In Operando Visualization of the Electrochemical Formation of Liquid Polybromide Microdroplets

Wu, Yutong; Huang, Po‐Wei; Howe, Joshua D.; Yan, Yu; Martinez, Jose; Marianchuk, Anna; Zhang, Yamin; Chen, Hang; Liu, Nian

doi:10.1002/ange.201906980

In Operando Visualization of the Electrochemical Formation of Liquid Polybromide Microdroplets

Journal Article · Thu Sep 05 00:00:00 EDT 2019 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201906980· OSTI ID:1560355

^[1]; Huang, Po‐Wei ^[1]; Howe, Joshua D. ^[2]; Yan, Yu ^[3]; Martinez, Jose ^[4]; Marianchuk, Anna ^[1]; Zhang, Yamin ^[1]; Chen, Hang ^[5]; ^[1]

School of Chemical and Biomolecular Engineering Georgia Institute of Technology Atlanta GA 30332 USA
Department of Chemical Engineering Texas Tech University Lubbock TX 79409 USA
School of Chemical and Biomolecular Engineering Georgia Institute of Technology Atlanta GA 30332 USA, School of Physical Sciences University of Science and Technology of China Hefei Anhui 230026 China
School of Chemical and Biomolecular Engineering Georgia Institute of Technology Atlanta GA 30332 USA, Department of Chemical Engineering Texas A&,M University College Station TX 77840 USA
Institute for Electronics and Nanotechnology Georgia Institute of Technology Atlanta GA 30332 USA

Abstract

Zinc–bromine flow batteries are promising for stationary energy storage, and bromine‐complexing agents have been used to form phase‐separated liquid polybromide products. However, an understanding of the dynamics of polybromide nucleation is limited due to the beam sensitivity and complexity of polybromides. Here we report an in operando platform composed of dark‐field light microscopy and a transparent electrochemical cell to reveal the dynamics of polybromide formation in their native environment. Using our platform, we confirm and reveal the liquid nature, chemical composition, pinning effect (strong interaction with Pt), residual effect (residual charge products on the surface), self‐discharging, and over‐oxidation of the polybromide products. The results provide insights into the role of complexing agents and guide the future design of zinc–bromine flow batteries. Furthermore, our in operando platform can potentially be used to study sensitive species and phases in other electrochemical reactions.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0012577

OSTI ID:: 1560355

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 43 Vol. 131; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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