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Title: How Transition Metals Enable Electron Transfer through the SEI: Part II. Redox-Cycling Mechanism Model and Experiment

Journal Article · · Journal of the Electrochemical Society
DOI:https://doi.org/10.1149/2.0032001JES· OSTI ID:1565986
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Abstract not provided.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC04-94AL85000; NA0003525; SC0001160
OSTI ID:
1565986
Alternate ID(s):
OSTI ID: 1575772; OSTI ID: 1634800
Report Number(s):
SAND-2019-13098J; SAND-2020-5557J; /jes/167/1/013503.atom
Journal Information:
Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Vol. 167 Journal Issue: 1; ISSN 0013-4651
Publisher:
IOP Publishing - The Electrochemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 9 works
Citation information provided by
Web of Science

References (28)

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Luminescent and Redox-Active Polynuclear Transition Metal Complexes † journal January 1996
Manganese in Graphite Anode and Capacity Fade in Li Ion Batteries journal October 2014
Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells journal December 2016
Aging Analysis of Graphite/LiNi 1/3 Mn 1/3 Co 1/3 O 2 Cells Using XRD, PGAA, and AC Impedance journal January 2015
Connecting the irreversible capacity loss in Li-ion batteries with the electronic insulating properties of solid electrolyte interphase (SEI) components journal March 2016
Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions
  • Marenich, Aleksandr V.; Cramer, Christopher J.; Truhlar, Donald G.
  • The Journal of Physical Chemistry B, Vol. 113, Issue 18, p. 6378-6396 https://doi.org/10.1021/jp810292n
journal May 2009
Comparison of Metal Ion Dissolutions from Lithium Ion Battery Cathodes journal January 2006
Toward reliable density functional methods without adjustable parameters: The PBE0 model journal April 1999
Electrolyte and SEI Decomposition Reactions of Transition Metal Ions Investigated by On-Line Electrochemical Mass Spectrometry journal January 2018
Molecular Probes Reveal Chemical Selectivity of the Solid–Electrolyte Interphase journal August 2018
First-Principles Modeling of Mn(II) Migration above and Dissolution from Li x Mn 2 O 4 (001) Surfaces journal November 2016
Evidence of Transition-Metal Accumulation on Aged Graphite Anodes by SIMS journal January 2008
Influence of Manganese Dissolution on the Degradation of Surface Films on Edge Plane Graphite Negative-Electrodes in Lithium-Ion Batteries journal January 2012
Electrochemical parametrization of metal complex redox potentials, using the ruthenium(III)/ruthenium(II) couple to generate a ligand electrochemical series journal March 1990
Oxidation state of cross-over manganese species on the graphite electrode of lithium-ion cells journal January 2014
Transition metal dissolution and deposition in Li-ion batteries investigated by operando X-ray absorption spectroscopy journal January 2016
Understanding self-discharge mechanism of layered nickel cobalt manganese oxide at high potential journal July 2015
Effect of Manganese Contamination on the Solid-Electrolyte-Interphase Properties in Li-Ion Batteries journal January 2013
Influence of manganese(II), cobalt(II), and nickel(II) additives in electrolyte on performance of graphite anode for lithium-ion batteries journal February 2002
The Formation Mechanism of Fluorescent Metal Complexes at the Li x Ni 0.5 Mn 1.5 O 4−δ /Carbonate Ester Electrolyte Interface journal March 2015
Nickel, Manganese, and Cobalt Dissolution from Ni-Rich NMC and Their Effects on NMC622-Graphite Cells journal January 2019
Correlation between dissolution behavior and electrochemical cycling performance for LiNi1/3Co1/3Mn1/3O2-based cells journal June 2012
Cycling Behavior of NCM523/Graphite Lithium-Ion Cells in the 3–4.4 V Range: Diagnostic Studies of Full Cells and Harvested Electrodes journal September 2016
Role of Manganese Deposition on Graphite in the Capacity Fading of Lithium Ion Batteries journal May 2016

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