Hierarchically Structured CeO2 Catalyst Particles From Nanocellulose/Alginate Templates for Upgrading of Fast Pyrolysis Vapors

Moyer, Kathleen; Conklin, Davis R.; Mukarakate, Calvin; Vardon, Derek R.; Nimlos, Mark R.; Ciesielski, Peter N.

doi:10.3389/fchem.2019.00730

Title: Hierarchically Structured CeO2 Catalyst Particles From Nanocellulose/Alginate Templates for Upgrading of Fast Pyrolysis Vapors

Journal Article · Wed Oct 30 00:00:00 EDT 2019 · Frontiers in Chemistry

DOI:https://doi.org/10.3389/fchem.2019.00730· OSTI ID:1572417

Moyer, Kathleen; Conklin, Davis R.; Mukarakate, Calvin; Vardon, Derek R.; Nimlos, Mark R.; Ciesielski, Peter N.

Hierarchically structured porous materials often exhibit advantageous functionality for many applications including catalysts, adsorbents, and filtration systems. In this study, we report a facile approach to achieve hierarchically structured, porous cerium oxide (CeO₂) catalyst particles using a templating method based on nanocellulose, a class of renewable, plant-derived nanomaterials. We demonstrate the catalyst performance benefits provided by this templating method in the context of Catalytic Fast Pyrolysis (CFP) which is a promising conversion technology to produce renewable fuel and chemical products from biomass and other types of organic waste. We show that variations in the porous structures imparted by this templating method may be achieved by modifying the content of cellulose nanofibrils, cellulose nanocrystals, and alginate in the templating suspensions. Nitrogen physisorption reveals that nearly 10-fold increases in surface area can be achieved using this method with respect to commercially available cerium oxide powder. Multiscale electron microscopy further verifies that bio-derived templating can alter the morphology of the catalyst nanostructure and tune the distribution of meso- and macro-porosity within the catalyst particles while maintaining CeO₂ crystal structure. CFP experiments demonstrate that the templated catalysts display substantially higher activity on a gravimetric basis than their non-templated counterpart, and that variations in the catalyst architecture can impact the distribution of upgraded pyrolysis products. Finally, we demonstrate that the templating method described here may be extended to other materials derived from metal chlorides to achieve 3-dimensional networks of hierarchical porosity.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Bioenergy Technologies Office (BETO)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1572417

Alternate ID(s):: OSTI ID: 1574198

Report Number(s):: NREL/JA-2700-75394; 730

Journal Information:: Frontiers in Chemistry, Journal Name: Frontiers in Chemistry Vol. 7; ISSN 2296-2646

Publisher:: Frontiers Media SACopyright Statement

Country of Publication:: Switzerland

Language:: English

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Cited by: 7 works

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Web of Science

References (55)

