Solubilities of six lithium salts in five non-aqueous solvents and in a few of their binary mixtures

Xin, Nan; Sun, Yanjun; He, Maogang; Radke, Clayton J.; Prausnitz, John M.

doi:10.1016/j.fluid.2017.12.034

Solubilities of six lithium salts in five non-aqueous solvents and in a few of their binary mixtures

Journal Article · Thu Dec 28 00:00:00 EST 2017 · Fluid Phase Equilibria

DOI:https://doi.org/10.1016/j.fluid.2017.12.034· OSTI ID:1571100

Xin, Nan ^[1]; Sun, Yanjun ^[1]; He, Maogang ^[2]; Radke, Clayton J. ^[3]; Prausnitz, John M. ^[3]

Univ. of California, Berkeley, CA (United States). Dept. of Chemical and Biomolecular Engineering; Xi'an Jiaotong Univ., Xi'an, Shannxi (China). MOE Key Lab. of Thermo-Fluid Science and Engineering
Xi'an Jiaotong Univ., Xi'an, Shannxi (China). MOE Key Lab. of Thermo-Fluid Science and Engineering
Univ. of California, Berkeley, CA (United States). Dept. of Chemical and Biomolecular Engineering

Solubilities were measured from 25 to 45 °C for six lithium salts (LiF, LiCl, LiBr, LiNO₃, LiTFSI and LiPF₆) in five pure non–aqueous solvents (ethanol, acetonitrile, dimethyl carbonate, dimethyl sulfoxide and propylene carbonate) and in a few of their binary mixtures (ethanol + DMSO, DMC + DMSO and DMC + PC). The experimental method uses a Varian inductively–coupled plasma–optical–emission spectrometer (ICP–OES). Solubilities increase with rising temperature. At a given temperature, LiNO₃ shows the highest solubility in all solvents. Salt solubilities follow the order LiNO₃ > LiTFSI > LiBr > LiCl > LiPF₆ > LiF. The dissolving abilities of the solvents are in the order ethanol > DMSO > acetonitrile > PC > DMC. Finally, coupled with the salt's melting temperature and enthalpy of fusion, liquid–phase activity coefficients for salts were obtained from the solubility data.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1571100

Journal Information:: Fluid Phase Equilibria, Journal Name: Fluid Phase Equilibria Journal Issue: C Vol. 461; ISSN 0378-3812

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Solubilities of six lithium salts in five non-aqueous solvents and in a few of their binary mixtures

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