U2Ni2Sn and the origin of magnetic anisotropy in uranium compounds

Mašková, S.; Andreev, A. V.; Skourski, Y.; Yasin, S.; Gorbunov, D. I.; Zherlitsyn, S.; Nakotte, H.; Kothapalli, K.; Nasreen, F.; Cupp, C.; Cao, H. B.; Kolomiets, A.; Havela, L.

doi:10.1103/PhysRevB.99.064415

Title: U₂Ni₂Sn and the origin of magnetic anisotropy in uranium compounds

Journal Article · Fri Feb 15 00:00:00 EST 2019 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.99.064415· OSTI ID:1569369

Mašková, S. ^[1]; Andreev, A. V. ^[2]; Skourski, Y. ^[3]; Yasin, S. ^[4]; Gorbunov, D. I. ^[3]; Zherlitsyn, S. ^[3]; Nakotte, H. ^[5]; Kothapalli, K. ^[6]; Nasreen, F. ^[7]; Cupp, C. ^[8]; Cao, H. B. ^[9]; Kolomiets, A. ^[10]; Havela, L. ^[1]

Charles Univ., Prague (Czech Republic). Dept. of Condensed Matter Physics
Academy of Sciences, Prague (Czech Republic). Inst. of Physics
Helmholtz-Zentrum Dresden-Rossendorf, Dresden (Germany). Hochfeld-Magnetlabor Dresden (HLD-EMFL)
Helmholtz-Zentrum Dresden-Rossendorf, Dresden (Germany). Hochfeld-Magnetlabor Dresden (HLD-EMFL); American Univ. of the Middle East (Kuwait). College of Engineering and Technology
New Mexico State Univ., Las Cruces, NM (United States). Dept. of Physics
New Mexico State Univ., Las Cruces, NM (United States). Dept. of Physics; King Univ., Bristol, TN (United States). College of Arts and Sciences
Univ. of Nevada, Las Vegas, NV (United States). High Pressure Science and Engineering Center (HiPSEC) and Dept. of Physics and Astronomy
King Univ., Bristol, TN (United States). College of Arts and Sciences
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Division
Charles Univ., Prague (Czech Republic). Dept. of Condensed Matter Physics; Lviv Poytechnic National Univ., Lviv (Ukraine). Dept. of Physics

Here, U₂Ni₂Sn is a member of a large family of intermetallic compounds with the tetragonal Mo₂FeB₂ crystal structure. It orders antiferromagnetically at 25 K with propagation vector $$q = (0, 0, \frac{1}{2})$$. Magnetization, magnetoacoustic, and neutron-diffraction experiments on a single crystal provide evidence that the uranium moments align parallel to the $$c$$ axis with the anisotropy energy of ≈170 K, indicating that U₂Ni₂Sn can be classified as an Ising system. The results are at variance with previous studies on polycrystals, which indicated different magnetic structure, and which were incompatible with the $5f - 5f$ two-ion anisotropy model dominant in most U band systems. High-field magnetization studies exhibit a weak linear response for fields along the basal plane up to the highest field applied (60 T), while the $$c$$-axis magnetization curve exhibits three metamagnetic transitions at approximately 30, 39, and 50 T. The U magnetic moments of $$0.87 μ_B$$, the low magnetic entropy, and the enhanced Sommerfeld coefficient $$γ$$ = 187 mJ/mol f.u.K² suggest that U₂Ni₂Sn can be classified as an itinerant antiferromagnet with strong electron-electron correlations.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1569369

Journal Information:: Physical Review B, Vol. 99, Issue 6; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 14 works

Citation information provided by
Web of Science

References (31)