Stabilization of furanics to cyclic ketone building blocks in the vapor phase Omotoso, Taiwo; Herrera, Leidy V.; Vann, Tyler Applied Catalysis B: Environmental, Vol. 254 https://doi.org/10.1016/j.apcatb.2019.04.079	journal	October 2019
Correction To Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications Zhu, Hongli; Luo, Wei; Ciesielski, Peter N. Chemical Reviews, Vol. 116, Issue 19 https://doi.org/10.1021/acs.chemrev.6b00576	journal	September 2016
Ultrahigh intercalation pseudocapacitance of mesoporous orthorhombic niobium pentoxide from a novel cellulose nanocrystal template Kong, Lingping; Zhang, Chuangfang; Wang, Jitong Materials Chemistry and Physics, Vol. 149-150 https://doi.org/10.1016/j.matchemphys.2014.10.051	journal	January 2015
Hierarchically porous materials: synthesis strategies and structure design Yang, Xiao-Yu; Chen, Li-Hua; Li, Yu Chemical Society Reviews, Vol. 46, Issue 2 https://doi.org/10.1039/C6CS00829A	journal	January 2017
Hierarchical porous ceramics with 3D reticular architecture and efficient flow-through filtration towards high-temperature particulate matter capture Liu, Jingjing; Ren, Bo; Wang, Yali Chemical Engineering Journal, Vol. 362 https://doi.org/10.1016/j.cej.2019.01.065	journal	April 2019
Low temperature carbonization of cellulose nanocrystals for high performance carbon anode of sodium-ion batteries Zhu, Hongli; Shen, Fei; Luo, Wei Nano Energy, Vol. 33 https://doi.org/10.1016/j.nanoen.2017.01.021	journal	March 2017
Multi-scale simulation of reaction, transport and deactivation in a SBA-16 supported catalyst for the conversion of ethanol to butadiene Bharadwaj, Vivek S.; Pecha, M. Brennan; Bu, Lintao Catalysis Today, Vol. 338 https://doi.org/10.1016/j.cattod.2019.05.042	journal	November 2019
A critical review of the current knowledge regarding the biological impact of nanocellulose Endes, C.; Camarero-Espinosa, S.; Mueller, S. Journal of Nanobiotechnology, Vol. 14, Issue 1 https://doi.org/10.1186/s12951-016-0230-9	journal	December 2016
A Sustainable Template for Mesoporous Zeolite Synthesis White, Robin J.; Fischer, Anna; Goebel, Caren Journal of the American Chemical Society, Vol. 136, Issue 7 https://doi.org/10.1021/ja411586h	journal	February 2014
Hierarchical zeolites: Synthesis and catalytic properties Feliczak-Guzik, Agnieszka Microporous and Mesoporous Materials, Vol. 259 https://doi.org/10.1016/j.micromeso.2017.09.030	journal	March 2018
Properties and Reactivity of Nanostructured CeO ₂ Powders: Comparison among Two Synthesis Procedures Natile, Marta M.; Boccaletti, Giovanni; Glisenti, Antonella Chemistry of Materials, Vol. 17, Issue 25 https://doi.org/10.1021/cm051352d	journal	December 2005
Photocatalytic Antifouling Graphene Oxide-Mediated Hierarchical Filtration Membranes with Potential Applications on Water Purification Xu, Chao; Xu, Yuelian; Zhu, Jiaoli ACS Applied Materials & Interfaces, Vol. 6, Issue 18 https://doi.org/10.1021/am5040945	journal	September 2014
Chemistry challenges to enable a sustainable bioeconomy Fitzgerald, Nichole D. Nature Reviews Chemistry, Vol. 1, Issue 10 https://doi.org/10.1038/s41570-017-0080	journal	September 2017
Condensation reactions of propanal over CexZr1−xO2 mixed oxide catalysts Gangadharan, Anirudhan; Shen, Min; Sooknoi, Tawan Applied Catalysis A: General, Vol. 385, Issue 1-2 https://doi.org/10.1016/j.apcata.2010.06.048	journal	September 2010
