issue: 44; ISSN 2040-3364
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English
Citation Metrics:
Cited by: 8 works
Citation information provided by
Web of Science

References (59)

The structure of monolayer SiO2 on Mo(112): A 2-D [Si–O–Si] network or isolated [SiO4] units? journal October 2006
Generalized Gradient Approximation Made Simple journal October 1996
Graphene allotropes under extreme uniaxial strain: an ab initio theoretical study journal January 2015
New Metallic Allotropes of Planar and Tubular Carbon journal February 2000
Epitaxial graphene on ruthenium journal April 2008
Patterned Defect Structures Predicted for Graphene Are Observed on Single-Layer Silica Films journal August 2013
Two-dimensional silica: Crystalline and vitreous journal October 2012
Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene journal March 2013
Tuning Surface Properties of Low Dimensional Materials via Strain Engineering journal July 2016
Evolutionary selection growth of two-dimensional materials on polycrystalline substrates journal March 2018
The interaction of molecular and atomic oxygen with Si(100) and Si(111) journal January 1993
Atomic Arrangement in Two-Dimensional Silica: From Crystalline to Vitreous Structures journal September 2012
Atomic structure of a thin silica film on a Mo ( 112 ) substrate: A combined experimental and theoretical study journal April 2006
Strain-controlled electrocatalysis on multimetallic nanomaterials journal September 2017
Synthesis and chemistry of elemental 2D materials journal January 2017
Stacked 2D materials shed light journal February 2015
Accurate Molecular Van Der Waals Interactions from Ground-State Electron Density and Free-Atom Reference Data journal February 2009
Ultrathin silica films on Pd(111): Structure and adsorption properties journal December 2018
2D materials and van der Waals heterostructures journal July 2016
Grains and grain boundaries in single-layer graphene atomic patchwork quilts journal January 2011
Graphene-Like Two-Dimensional Materials journal January 2013
A high-speed variable-temperature ultrahigh vacuum scanning tunneling microscope journal September 1998
Virtual crystal approximation revisited: Application to dielectric and piezoelectric properties of perovskites journal March 2000
Controlling phase transition for single-layer MTe 2 (M = Mo and W): modulation of the potential barrier under strain journal January 2016
Thermodynamic modeling of the Pd-X (X=Ag, Co, Fe, Ni) systems journal May 1999
Template Effect in the Competition between Haeckelite and Graphene Growth on Ni(111): Quantum Chemical Molecular Dynamics Simulations journal November 2011
Directing the Structure of Two-Dimensional Silica and Silicates journal November 2016
Two-dimensional silica: Structural, mechanical properties, and strain-induced band gap tuning journal January 2016
Two-dimensional silica opens new perspectives journal December 2017
Thin silica films on Ru(0001): monolayer, bilayer and three-dimensional networks of [SiO4] tetrahedra journal January 2012
Structural and Electronic Heterogeneity of Two Dimensional Amorphous Silica Layers journal June 2014
Composition, structure, and stability of RuO 2 ( 110 ) as a function of oxygen pressure journal December 2001
Self-Consistent Equations Including Exchange and Correlation Effects journal November 1965
Support effects on the atomic structure of ultrathin silica films on metals journal April 2012
Transition Metal Induced Crystallization of Ultrathin Silica Films journal January 2017
Formation and Evolution of Ultrathin Silica Polymorphs on Ru(0001) Studied with Combined in Situ , Real-Time Methods journal October 2018
The Ni−Pd (Nickel-Palladium) system journal October 1984
Colossal grain growth yields single-crystal metal foils by contact-free annealing journal October 2018
Preparation and structure of Fe-containing aluminosilicate thin films journal January 2016
Nanometre-scale electronics with III–V compound semiconductors journal November 2011
Growth and Characterization of Crystalline Silica Films on Pd(100) journal November 2013
Van der Waals heterostructures journal July 2013
Strain Engineering of 2D Materials: Issues and Opportunities at the Interface journal January 2019
Recent Advances in Two-Dimensional Materials beyond Graphene journal October 2015
The Perdew–Burke–Ernzerhof exchange-correlation functional applied to the G2-1 test set using a plane-wave basis set journal June 2005
Inhomogeneous Electron Gas journal November 1964
The Atomic Structure of a Metal-Supported Vitreous Thin Silica Film journal November 2011
Atomic Structure of a Thin Silica Film on a Mo(112) Substrate: A Two-Dimensional Network of SiO 4 Tetrahedra journal August 2005
2H → 1T phase transition and hydrogen evolution activity of MoS 2 , MoSe 2 , WS 2 and WSe 2 strongly depends on the MX 2 composition journal January 2015
Epitaxial Ni x Pd 1– x (111) Alloy Substrates with Continuously Tunable Lattice Constants for 2D Materials Growth journal March 2017
Semiempirical GGA-type density functional constructed with a long-range dispersion correction journal January 2006
Ultrathin Silica Films on Metals: The Long and Winding Road to Understanding the Atomic Structure journal November 2012
Graphene on metal surfaces journal June 2009
Atomic Structure of an Ultrathin Fe-Silicate Film Grown on a Metal: A Monolayer of Clay? journal December 2013
Direct Imaging of a Two-Dimensional Silica Glass on Graphene journal January 2012
Structure of a Two-Dimensional Silicate Layer Formed by Reaction with an Alloy Substrate journal January 2019
First-Principles Atomistic Thermodynamics for Oxidation Catalysis: Surface Phase Diagrams and Catalytically Interesting Regions journal January 2003
Ultrathin Ti-Silicate Film on a Ru(0001) Surface journal June 2015
Defects in bilayer silica and graphene: common trends in diverse hexagonal two-dimensional systems journal December 2013

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