Transport and magnetic properties of U2Ni2Sn and U2Co2Sn Pinto, R. P.; Amado, M. M.; Salgueiro, M. A. Journal of Magnetism and Magnetic Materials, Vol. 140-144 https://doi.org/10.1016/0304-8853(94)01322-5	journal	February 1995
Lattice anisotropy in uranium ternary compounds: UTX Mašková, S.; Adamska, A. M.; Havela, L. Journal of Alloys and Compounds, Vol. 522 https://doi.org/10.1016/j.jallcom.2012.01.122	journal	May 2012
Fractional Magnetization Plateaus and Magnetic Order in the Shastry-Sutherland Magnet ${TmB}_{4}$ Siemensmeyer, K.; Wulf, E.; Mikeska, H. -J. Physical Review Letters, Vol. 101, Issue 17 https://doi.org/10.1103/PhysRevLett.101.177201	journal	October 2008
Investigation by 119Sn mössbauer spectroscopy, magnetic and electrical resistivity measurements of U2M2Sn stannides (M  Fe, Co, Ni, Ru, Rh, Pd) Mirambet, F.; Chevalier, B.; Fournès, L. Journal of Alloys and Compounds, Vol. 203 https://doi.org/10.1016/0925-8388(94)90710-2	journal	January 1994
Magnetic ordering in $U_{2}$ ${Pd}_{2}$ In and $U_{2}$ ${Pd}_{2}$ Sn Purwanto, A.; Robinson, R. A.; Havela, L. Physical Review B, Vol. 50, Issue 10 https://doi.org/10.1103/PhysRevB.50.6792	journal	September 1994
Resonant band‐ f scattering and the magnetic properties of highly correlated actinide systems Hu, G. ‐J.; Kioussis, N.; Cooper, B. R. Journal of Applied Physics, Vol. 61, Issue 8 https://doi.org/10.1063/1.338780	journal	April 1987
Dzyaloshinskii-Moriya interaction and magnetic anisotropies in Uranium compounds Sandratskii, L. M. Physica B: Condensed Matter, Vol. 536 https://doi.org/10.1016/j.physb.2017.11.014	journal	May 2018
High-field magnetization studies of some U2T2X compounds Fukushima, T.; Matsuyama, S.; Kumada, T. Physica B: Condensed Matter, Vol. 211, Issue 1-4 https://doi.org/10.1016/0921-4526(94)00967-Z	journal	May 1995
Electronic properties of U2Ni2Sn Kindo, K.; Fukushima, T.; Kumada, T. Journal of Magnetism and Magnetic Materials, Vol. 140-144 https://doi.org/10.1016/0304-8853(94)00606-7	journal	February 1995
Four-circle single-crystal neutron diffractometer at the High Flux Isotope Reactor Chakoumakos, Bryan C.; Cao, Huibo; Ye, Feng Journal of Applied Crystallography, Vol. 44, Issue 3 https://doi.org/10.1107/S0021889811012301	journal	May 2011
Anisotropic physical properties of single-crystal $U_{2} {Rh}_{2} Sn$ in high magnetic fields Prokeš, K.; Gorbunov, D. I.; Reehuis, M. Physical Review B, Vol. 95, Issue 17 https://doi.org/10.1103/PhysRevB.95.174433	journal	May 2017
Magnetism in U2T2X compounds Havela, L.; Sechovský, V.; Svoboda, P. Journal of Magnetism and Magnetic Materials, Vol. 140-144 https://doi.org/10.1016/0304-8853(94)00934-1	journal	February 1995
Low Temperature Magnetization of Yb ₂ Pt ₂ Pb with the Shastry–Sutherland Type Lattice and a High-Rank Multipole Interaction Shimura, Yasuyuki; Sakakibara, Toshiro; Iwakawa, Ken Journal of the Physical Society of Japan, Vol. 81, Issue 10 https://doi.org/10.1143/JPSJ.81.103601	journal	October 2012
New experimental techniques for pulsed magnetic fields – ESR and ultrasonics Wolf, B.; Lüthi, B.; Schmidt, S. Physica B: Condensed Matter, Vol. 294-295 https://doi.org/10.1016/S0921-4526(00)00729-8	journal	January 2001
Onset of magnetic order in U2(Ni1−x Fe x )2Sn-H Mašková, S.; Havela, L.; Kolomiets, A. Journal of the Korean Physical Society, Vol. 62, Issue 10 https://doi.org/10.3938/jkps.62.1542	journal	May 2013
First principles study of the electronic and magnetic structures of U ₂ Ni ₂ SnH ₂ Matar, S. F.; Al Alam, A. F. New Journal of Physics, Vol. 10, Issue 8 https://doi.org/10.1088/1367-2630/10/8/083013	journal	August 2008
Large Orbital-Moment Contribution to $5 f$ Band Magnetism Brooks, M. S. S.; Kelly, P. J. Physical Review Letters, Vol. 51, Issue 18 https://doi.org/10.1103/PhysRevLett.51.1708	journal	October 1983
Ferromagnetism and Superconductivity in Uranium Compounds Aoki, Dai; Flouquet, Jacques Journal of the Physical Society of Japan, Vol. 81, Issue 1 https://doi.org/10.1143/JPSJ.81.011003	journal	January 2012
High-field magnetization of Ho $_{2}$ Fe $_{17}$ Skourski, Y.; Kuz’min, M. D.; Skokov, K. P. Physical Review B, Vol. 83, Issue 21 https://doi.org/10.1103/PhysRevB.83.214420	journal	June 2011
The theory of equilibrium critical phenomena Fisher, M. E. Reports on Progress in Physics, Vol. 30, Issue 2 https://doi.org/10.1088/0034-4885/30/2/306	journal	July 1967
Magnetic structures of the ternary stannide U2(Ni0.70Pd0.30)2Sn Laffargue, D.; Bourée, F.; Chevalier, B. Journal of Alloys and Compounds, Vol. 271-273 https://doi.org/10.1016/S0925-8388(98)00107-8	journal	June 1998
Magnetic Properties of Tb<sub>2</sub>Pd<sub>2</sub>In; Single Crystal Study Maskova, Silvie; Kolomiets, Aleksandre V.; Havela, Ladislav Solid State Phenomena, Vol. 194 https://doi.org/10.4028/www.scientific.net/SSP.194.58	journal	November 2012
Crystal and magnetic structures of U2Ni2Sn investigated by neutron diffraction and 119Sn Mössbauer spectroscopy Bourée, F.; Chevalier, B.; Fournès, L. Journal of Magnetism and Magnetic Materials, Vol. 138, Issue 3 https://doi.org/10.1016/0304-8853(94)90052-3	journal	December 1994
Peculiarities of hydrides Miliyanchuk, K.; Havela, L.; Pereira, L. C. J. Journal of Magnetism and Magnetic Materials, Vol. 310, Issue 2 https://doi.org/10.1016/j.jmmm.2006.10.157	journal	March 2007
A single-crystal magnetization and neutron scattering investigation of the magnetic structure of Pereira, L. C. J.; Paixão, J. A.; Estrela, P. Journal of Physics: Condensed Matter, Vol. 8, Issue 50 https://doi.org/10.1088/0953-8984/8/50/039	journal	December 1996
Magnetic anisotropy in UTX compounds Havela, L.; Sechovsky, V.; de Boer, F. R. Physica B: Condensed Matter, Vol. 177, Issue 1-4 https://doi.org/10.1016/0921-4526(92)90087-9	journal	March 1992
Ising model with solitons, phasons, and "the devil's staircase" Bak, Per; von Boehm, J. Physical Review B, Vol. 21, Issue 11 https://doi.org/10.1103/PhysRevB.21.5297	journal	June 1980
Lattice and Magnetic Anisotropies in Uranium Intermetallic Compounds Havela, Ladislav; Maskova, Silvie; Adamska, Anna Solid State Phenomena, Vol. 194 https://doi.org/10.4028/www.scientific.net/SSP.194.75	journal	November 2012
Hybridization effects in $U_{2}$ $T_{2}$ X compounds: Magnetic structures of $U_{2}$ ${Rh}_{2}$ Sn and $U_{2}$ ${Ni}_{2}$ In Nakotte, H.; Purwanto, A.; Robinson, R. A. Physical Review B, Vol. 53, Issue 6 https://doi.org/10.1103/PhysRevB.53.3263	journal	February 1996
5f electron localization in metallic UPd3 Baer, Y.; Ott, H. R.; Andres, K. Solid State Communications, Vol. 36, Issue 5 https://doi.org/10.1016/0038-1098(80)90917-5	journal	November 1980
The theory of equilibrium critical phenomena Fisher, M. E. Reports on Progress in Physics, Vol. 31, Issue 1 https://doi.org/10.1088/0034-4885/31/1/508	journal	January 1968