American Process: Production of Low Cost Nanocellulose for Renewable, Advanced Materials Applications Nelson, Kim; Retsina, Theodora; Iakovlev, Mikhail Materials Research for Manufacturing https://doi.org/10.1007/978-3-319-23419-9_9	book	January 2016
Surfactant-assisted synthesis of CeO2 nanoparticles and their application in wastewater treatment Li, He; Wang, Guofeng; Zhang, Fei RSC Advances, Vol. 2, Issue 32 https://doi.org/10.1039/c2ra21590j	journal	January 2012
Biological Chitin-MOF Composites with Hierarchical Pore Systems for Air-Filtration Applications Wisser, Dorothea; Wisser, Florian M.; Raschke, Silvia Angewandte Chemie International Edition, Vol. 54, Issue 43 https://doi.org/10.1002/anie.201504572	journal	August 2015
Key advances in the chemical modification of nanocelluloses Habibi, Youssef Chem. Soc. Rev., Vol. 43, Issue 5 https://doi.org/10.1039/C3CS60204D	journal	January 2014
Inorganic Hollow Nanotube Aerogels by Atomic Layer Deposition onto Native Nanocellulose Templates Korhonen, Juuso T.; Hiekkataipale, Panu; Malm, Jari ACS Nano, Vol. 5, Issue 3 https://doi.org/10.1021/nn200108s	journal	February 2011
A Perspective on Catalytic Strategies for Deoxygenation in Biomass Pyrolysis Nolte, Michael W.; Shanks, Brent H. Energy Technology, Vol. 5, Issue 1 https://doi.org/10.1002/ente.201600096	journal	August 2016
Ordered Mesoporous CeO ₂ Synthesized by Nanocasting from Cubic Ia3d Mesoporous MCM-48 Silica: Formation, Characterization and Photocatalytic Activity Ji, Pengfei; Zhang, Jinlong; Chen, Feng The Journal of Physical Chemistry C, Vol. 112, Issue 46 https://doi.org/10.1021/jp8054087	journal	October 2008
Ultralight, highly thermally insulating and fire resistant aerogel by encapsulating cellulose nanofibers with two-dimensional MoS ₂ Yang, Lei; Mukhopadhyay, Alolika; Jiao, Yucong Nanoscale, Vol. 9, Issue 32 https://doi.org/10.1039/C7NR02243C	journal	January 2017
Catalytic Upgrading of Biomass Fast Pyrolysis Vapors with Nano Metal Oxides: An Analytical Py-GC/MS Study Lu, Qiang; Zhang, Zhi-Fei; Dong, Chang-Qing Energies, Vol. 3, Issue 11 https://doi.org/10.3390/en3111805	journal	November 2010
Review: nanocelluloses as versatile supports for metal nanoparticles and their applications in catalysis Kaushik, Madhu; Moores, Audrey Green Chemistry, Vol. 18, Issue 3 https://doi.org/10.1039/C5GC02500A	journal	January 2016
Synthesis and Characterization of Cerium Oxide Nanoparticles by Hydroxide Mediated Approach Chelliah, Muruganantham; Rayappan, John Bosco Balaguru; Krishnan, Uma Maheshwari Journal of Applied Sciences, Vol. 12, Issue 16 https://doi.org/10.3923/jas.2012.1734.1737	journal	December 2012
Modeling HCCI combustion of biofuels: A review Komninos, N. P.; Rakopoulos, C. D. Renewable and Sustainable Energy Reviews, Vol. 16, Issue 3 https://doi.org/10.1016/j.rser.2011.11.026	journal	April 2012
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Provisional) Sing, K. S. W. Pure and Applied Chemistry, Vol. 54, Issue 11 https://doi.org/10.1351/pac198254112201	journal	January 1982
Deactivation of Multilayered MFI Nanosheet Zeolite during Upgrading of Biomass Pyrolysis Vapors Xu, Mengze; Mukarakate, Calvin; Iisa, Kristiina ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 6 https://doi.org/10.1021/acssuschemeng.7b00817	journal	May 2017
