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Title: A modular, multi-diagnostic, automated shock tube for gas-phase chemistry

Journal Article · · Review of Scientific Instruments
DOI:https://doi.org/10.1063/1.5095077· OSTI ID:1559884

A new shock tube has been constructed for investigations of high-temperature chemical kinetics with an emphasis on combustion chemistry. This instrument includes a diaphragmless driver and electrical control of valving. A diaphragmless design significantly improves repeatability of experimental conditions vs the use of diaphragms and leads to an approximate order of magnitude reduction in turnaround time between experiments. Electrical control of valves, combined with diaphragmless operation, also enables remote and automated operation of the shock tube. The design allows for both incident and reflected shock experiments with multiple diagnostics. The performance of the shock tube is demonstrated by reproducing previous literature measurements on the unimolecular decomposition of isobutyl nitrite and cyclohexene.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; Brown University, Providence, RI (United States)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1559884
Journal Information:
Review of Scientific Instruments, Vol. 90, Issue 6; ISSN 0034-6748
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 5 works
Citation information provided by
Web of Science

References (15)

A diaphragmless shock tube for high temperature kinetic studies journal January 2008
Recent advances in laser absorption and shock tube methods for studies of combustion chemistry journal October 2014
A miniature high repetition rate shock tube journal September 2013
Note: An improved driver section for a diaphragmless shock tube journal January 2015
Unimolecular dissociation of cyclohexene at extremely high temperatures: behavior of the energy-transfer collision efficiency journal May 1987
An Experimental and Theoretical Study of the Thermal Decomposition of C 4 H 6 Isomers journal May 2017
Thermal dissociation of alkyl nitrites and recombination of alkyl radicals journal January 2019
Thermal Dissociation and Roaming Isomerization of Nitromethane: Experiment and Theory journal February 2015
Vibrational Relaxation of Deuterium by a Quantitative Schlieren Method journal January 1966
Reaction Mechanism Generator: Automatic construction of chemical kinetic mechanisms journal June 2016
Vibrational Relaxation of Hydrogen journal January 1966
Refractivity of combustion gases journal January 1981
Design of a high-pressure single pulse shock tube for chemical kinetic investigations journal July 2001
Vibrational Relaxation of Hydrogen journal October 1972
Thermal dissociation of alkyl nitrites and recombination of alkyl radicals text January 2019

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