Similar Records

Neutron scattering study of magnetic structure and metamagnetic transition between low- and high-moment states of NpNiGa{sub 5}

Journal Article · Sun Oct 01 00:00:00 EDT 2006 · Physical Review. B, Condensed Matter and Materials Physics · OSTI ID:1569369

Honda, Fuminori; Kaneko, Koji; Jonen, Shintaro; +7 more

Mo{sub 2}NiB{sub 2}-type (Gd, Tb, Dy){sub 2}Ni{sub 2.35}Si{sub 0.65} and La{sub 2}Ni{sub 3}-type (Dy, Ho){sub 2}Ni{sub 2.5}Si{sub 0.5} compounds: Crystal structure and magnetic properties

Journal Article · Fri May 15 00:00:00 EDT 2015 · Journal of Solid State Chemistry · OSTI ID:1569369

Isnard, O.; Nirmala, R.; Malik, S. K.

Suppression of antiferromagnetic order and strong ferromagnetic spin fluctuations in Ca(Co_1-xNi_x)_2-y As₂ single crystals

Journal Article · Wed Sep 15 00:00:00 EDT 2021 · Physical Review B · OSTI ID:1569369

Pakhira, Santanu; Lee, Y.; Ke, Liqin; +5 more

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY

Title: U2Ni2Sn and the origin of magnetic anisotropy in uranium compounds

Citation Formats

References (31)

Similar Records

Related Subjects

Title: U₂Ni₂Sn and the origin of magnetic anisotropy in uranium compounds