Synthesis of thermally stable mesoporous cerium oxide with nanocrystalline frameworks using mesoporous silica templates Laha, S. C.; Ryoo, R. Chem. Commun., Issue 17 https://doi.org/10.1039/B305524H	journal	January 2003
Synthesis of mesoporous silica by sol–gel mineralisation of cellulose nanorod nematic suspensions Dujardin, Erik; Blaseby, Matthew; Mann, Stephen Journal of Materials Chemistry, Vol. 13, Issue 4 https://doi.org/10.1039/b212689c	journal	February 2003
N-doped mesoporous TiO 2 nanoparticles synthesized by using biological renewable nanocrystalline cellulose as template for the degradation of pollutants under visible and sun light Chen, Xiaoyun; Kuo, Dong-Hau; Lu, Dongfang Chemical Engineering Journal, Vol. 295 https://doi.org/10.1016/j.cej.2016.03.047	journal	July 2016
Chiral Nematic Mesoporous Carbon Derived From Nanocrystalline Cellulose Shopsowitz, Kevin E.; Hamad, Wadood Y.; MacLachlan, Mark J. Angewandte Chemie International Edition, Vol. 50, Issue 46 https://doi.org/10.1002/anie.201105479	journal	September 2011
Multifunctional Cellulolytic Enzymes Outperform Processive Fungal Cellulases for Coproduction of Nanocellulose and Biofuels Yarbrough, John. M.; Zhang, Ruoran; Mittal, Ashutosh ACS Nano, Vol. 11, Issue 3 https://doi.org/10.1021/acsnano.7b00086	journal	February 2017
Advancing catalytic fast pyrolysis through integrated multiscale modeling and experimentation: Challenges, progress, and perspectives Ciesielski, Peter N.; Pecha, M. Brennan; Bharadwaj, Vivek S. Wiley Interdisciplinary Reviews: Energy and Environment, Vol. 7, Issue 4 https://doi.org/10.1002/wene.297	journal	April 2018
Real-time monitoring of the deactivation of HZSM-5 during upgrading of pine pyrolysis vapors Mukarakate, Calvin; Zhang, Xiaodong; Stanton, Alexander R. Green Chem., Vol. 16, Issue 3 https://doi.org/10.1039/C3GC42065E	journal	January 2014
Molybdenum incorporated mesoporous silica catalyst for production of biofuels and value-added chemicals via catalytic fast pyrolysis Budhi, Sridhar; Mukarakate, Calvin; Iisa, Kristiina Green Chemistry, Vol. 17, Issue 5 https://doi.org/10.1039/C4GC02477J	journal	January 2015
Life-cycle analysis of integrated biorefineries with co-production of biofuels and bio-based chemicals: co-product handling methods and implications: Co-product handling methods and implications of life-cycle analysis of biofuel and bio-chemical co-producing biorefineries Cai, Hao; Han, Jeongwoo; Wang, Michael Biofuels, Bioproducts and Biorefining, Vol. 12, Issue 5 https://doi.org/10.1002/bbb.1893	journal	June 2018
Engineering of silica-supported platinum catalysts with hierarchical porosity combining latex synthesis, sonochemistry and sol-gel process – II. Catalytic performance Sierra-Salazar, Andrés Felipe; Hulea, Vasile; Ayral, André Microporous and Mesoporous Materials, Vol. 256 https://doi.org/10.1016/j.micromeso.2017.08.016	journal	January 2018
From Hydrocolloids to High Specific Surface Area Porous Supports for Catalysis Valentin, Romain; Molvinger, Karine; Viton, Christophe Biomacromolecules, Vol. 6, Issue 5 https://doi.org/10.1021/bm050264j	journal	September 2005
Catalytic conversion of biomass pyrolysis vapors into hydrocarbon fuel precursors Mante, Ofei D.; Rodriguez, Jose A.; Senanayake, Sanjaya D. Green Chemistry, Vol. 17, Issue 4 https://doi.org/10.1039/C4GC02238F	journal	January 2015
