Crystallization kinetics of amorphous calcium carbonate in confinement

Cavanaugh, Jack; Whittaker, Michael L.; Joester, Derk

doi:10.1039/c8sc05634j

Title: Crystallization kinetics of amorphous calcium carbonate in confinement

Journal Article · Tue Jan 01 00:00:00 EST 2019 · Chemical Science

DOI:https://doi.org/10.1039/c8sc05634j· OSTI ID:1559215

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Northwestern Univ., Evanston, IL (United States)

In situobservation of amorphous calcium carbonate (ACC) confined in ~500 pL emulsion droplets allows determination of the timing of individual crystal nucleation events. Statistical analysis of events in hundreds of droplets establishes an upper limit for the steady-state nucleation rate of 1.2 cm^-3s^-1for the crystallization from ACC.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1559215

Journal Information:: Chemical Science, Vol. 10, Issue 19; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 21 works

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