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Title: Structural diversity in multinuclear tantalum polyhydrides formed via reductive hydrogenolysis of metal–carbon bonds

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/C9CC07686G· OSTI ID:1570788
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry, University of California, Berkeley, USA
+ Show Author Affiliations

Put the methyl to the metal: hydrogenolysis of metal–carbon bonds offers controlled access to low-valent early metal complexes.

Sponsoring Organization:
USDOE
OSTI ID:
1570788
Journal Information:
ChemComm, Journal Name: ChemComm Vol. 55 Journal Issue: 88; ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English
Citation Metrics:
Cited by: 10 works
Citation information provided by
Web of Science

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Synthesis and Bonding in the Diamagnetic Dinuclear Tantalum(IV) Hydride Species ([P 2 N 2 ]Ta) 2 (μ-H) 4 and the Paramagnetic Cationic Dinuclear Hydride Species {([P 2 N 2 ]Ta) 2 (μ-H) 4 } + I - ([P 2 N 2 ] = PhP(CH 2 SiMe 2 NSiMe 2 CH 2 ) 2 PPh):  The Reducing Ability of a Metal−Metal Bond journal September 2000
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