A nanocellulose template strategy for the controllable synthesis of tungsten-containing mesoporous silica for ultra-deep oxidative desulfurization Shen, Dazhi; Dai, Yanfei; Han, Jiang Chemical Engineering Journal, Vol. 332 https://doi.org/10.1016/j.cej.2017.09.087	journal	January 2018
Role of Biopolymers in the Deactivation of ZSM-5 during Catalytic Fast Pyrolysis of Biomass Stanton, Alexander R.; Iisa, Kristiina; Mukarakate, Calvin ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 8 https://doi.org/10.1021/acssuschemeng.8b01333	journal	June 2018
Preparation methods of alginate nanoparticles Paques, Jerome P.; van der Linden, Erik; van Rijn, Cees J. M. Advances in Colloid and Interface Science, Vol. 209 https://doi.org/10.1016/j.cis.2014.03.009	journal	July 2014
Template synthesis of porous titania using cellulose nanocrystals Shin, Yongsoon; Exarhos, Gregory J. Materials Letters, Vol. 61, Issue 11-12 https://doi.org/10.1016/j.matlet.2006.10.005	journal	May 2007
Ceria Catalysts at Nanoscale: How Do Crystal Shapes Shape Catalysis? Trovarelli, Alessandro; Llorca, Jordi ACS Catalysis, Vol. 7, Issue 7 https://doi.org/10.1021/acscatal.7b01246	journal	June 2017
Sol–gel synthesis highly porous titanium dioxide microspheres with cellulose nanofibrils-based aerogel templates Cai, Hongli; Mu, Wei; Liu, Wei Inorganic Chemistry Communications, Vol. 51 https://doi.org/10.1016/j.inoche.2014.11.013	journal	January 2015
Ketonization of Carboxylic Acids: Mechanisms, Catalysts, and Implications for Biomass Conversion Pham, Tu N.; Sooknoi, Tawan; Crossley, Steven P. ACS Catalysis, Vol. 3, Issue 11 https://doi.org/10.1021/cs400501h	journal	October 2013
Review of Hydrogels and Aerogels Containing Nanocellulose De France, Kevin J.; Hoare, Todd; Cranston, Emily D. Chemistry of Materials, Vol. 29, Issue 11 https://doi.org/10.1021/acs.chemmater.7b00531	journal	April 2017
Cellulose Nanofibril Hydrogel Tubes as Sacrificial Templates for Freestanding Tubular Cell Constructs Torres-Rendon, Jose Guillermo; Köpf, Marius; Gehlen, David Biomacromolecules, Vol. 17, Issue 3 https://doi.org/10.1021/acs.biomac.5b01593	journal	February 2016
Production of nanocrystalline cellulose from lignocellulosic biomass: Technology and applications Brinchi, L.; Cotana, F.; Fortunati, E. Carbohydrate Polymers, Vol. 94, Issue 1 https://doi.org/10.1016/j.carbpol.2013.01.033	journal	April 2013
Ceria-Based Solid Catalysts for Organic Chemistry Vivier, Laurence; Duprez, Daniel ChemSusChem, Vol. 3, Issue 6 https://doi.org/10.1002/cssc.201000054	journal	May 2010
Free-standing mesoporous silica films with tunable chiral nematic structures Shopsowitz, Kevin E.; Qi, Hao; Hamad, Wadood Y. Nature, Vol. 468, Issue 7322, p. 422-425 https://doi.org/10.1038/nature09540	journal	November 2010
Cellulose Nanocrystals: Chemistry, Self-Assembly, and Applications Habibi, Youssef; Lucia, Lucian A.; Rojas, Orlando J. Chemical Reviews, Vol. 110, Issue 6 https://doi.org/10.1021/cr900339w	journal	June 2010
Heat and Mass Transfer Effects in a Furnace-Based Micropyrolyzer Proano-Aviles, Juan; Lindstrom, Jake K.; Johnston, Patrick A. Energy Technology, Vol. 5, Issue 1 https://doi.org/10.1002/ente.201600279	journal	August 2016
Chiral Nematic Mesoporous Carbon Derived From Nanocrystalline Cellulose Shopsowitz, Kevin E.; Hamad, Wadood Y.; MacLachlan, Mark J. Angewandte Chemie, Vol. 123, Issue 46 https://doi.org/10.1002/ange.201105479	journal	September 2011

