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Pore-scale modelling of multiphase reactive flow: application to mineral dissolution with production of CO2

Journal Article · · Journal of Fluid Mechanics
DOI:https://doi.org/10.1017/jfm.2018.655· OSTI ID:1566339

A micro-continuum approach is proposed to simulate the dissolution of solid minerals at the pore scale in the presence of multiple fluid phases. The approach employs an extended Darcy–Brinkman–Stokes formulation that accounts for the interfacial tension between the two immiscible fluid phases and the moving contact line at the mineral surface. The simulation framework is validated using an experimental microfluidic device that provides time-lapse images of the dissolution dynamics. The set-up involves a single-calcite crystal and the subsequent generation of CO2 bubbles in the domain. The dissolution of the calcite crystal and the production of gas during the acidizing process are analysed. We then show that the production of CO2 bubbles during the injection of acid in a carbonate formation may limit the overall dissolution rate and prevent the emergence of wormholes.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Nanoscale Control of Geologic CO2 (NCGC); Univ. of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE SC Office of Basic Energy Sciences (SC-22)
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1566339
Journal Information:
Journal of Fluid Mechanics, Journal Name: Journal of Fluid Mechanics Journal Issue: N/A Vol. 855; ISSN 0022-1120
Publisher:
Cambridge University Press
Country of Publication:
United States
Language:
English

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