Structural and thermodynamic mixing properties of monazite-type solid solutions
La1-xNdxPO4 monazite-type ceramics were synthesized by precipitation and sintering. The obtained crystalline powders and pellets were structurally characterized by X-ray diffraction, electron microscopy, and infrared and Raman spectroscopy. The determined unit cell constants agree with published values for the pure end-members ranging from LaPO4 to DyPO4, as well as with values for known mixed monazite-type lanthanide orthophosphates, indicating a homogeneous solid solution. However, Raman spectroscopy shows a change in short-range order and the results of high temperature oxide melt solution calorimetry suggest a subregular solid solution, which requires two Margules parameters to calculate the observed enthalpy of mixing ΔHmix for La1-xNdxPO4, which is positive and asymmetric and shows a maximum at x = 0.299 (ΔHmix=7.53±0.01kJmol-1) at 298 K.
- Research Organization:
- Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA); Univ. of Notre Dame, IN (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- DOE Contract Number:
- SC0001089
- OSTI ID:
- 1566464
- Journal Information:
- Journal of Solid State Chemistry, Vol. 270, Issue C; ISSN 0022-4596
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
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