Cited By (46)

Chiral Nematic Mesoporous Carbon Derived From Nanocrystalline Cellulose Shopsowitz, Kevin E.; Hamad, Wadood Y.; MacLachlan, Mark J. Angewandte Chemie International Edition, Vol. 50, Issue 46 https://doi.org/10.1002/anie.201105479	journal	September 2011
Biological Chitin-MOF Composites with Hierarchical Pore Systems for Air-Filtration Applications Wisser, Dorothea; Wisser, Florian M.; Raschke, Silvia Angewandte Chemie International Edition, Vol. 54, Issue 43 https://doi.org/10.1002/anie.201504572	journal	August 2015
Life-cycle analysis of integrated biorefineries with co-production of biofuels and bio-based chemicals: co-product handling methods and implications: Co-product handling methods and implications of life-cycle analysis of biofuel and bio-chemical co-producing biorefineries Cai, Hao; Han, Jeongwoo; Wang, Michael Biofuels, Bioproducts and Biorefining, Vol. 12, Issue 5 https://doi.org/10.1002/bbb.1893	journal	June 2018
Ceria-Based Solid Catalysts for Organic Chemistry Vivier, Laurence; Duprez, Daniel ChemSusChem, Vol. 3, Issue 6 https://doi.org/10.1002/cssc.201000054	journal	May 2010
A Perspective on Catalytic Strategies for Deoxygenation in Biomass Pyrolysis Nolte, Michael W.; Shanks, Brent H. Energy Technology, Vol. 5, Issue 1 https://doi.org/10.1002/ente.201600096	journal	August 2016
Heat and Mass Transfer Effects in a Furnace-Based Micropyrolyzer Proano-Aviles, Juan; Lindstrom, Jake K.; Johnston, Patrick A. Energy Technology, Vol. 5, Issue 1 https://doi.org/10.1002/ente.201600279	journal	August 2016
Advancing catalytic fast pyrolysis through integrated multiscale modeling and experimentation: Challenges, progress, and perspectives Ciesielski, Peter N.; Pecha, M. Brennan; Bharadwaj, Vivek S. Wiley Interdisciplinary Reviews: Energy and Environment, Vol. 7, Issue 4 https://doi.org/10.1002/wene.297	journal	April 2018
American Process: Production of Low Cost Nanocellulose for Renewable, Advanced Materials Applications Nelson, Kim; Retsina, Theodora; Iakovlev, Mikhail Materials Research for Manufacturing https://doi.org/10.1007/978-3-319-23419-9_9	book	January 2016
Condensation reactions of propanal over CexZr1−xO2 mixed oxide catalysts Gangadharan, Anirudhan; Shen, Min; Sooknoi, Tawan Applied Catalysis A: General, Vol. 385, Issue 1-2 https://doi.org/10.1016/j.apcata.2010.06.048	journal	September 2010
Stabilization of furanics to cyclic ketone building blocks in the vapor phase Omotoso, Taiwo; Herrera, Leidy V.; Vann, Tyler Applied Catalysis B: Environmental, Vol. 254 https://doi.org/10.1016/j.apcatb.2019.04.079	journal	October 2019
Production of nanocrystalline cellulose from lignocellulosic biomass: Technology and applications Brinchi, L.; Cotana, F.; Fortunati, E. Carbohydrate Polymers, Vol. 94, Issue 1 https://doi.org/10.1016/j.carbpol.2013.01.033	journal	April 2013
Multi-scale simulation of reaction, transport and deactivation in a SBA-16 supported catalyst for the conversion of ethanol to butadiene Bharadwaj, Vivek S.; Pecha, M. Brennan; Bu, Lintao Catalysis Today, Vol. 338 https://doi.org/10.1016/j.cattod.2019.05.042	journal	November 2019
N-doped mesoporous TiO 2 nanoparticles synthesized by using biological renewable nanocrystalline cellulose as template for the degradation of pollutants under visible and sun light Chen, Xiaoyun; Kuo, Dong-Hau; Lu, Dongfang Chemical Engineering Journal, Vol. 295 https://doi.org/10.1016/j.cej.2016.03.047	journal	July 2016
A nanocellulose template strategy for the controllable synthesis of tungsten-containing mesoporous silica for ultra-deep oxidative desulfurization Shen, Dazhi; Dai, Yanfei; Han, Jiang Chemical Engineering Journal, Vol. 332 https://doi.org/10.1016/j.cej.2017.09.087	journal	January 2018
