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Analysis of Tank 30H (HTF-30-19-33, -34), Tank 32H (HTF-32-19-35, -36), and Tank 37H (HTF-37- 19-53, -54) Samples for Support of the Evaporator Feed Qualification and Corrosion Control Programs for the 3H-Evaporator

Technical Report ·
DOI:https://doi.org/10.2172/1559861· OSTI ID:1559861
 [1];  [1];  [1]
  1. Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

SRNL analyzed samples from Tank 30H, Tank 32H, and Tank 37H to support the Evaporator Feed Qualification and Corrosion Control Programs for the 3H-Evaporator system. The six samples from Tanks 30H, 32H, and 37H all contain highly concentrated salt solutions with sodium concentrations ranging from 13.8 M to 16.9 M. Hydroxide is the dominant anion in all of the samples followed by nitrate and nitrite. The preponderance of the analytical determinations (density, anions, cations) on all three tanks show slightly higher concentrations of solute in the sub-surface sample than in the surface sample, indicating some stratification within the tanks. With the exception of the Tank 30H VDS, all of the samples are somewhat more concentrated compared with the compositions of the previous samples. The sum of the major cations versus the sum of the major anions show a difference of <5% for all of the samples indicating good data quality for the non-radioactive analytes in the table. The silicon concentrations measured in the VDS and surface samples from Tank 30H, Tank 32H, and Tank 37H were all below detection.

Research Organization:
Savannah River Site (SRS), Aiken, SC (United States); Savannah River National Lab (SRNL), Aiken, SC (United States)
Sponsoring Organization:
USDOE Office of Environmental Management (EM)
DOE Contract Number:
AC09-08SR22470
OSTI ID:
1559861
Report Number(s):
SRNL-STI--2019-00366
Country of Publication:
United States
Language:
English