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Title: A critical review of cathodes for rechargeable Mg batteries

Abstract

Benefiting from a higher volumetric capacity (3833 mA h cm−3 for Mg vs. 2046 mA h cm−3 for Li) and dendrite-free Mg metal anode, reversible Mg batteries (RMBs) are a promising chemistry for applications beyond Li ion batteries. However, RMBs are still severely restricted by the absence of high performance cathodes for any practical application. In this review, we provide a critical and rigorous review of Mg battery cathode materials, mainly reported since 2013, focusing on the impact of structure and composition on magnesiation kinetics. We discuss cathode materials, including intercalation compounds, conversion materials (O2, S, organic compounds), water co-intercalation cathodes (V2O5, MnO2etc.), as well as hybrid systems using Mg metal anode. Among them, intercalation cathodes are further categorized by 3D (Chevrel phase, spinel structure etc.), 2D (layered structure), and 1D materials (polyanion: phosphate and silicate), according to the diffusion pathway of Mg2+ in the framework. Instead of discussing every published work in detail, this review selects the most representative works and highlights the merits and challenges of each class of cathodes. Advances in theoretical analysis are also reviewed and compared with experimental results. This critical review will provide comprehensive knowledge of Mg cathodes and guidelines for exploring new cathodesmore » for rechargeable magnesium batteries.« less

Authors:
 [1];  [2];  [2]; ORCiD logo [2]
  1. Department of Chemical and Biomolecular Engineering; University of Maryland; College Park; USA; College of Chemistry and Chemical Engineering
  2. Department of Chemical and Biomolecular Engineering; University of Maryland; College Park; USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES); Univ. of Maryland, College Park, MD (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1566634
DOE Contract Number:  
SC0001160
Resource Type:
Journal Article
Journal Name:
Chemical Society Reviews
Additional Journal Information:
Journal Volume: 47; Journal Issue: 23; Journal ID: ISSN 0306-0012
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
bio-inspired, energy storage (including batteries and capacitors), defects, charge transport, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Mao, Minglei, Gao, Tao, Hou, Singyuk, and Wang, Chunsheng. A critical review of cathodes for rechargeable Mg batteries. United States: N. p., 2018. Web. doi:10.1039/c8cs00319j.
Mao, Minglei, Gao, Tao, Hou, Singyuk, & Wang, Chunsheng. A critical review of cathodes for rechargeable Mg batteries. United States. doi:10.1039/c8cs00319j.
Mao, Minglei, Gao, Tao, Hou, Singyuk, and Wang, Chunsheng. Mon . "A critical review of cathodes for rechargeable Mg batteries". United States. doi:10.1039/c8cs00319j.
@article{osti_1566634,
title = {A critical review of cathodes for rechargeable Mg batteries},
author = {Mao, Minglei and Gao, Tao and Hou, Singyuk and Wang, Chunsheng},
abstractNote = {Benefiting from a higher volumetric capacity (3833 mA h cm−3 for Mg vs. 2046 mA h cm−3 for Li) and dendrite-free Mg metal anode, reversible Mg batteries (RMBs) are a promising chemistry for applications beyond Li ion batteries. However, RMBs are still severely restricted by the absence of high performance cathodes for any practical application. In this review, we provide a critical and rigorous review of Mg battery cathode materials, mainly reported since 2013, focusing on the impact of structure and composition on magnesiation kinetics. We discuss cathode materials, including intercalation compounds, conversion materials (O2, S, organic compounds), water co-intercalation cathodes (V2O5, MnO2etc.), as well as hybrid systems using Mg metal anode. Among them, intercalation cathodes are further categorized by 3D (Chevrel phase, spinel structure etc.), 2D (layered structure), and 1D materials (polyanion: phosphate and silicate), according to the diffusion pathway of Mg2+ in the framework. Instead of discussing every published work in detail, this review selects the most representative works and highlights the merits and challenges of each class of cathodes. Advances in theoretical analysis are also reviewed and compared with experimental results. This critical review will provide comprehensive knowledge of Mg cathodes and guidelines for exploring new cathodes for rechargeable magnesium batteries.},
doi = {10.1039/c8cs00319j},
journal = {Chemical Society Reviews},
issn = {0306-0012},
number = 23,
volume = 47,
place = {United States},
year = {2018},
month = {1}
}

Works referenced in this record:

Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

Mg rechargeable batteries: an on-going challenge
journal, January 2013

  • Yoo, Hyun Deog; Shterenberg, Ivgeni; Gofer, Yosef
  • Energy & Environmental Science, Vol. 6, Issue 8, p. 2265-2279
  • DOI: 10.1039/c3ee40871j

Lithium Batteries and Cathode Materials
journal, October 2004

  • Whittingham, M. Stanley
  • Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302
  • DOI: 10.1021/cr020731c

Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

Prototype systems for rechargeable magnesium batteries
journal, October 2000

  • Aurbach, D.; Lu, Z.; Schechter, A.
  • Nature, Vol. 407, Issue 6805, p. 724-727
  • DOI: 10.1038/35037553

Nonaqueous magnesium electrochemistry and its application in secondary batteries
journal, January 2003

  • Aurbach, Doron; Weissman, Idit; Gofer, Yosef
  • The Chemical Record, Vol. 3, Issue 1, p. 61-73
  • DOI: 10.1002/tcr.10051

Magnesium insertion electrodes for rechargeable nonaqueous batteries — a competitive alternative to lithium?
journal, September 1999


Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
journal, April 1997

  • Padhi, A. K.
  • Journal of The Electrochemical Society, Vol. 144, Issue 4, p. 1188-1194
  • DOI: 10.1149/1.1837571

Electrochemistry of polynuclear transition metal cyanides: Prussian blue and its analogues
journal, June 1986

  • Itaya, Kingo; Uchida, Isamu; Neff, Vernon D.
  • Accounts of Chemical Research, Vol. 19, Issue 6, p. 162-168
  • DOI: 10.1021/ar00126a001

Copper hexacyanoferrate battery electrodes with long cycle life and high power
journal, November 2011

  • Wessells, Colin D.; Huggins, Robert A.; Cui, Yi
  • Nature Communications, Vol. 2, Article No. 550
  • DOI: 10.1038/ncomms1563

Prussian blue: a new framework of electrode materials for sodium batteries
journal, January 2012

  • Lu, Yuhao; Wang, Long; Cheng, Jinguang
  • Chemical Communications, Vol. 48, Issue 52, p. 6544-6546
  • DOI: 10.1039/c2cc31777j

Nickel Hexacyanoferrate Nanoparticle Electrodes For Aqueous Sodium and Potassium Ion Batteries
journal, December 2011

  • Wessells, Colin D.; Peddada, Sandeep V.; Huggins, Robert A.
  • Nano Letters, Vol. 11, Issue 12, p. 5421-5425
  • DOI: 10.1021/nl203193q

Copper ion liquid-like thermoelectrics
journal, March 2012

  • Liu, Huili; Shi, Xun; Xu, Fangfang
  • Nature Materials, Vol. 11, Issue 5, p. 422-425
  • DOI: 10.1038/nmat3273

High-capacity organic positive-electrode material based on a benzoquinone derivative for use in rechargeable lithium batteries
journal, December 2010


Sulfone-Based Electrolyte Solutions for Rechargeable Magnesium Batteries Using 2,5-Dimethoxy-1,4-benzoquinone Positive Electrode
journal, January 2014

  • Senoh, H.; Sakaebe, H.; Sano, H.
  • Journal of the Electrochemical Society, Vol. 161, Issue 9, p. A1315-A1320
  • DOI: 10.1149/2.0531409jes

Aprotic and Aqueous Li–O2 Batteries
journal, April 2014

  • Lu, Jun; Li, Li; Park, Jin-Bum
  • Chemical Reviews, Vol. 114, Issue 11, p. 5611-5640
  • DOI: 10.1021/cr400573b

A rechargeable room-temperature sodium superoxide (NaO2) battery
journal, December 2012

  • Hartmann, Pascal; Bender, Conrad L.; Vračar, Miloš
  • Nature Materials, Vol. 12, Issue 3, p. 228-232
  • DOI: 10.1038/nmat3486

A Low-Overpotential Potassium–Oxygen Battery Based on Potassium Superoxide
journal, February 2013

  • Ren, Xiaodi; Wu, Yiying
  • Journal of the American Chemical Society, Vol. 135, Issue 8, p. 2923-2926
  • DOI: 10.1021/ja312059q

Li–O2 and Li–S batteries with high energy storage
journal, January 2012

  • Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
  • Nature Materials, Vol. 11, Issue 1, p. 19-29
  • DOI: 10.1038/nmat3191

Sulfur-Impregnated Activated Carbon Fiber Cloth as a Binder-Free Cathode for Rechargeable Li-S Batteries
journal, November 2011

  • Elazari, Ran; Salitra, Gregory; Garsuch, Arnd
  • Advanced Materials, Vol. 23, Issue 47, p. 5641-5644
  • DOI: 10.1002/adma.201103274

A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009

  • Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F.
  • Nature Materials, Vol. 8, Issue 6, p. 500-506
  • DOI: 10.1038/nmat2460

New insights into the limiting parameters of the Li/S rechargeable cell
journal, February 2012


Structure and compatibility of a magnesium electrolyte with a sulphur cathode
journal, August 2011

  • Kim, Hee Soo; Arthur, Timothy S.; Allred, Gary D.
  • Nature Communications, Vol. 2, Article No. 427
  • DOI: 10.1038/ncomms1435