Hierarchical porous ceramics with 3D reticular architecture and efficient flow-through filtration towards high-temperature particulate matter capture Liu, Jingjing; Ren, Bo; Wang, Yali Chemical Engineering Journal, Vol. 362 https://doi.org/10.1016/j.cej.2019.01.065	journal	April 2019
Preparation methods of alginate nanoparticles Paques, Jerome P.; van der Linden, Erik; van Rijn, Cees J. M. Advances in Colloid and Interface Science, Vol. 209 https://doi.org/10.1016/j.cis.2014.03.009	journal	July 2014
Sol–gel synthesis highly porous titanium dioxide microspheres with cellulose nanofibrils-based aerogel templates Cai, Hongli; Mu, Wei; Liu, Wei Inorganic Chemistry Communications, Vol. 51 https://doi.org/10.1016/j.inoche.2014.11.013	journal	January 2015
Ultrahigh intercalation pseudocapacitance of mesoporous orthorhombic niobium pentoxide from a novel cellulose nanocrystal template Kong, Lingping; Zhang, Chuangfang; Wang, Jitong Materials Chemistry and Physics, Vol. 149-150 https://doi.org/10.1016/j.matchemphys.2014.10.051	journal	January 2015
Template synthesis of porous titania using cellulose nanocrystals Shin, Yongsoon; Exarhos, Gregory J. Materials Letters, Vol. 61, Issue 11-12 https://doi.org/10.1016/j.matlet.2006.10.005	journal	May 2007
Engineering of silica-supported platinum catalysts with hierarchical porosity combining latex synthesis, sonochemistry and sol-gel process – II. Catalytic performance Sierra-Salazar, Andrés Felipe; Hulea, Vasile; Ayral, André Microporous and Mesoporous Materials, Vol. 256 https://doi.org/10.1016/j.micromeso.2017.08.016	journal	January 2018
Hierarchical zeolites: Synthesis and catalytic properties Feliczak-Guzik, Agnieszka Microporous and Mesoporous Materials, Vol. 259 https://doi.org/10.1016/j.micromeso.2017.09.030	journal	March 2018
Low temperature carbonization of cellulose nanocrystals for high performance carbon anode of sodium-ion batteries Zhu, Hongli; Shen, Fei; Luo, Wei Nano Energy, Vol. 33 https://doi.org/10.1016/j.nanoen.2017.01.021	journal	March 2017
Modeling HCCI combustion of biofuels: A review Komninos, N. P.; Rakopoulos, C. D. Renewable and Sustainable Energy Reviews, Vol. 16, Issue 3 https://doi.org/10.1016/j.rser.2011.11.026	journal	April 2012
Cellulose Nanofibril Hydrogel Tubes as Sacrificial Templates for Freestanding Tubular Cell Constructs Torres-Rendon, Jose Guillermo; Köpf, Marius; Gehlen, David Biomacromolecules, Vol. 17, Issue 3 https://doi.org/10.1021/acs.biomac.5b01593	journal	February 2016
Review of Hydrogels and Aerogels Containing Nanocellulose De France, Kevin J.; Hoare, Todd; Cranston, Emily D. Chemistry of Materials, Vol. 29, Issue 11 https://doi.org/10.1021/acs.chemmater.7b00531	journal	April 2017
Correction To Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications Zhu, Hongli; Luo, Wei; Ciesielski, Peter N. Chemical Reviews, Vol. 116, Issue 19 https://doi.org/10.1021/acs.chemrev.6b00576	journal	September 2016
Ceria Catalysts at Nanoscale: How Do Crystal Shapes Shape Catalysis? Trovarelli, Alessandro; Llorca, Jordi ACS Catalysis, Vol. 7, Issue 7 https://doi.org/10.1021/acscatal.7b01246	journal	June 2017
Multifunctional Cellulolytic Enzymes Outperform Processive Fungal Cellulases for Coproduction of Nanocellulose and Biofuels Yarbrough, John. M.; Zhang, Ruoran; Mittal, Ashutosh ACS Nano, Vol. 11, Issue 3 https://doi.org/10.1021/acsnano.7b00086	journal	February 2017
Deactivation of Multilayered MFI Nanosheet Zeolite during Upgrading of Biomass Pyrolysis Vapors Xu, Mengze; Mukarakate, Calvin; Iisa, Kristiina ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 6 https://doi.org/10.1021/acssuschemeng.7b00817	journal	May 2017
Role of Biopolymers in the Deactivation of ZSM-5 during Catalytic Fast Pyrolysis of Biomass Stanton, Alexander R.; Iisa, Kristiina; Mukarakate, Calvin ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 8 https://doi.org/10.1021/acssuschemeng.8b01333	journal	June 2018
