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A Nationwide Study of REEs in Geothermal and Produced Waters: Final Results

Conference ·
OSTI ID:1564258
This study sampled and analyzed water from around the United States. Activities that enhanced this work included the co-collection of rock samples, the statistical analysis of the data with an ESOM, and evaluation of extraction by three promising methods. These activities led to five conclusions (1) REEs sometimes occur in continental groundwater in excess of 1000-times their seawater concentrations. (2) REEs exist as a trace (ng/L) component in all analyzed samples. (3) The traditional distinction of light (Z=57-64) and heavy (Z=65-71) REEs in rock-mineral chemistry applies to aqueous chemistry. (4) REE content is not significantly controlled by lithology, reservoir temperature, nor salinity. (5) REE concentration, both in sampled basins and neural network predictions of potential, appears to be spatially co-associated, with the basin mattering more than formation. These five conclusions have advanced the scientific understanding of REEs in subsurface geothermal systems. These conclusions suggest that future work study three questions. (1) What is the spatially–dependent variable that controls REE concentration? (2) Does the output of the ESOM change significantly as input samples are grown in both number and spatial extent? (3) Compared with next-gen analytical techniques, under what metrics does the current method for aqueous REE analysis perform well, and under what metrics is it surpassed? Some of these questions are being investigated in new projects that grew from this work, others would benefit from government support.
Research Organization:
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
AC07-05ID14517
OSTI ID:
1564258
Report Number(s):
INL/CON-19-52743-Rev000
Country of Publication:
United States
Language:
English