Photocatalytic Antifouling Graphene Oxide-Mediated Hierarchical Filtration Membranes with Potential Applications on Water Purification Xu, Chao; Xu, Yuelian; Zhu, Jiaoli ACS Applied Materials & Interfaces, Vol. 6, Issue 18 https://doi.org/10.1021/am5040945	journal	September 2014
From Hydrocolloids to High Specific Surface Area Porous Supports for Catalysis Valentin, Romain; Molvinger, Karine; Viton, Christophe Biomacromolecules, Vol. 6, Issue 5 https://doi.org/10.1021/bm050264j	journal	September 2005
Properties and Reactivity of Nanostructured CeO ₂ Powders: Comparison among Two Synthesis Procedures Natile, Marta M.; Boccaletti, Giovanni; Glisenti, Antonella Chemistry of Materials, Vol. 17, Issue 25 https://doi.org/10.1021/cm051352d	journal	December 2005
Cellulose Nanocrystals: Chemistry, Self-Assembly, and Applications Habibi, Youssef; Lucia, Lucian A.; Rojas, Orlando J. Chemical Reviews, Vol. 110, Issue 6 https://doi.org/10.1021/cr900339w	journal	June 2010
Ketonization of Carboxylic Acids: Mechanisms, Catalysts, and Implications for Biomass Conversion Pham, Tu N.; Sooknoi, Tawan; Crossley, Steven P. ACS Catalysis, Vol. 3, Issue 11 https://doi.org/10.1021/cs400501h	journal	October 2013
A Sustainable Template for Mesoporous Zeolite Synthesis White, Robin J.; Fischer, Anna; Goebel, Caren Journal of the American Chemical Society, Vol. 136, Issue 7 https://doi.org/10.1021/ja411586h	journal	February 2014
Ordered Mesoporous CeO ₂ Synthesized by Nanocasting from Cubic Ia3d Mesoporous MCM-48 Silica: Formation, Characterization and Photocatalytic Activity Ji, Pengfei; Zhang, Jinlong; Chen, Feng The Journal of Physical Chemistry C, Vol. 112, Issue 46 https://doi.org/10.1021/jp8054087	journal	October 2008
Inorganic Hollow Nanotube Aerogels by Atomic Layer Deposition onto Native Nanocellulose Templates Korhonen, Juuso T.; Hiekkataipale, Panu; Malm, Jari ACS Nano, Vol. 5, Issue 3 https://doi.org/10.1021/nn200108s	journal	February 2011
Free-standing mesoporous silica films with tunable chiral nematic structures Shopsowitz, Kevin E.; Qi, Hao; Hamad, Wadood Y. Nature, Vol. 468, Issue 7322, p. 422-425 https://doi.org/10.1038/nature09540	journal	November 2010
Chemistry challenges to enable a sustainable bioeconomy Fitzgerald, Nichole D. Nature Reviews Chemistry, Vol. 1, Issue 10 https://doi.org/10.1038/s41570-017-0080	journal	September 2017
Synthesis of mesoporous silica by sol–gel mineralisation of cellulose nanorod nematic suspensions Dujardin, Erik; Blaseby, Matthew; Mann, Stephen Journal of Materials Chemistry, Vol. 13, Issue 4 https://doi.org/10.1039/b212689c	journal	February 2003
Surfactant-assisted synthesis of CeO2 nanoparticles and their application in wastewater treatment Li, He; Wang, Guofeng; Zhang, Fei RSC Advances, Vol. 2, Issue 32 https://doi.org/10.1039/c2ra21590j	journal	January 2012
A critical review of the current knowledge regarding the biological impact of nanocellulose Endes, C.; Camarero-Espinosa, S.; Mueller, S. Journal of Nanobiotechnology, Vol. 14, Issue 1 https://doi.org/10.1186/s12951-016-0230-9	journal	December 2016
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Provisional) Sing, K. S. W. Pure and Applied Chemistry, Vol. 54, Issue 11 https://doi.org/10.1351/pac198254112201	journal	January 1982
Catalytic Upgrading of Biomass Fast Pyrolysis Vapors with Nano Metal Oxides: An Analytical Py-GC/MS Study Lu, Qiang; Zhang, Zhi-Fei; Dong, Chang-Qing Energies, Vol. 3, Issue 11 https://doi.org/10.3390/en3111805	journal	November 2010
Synthesis and Characterization of Cerium Oxide Nanoparticles by Hydroxide Mediated Approach Chelliah, Muruganantham; Rayappan, John Bosco Balaguru; Krishnan, Uma Maheshwari Journal of Applied Sciences, Vol. 12, Issue 16 https://doi.org/10.3923/jas.2012.1734.1737	journal	December 2012

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